Dimerization of propargyl and homopropargyl 6-azido- 6-deoxy- glycosides upon 1,3-dipolar cycloaddition

• Nikolas Pietrzik,
• Daniel Schmollinger and
• Thomas Ziegler

Beilstein J. Org. Chem. 2008, 4, No. 30, doi:10.3762/bjoc.4.30

• product of dimerization though. Only oligomers 8 were observed in this case (for details see Supporting Information File 1). At first, it was unclear whether 7a was formed by an intramolecular cyclization or a dimerization of 4a since its concentration-dependent ESI-MS and MALDI-TOF-MS spectra both showed