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Search for "electron donor" in Full Text gives 172 result(s) in Beilstein Journal of Organic Chemistry.

Graphitic carbon nitride prepared from urea as a photocatalyst for visible-light carbon dioxide reduction with the aid of a mononuclear ruthenium(II) complex

  • Kazuhiko Maeda,
  • Daehyeon An,
  • Ryo Kuriki,
  • Daling Lu and
  • Osamu Ishitani

Beilstein J. Org. Chem. 2018, 14, 1806–1812, doi:10.3762/bjoc.14.153

Graphical Abstract
  • nanoparticles, were capable of reducing CO2 into formate under visible light (λ > 400 nm) in the presence of triethanolamine as an electron donor, with the aid of a molecular Ru(II) cocatalyst (RuP). The CO2 reduction activity was improved by increasing the synthesis temperature of g-C3N4, with the maximum
  • evolution Using the as-prepared g-C3N4, CO2 reduction was conducted with the aid of RuP cocatalyst and Ag promoter in a N,N-dimethylacetamide (DMA)/TEOA mixed solution under visible light (λ > 400 nm). Here TEOA works as an effective electron donor that scavenges holes generated in the valence band of g
  • activity for CO2 reduction was much lower than that for H2 evolution, even though the same electron donor, TEOA, was employed. This in turn implies that there still remains much room for the improvement of CO2 reduction activity, for example, if a proper modification method, which allows for more efficient
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Published 17 Jul 2018

Recent advances in phosphorescent platinum complexes for organic light-emitting diodes

  • Cristina Cebrián and
  • Matteo Mauro

Beilstein J. Org. Chem. 2018, 14, 1459–1481, doi:10.3762/bjoc.14.124

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  • same group reported very recently another family of platinum(II) complexes containing both electron-donor and electron-acceptor moieties embedded within the dopant structure (Figure 13) [63]. This bipolar character was intended to reduce the TTA phenomena commonly experienced at high current density
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Published 18 Jun 2018

Rapid transformation of sulfinate salts into sulfonates promoted by a hypervalent iodine(III) reagent

  • Elsa Deruer,
  • Vincent Hamel,
  • Samuel Blais and
  • Sylvain Canesi

Beilstein J. Org. Chem. 2018, 14, 1203–1207, doi:10.3762/bjoc.14.101

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  • investigations to extend this approach to other carbon-based nucleophiles must be developed. Presumably, the presence of an electron-donor group such as methoxy on the aromatic moiety would stabilize the sulfonium species and increase the yield obtained in these transformations (Scheme 3). This process may also
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Published 24 May 2018

An overview of recent advances in duplex DNA recognition by small molecules

  • Sayantan Bhaduri,
  • Nihar Ranjan and
  • Dev P. Arya

Beilstein J. Org. Chem. 2018, 14, 1051–1086, doi:10.3762/bjoc.14.93

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  • selectively bind mixed G·C and A·T sequences of DNA. They hypothesized that thiophene (positive electrostatic potential) and the electron-donor nitrogen of N-MeBI should pre-organize the conformation for accepting hydrogen bond from G-NH2, which was validated by replacing the thiophene moiety with other
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Published 16 May 2018

Diels–Alder cycloadditions of N-arylpyrroles via aryne intermediates using diaryliodonium salts

  • Huangguan Chen,
  • Jianwei Han and
  • Limin Wang

Beilstein J. Org. Chem. 2018, 14, 354–363, doi:10.3762/bjoc.14.23

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  • synthesized in 75% yield (Scheme 2b), whose structure was determined by 2D-NMR analyses (see Supporting Information File 1). Furthermore, as a unique electron donor, the novel compound 5 may have potential applications in photosensitive dyes and OLEDs [28][29]. Interestingly, the bridged-ring compound 6 could
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Published 06 Feb 2018

Recent advances on organic blue thermally activated delayed fluorescence (TADF) emitters for organic light-emitting diodes (OLEDs)

  • Thanh-Tuân Bui,
  • Fabrice Goubard,
  • Malika Ibrahim-Ouali,
  • Didier Gigmes and
  • Frédéric Dumur

Beilstein J. Org. Chem. 2018, 14, 282–308, doi:10.3762/bjoc.14.18

Graphical Abstract
  • silicon atom, two phenyl rings can be introduced on the silicon-bridged structure providing bulkiness and rigidity to the donor. Intermolecular interactions are thus efficiently prevented and the conformation disorder drastically reduced. When used as electron donor in T1, a ΔEST of 0.14 eV was determined
  • ). Azasiline is a promising electron donor but examples of blue TADF emitters are still scarce. The opposite situation is found for carbazole, which has long been considered as an excellent donor and a large variety of blue TADF emitters have been designed on the basis of this scaffold. At least 19 examples of
  • to combine the electron-donating 9,9-dimethyl-10-phenylacridan with the electron-accepting 2,4,6-triphenyl-1,3,5-triazine was reported under the form of random copolymers derived from a polystyrene (T31–T34, see Figure 9) [60]. Contrarily to the classical TADF materials in which the electron donor is
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Published 30 Jan 2018

Photocatalytic formation of carbon–sulfur bonds

  • Alexander Wimmer and
  • Burkhard König

Beilstein J. Org. Chem. 2018, 14, 54–83, doi:10.3762/bjoc.14.4

Graphical Abstract
  • base and DMSO as solvent they observed a colouring of the reaction mixture, whereas the reagents are colourless themselves. They suggest that the thiol becomes deprotonated to the respective thiolate anion and subsequently an electron donor–acceptor complex with the aryl halide is formed. Irradiation
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Published 05 Jan 2018

Structure–property relationships and third-order nonlinearities in diketopyrrolopyrrole based D–π–A–π–D molecules

  • Jan Podlesný,
  • Lenka Dokládalová,
  • Oldřich Pytela,
  • Adam Urbanec,
  • Milan Klikar,
  • Numan Almonasy,
  • Tomáš Mikysek,
  • Jaroslav Jedryka,
  • Iwan V. Kityk and
  • Filip Bureš

Beilstein J. Org. Chem. 2017, 13, 2374–2384, doi:10.3762/bjoc.13.235

Graphical Abstract
  • be the strongest electron donor within the studied series of compounds. This is in accordance with our previous observations [9][35]. Except for chromophores 3a,b, insertion of an additional acetylene linker rather extended the electrochemical HOMO–LUMO gap (series a vs b). Linear optical properties
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Published 08 Nov 2017

Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines

  • Satoru Mori and
  • Norio Shibata

Beilstein J. Org. Chem. 2017, 13, 2273–2296, doi:10.3762/bjoc.13.224

Graphical Abstract
  • phthalocyanine, which originally acts as an electron donor, will exhibit an electron acceptor property. Thus, it is expected that TFEO-Pcs can be developed as unique functional molecules [41]. This review summarizes the synthesis of various TFEO-Pc derivatives and the effect of fluorine on their properties
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Published 27 Oct 2017

Conformational impact of structural modifications in 2-fluorocyclohexanone

  • Francisco A. Martins,
  • Josué M. Silla and
  • Matheus P. Freitas

Beilstein J. Org. Chem. 2017, 13, 1781–1787, doi:10.3762/bjoc.13.172

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  • of the studied compounds, according to the NBO analysis and in spite of some stabilizing electronic delocalization interactions from electron-donor orbitals to antiperiplanar antibonding orbitals. The electronic interactions mentioned above appeared to be sensitive to the solvent effect, since the
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Published 24 Aug 2017

Chemical systems, chemical contiguity and the emergence of life

  • Terrence P. Kee and
  • Pierre-Alain Monnard

Beilstein J. Org. Chem. 2017, 13, 1551–1563, doi:10.3762/bjoc.13.155

Graphical Abstract
  • , and a nucleobase, 8-oxoguanine, serving as recyclable electron donor to trigger the redox cleavage of the precursor molecule, [71] was also found to be enhanced by the presence of pre-formed fatty acid vesicles. In aqueous media, both parts of the photochemical catalyst needed to be covalently linked
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Published 07 Aug 2017

Transition-metal-free one-pot synthesis of alkynyl selenides from terminal alkynes under aerobic and sustainable conditions

  • Adrián A. Heredia and
  • Alicia B. Peñéñory

Beilstein J. Org. Chem. 2017, 13, 910–918, doi:10.3762/bjoc.13.92

Graphical Abstract
  • to the acetylenic group were also studied (Table 4). Thus, the p-methyl-substituted derivative 6b afforded the selenide 5i in comparable yields as with the unsubstituted alkyne 6a (Table 4, entries 1 and 2). The presence of a strong electron donor such as a methoxy group (compound 6c), decreased the
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Published 16 May 2017

Synthesis of 1-indanones with a broad range of biological activity

  • Marika Turek,
  • Dorota Szczęsna,
  • Marek Koprowski and
  • Piotr Bałczewski

Beilstein J. Org. Chem. 2017, 13, 451–494, doi:10.3762/bjoc.13.48

Graphical Abstract
  • )propanenitriles 193 has been described by Pletnev and Larock [84]. This reaction was compatible with a wide variety of electron-donor and electron-acceptor functional groups. The authors have also found that the formation of 1-indanones 194 is accompanied by the reduction of the carbon–iodine bond in 3-(2
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Published 09 Mar 2017

The reductive decyanation reaction: an overview and recent developments

  • Jean-Marc R. Mattalia

Beilstein J. Org. Chem. 2017, 13, 267–284, doi:10.3762/bjoc.13.30

Graphical Abstract
  • advantages of the nitrile functional group before its removal. Mechanistic details and applications to organic synthesis are provided. Keywords: α-aminonitrile; decyanation; electron donor; hydride; malononitrile; transition metal catalysis; Introduction Many strategies in organic synthesis involve the
  • ) iodide/THF/HMPA at respectively 0 °C and room temperature [123]. Metallic samarium can also promote the decyanation [124]. Doni and Murphy have reported the reductive decyanation of malononitriles and α-cyanoesters by using the neutral organic electron donor 78 (Scheme 25) under photoactivation (method A
  • highly efficient neutral organic electron donor (Scheme 25) [127]. This compound is able to reduce aryl halides and appears as the only reductant able to reduce dialkylarenesulfonamides as well as malononitriles without photoexcitation. Electron donor 80 can be isolated but is more conveniently generated
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Published 13 Feb 2017

Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I)

  • Sem Raj Tamang and
  • James D. Hoefelmeyer

Beilstein J. Org. Chem. 2016, 12, 2757–2762, doi:10.3762/bjoc.12.272

Graphical Abstract
  • ) to form benzyne or that organic electron donors form in situ with suitable additives under the basic conditions of the reaction [58][59][60]. For example, observation of faster direct arylation in the presence of DMF led to proposals of deprotonated DMF as one electron donor [61] or forming a dibasic
  • -enediol in situ as an electron donor [62]. While the SET mechanism has drawn much interest, our observation of large rate enhancement upon addition of the preformed catalyst 2 may be better described with a metalation–deprotonation step followed by oxidative addition/reductive elimination (Scheme 2) [63
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Published 15 Dec 2016

Effects of solvent additive on “s-shaped” curves in solution-processed small molecule solar cells

  • John A. Love,
  • Shu-Hua Chou,
  • Ye Huang,
  • Guilllermo C. Bazan and
  • Thuc-Quyen Nguyen

Beilstein J. Org. Chem. 2016, 12, 2543–2555, doi:10.3762/bjoc.12.249

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  • , National Taiwan University, Taipei, 10617, Taiwan 10.3762/bjoc.12.249 Abstract A novel molecular chromophore, p-SIDT(FBTThCA8)2, is introduced as an electron-donor material for bulk heterojunction (BHJ) solar cells with broad absorption and near ideal energy levels for the use in combination with common
  • counterparts [5][6]. Also of import stands the fact that easily modified, modular structures lead to finely-tunable energy levels and optical properties through molecular design [7][8]. Most high-performing small molecule electron-donor materials are configured such that the conjugated backbone consists of
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Published 28 Nov 2016

High performance p-type molecular electron donors for OPV applications via alkylthiophene catenation chromophore extension

  • Paul B. Geraghty,
  • Calvin Lee,
  • Jegadesan Subbiah,
  • Wallace W. H. Wong,
  • James L. Banal,
  • Mohammed A. Jameel,
  • Trevor A. Smith and
  • David J. Jones

Beilstein J. Org. Chem. 2016, 12, 2298–2314, doi:10.3762/bjoc.12.223

Graphical Abstract
  • -donor– π-bridge-acceptor (A–π-D–π-A) electron donor molecules. Based on the known benzodithiophene-terthiophene-rhodanine (BTR) material, the BXR series of materials, BMR (X = M, monothiophene), BBR (X = B, bithiophene), known BTR (X = T, terthiophene), BQR (X = Q, quaterthiophene), and BPR (X = P(penta
  • to the SVA devices indicates that further optimization may be required. It is evident that modification of the chromophore length has a large impact on the device stability and performance. BQR as a molecular electron donor is the stand-out performer with the best initial results under all device
  • devices optimization is still required. The performance of BQR as a molecular electron donor and the stability of BQR containing BHJ devices encouraged the examination of BQR in ternary BHJ devices. It has been reported that addition of a small percentage of a molecular electron donor to polymer:fullerene
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Published 02 Nov 2016

Comparing blends and blocks: Synthesis of partially fluorinated diblock polythiophene copolymers to investigate the thermal stability of optical and morphological properties

  • Pierre Boufflet,
  • Sebastian Wood,
  • Jessica Wade,
  • Zhuping Fei,
  • Ji-Seon Kim and
  • Martin Heeney

Beilstein J. Org. Chem. 2016, 12, 2150–2163, doi:10.3762/bjoc.12.205

Graphical Abstract
  • -scale is of particular interest in the field of organic photovoltaics (OPV), where separation of the electron donor and acceptor domains on the order of the exciton diffusion length (5–10 nm) is required [1][6][7][8][9]. Many approaches have been reported to tether two or more light-absorbing polymers
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Published 10 Oct 2016

The in situ generation and reactive quench of diazonium compounds in the synthesis of azo compounds in microreactors

  • Faith M. Akwi and
  • Paul Watts

Beilstein J. Org. Chem. 2016, 12, 1987–2004, doi:10.3762/bjoc.12.186

Graphical Abstract
  • with an increase in electron donor strength of the coupling compound. This method eliminates the use of alkaline and acidic solutions (Scheme 1). In another method developed by Rahimizadeh et al., ferric hydrogen sulfate was used as a catalyst to synthesize azo compounds from aromatic amines and 2
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Published 06 Sep 2016

Synthesis and characterization of fluorinated azadipyrromethene complexes as acceptors for organic photovoltaics

  • Forrest S. Etheridge,
  • Roshan J. Fernando,
  • Sandra Pejić,
  • Matthias Zeller and
  • Geneviève Sauvé

Beilstein J. Org. Chem. 2016, 12, 1925–1938, doi:10.3762/bjoc.12.182

Graphical Abstract
  • configuration using P3HT as the electron donor. The best results obtained so far are reported in Table 3. For comparison, we also included results for a typical P3HT:PCBM solar cell. First, we note that best PCEs for Zn(WS3)2 are lower than in our previous publication, 2.36% instead of 4.10% [10]. The main
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Published 29 Aug 2016

Experimental and theoretical investigations on the high-electron donor character of pyrido-annelated N-heterocyclic carbenes

  • Michael Nonnenmacher,
  • Dominik M. Buck and
  • Doris Kunz

Beilstein J. Org. Chem. 2016, 12, 1884–1896, doi:10.3762/bjoc.12.178

Graphical Abstract
  • character than that of typical unsaturated NHCs is expected. However, the IR stretching frequencies of their Rh(CO)2Cl complexes suggest an electron-donor character even stronger than that of saturated NHCs. We ascribe this to the extremely weak π-acceptor character of the dipyrido-annelated NHCs caused by
  • ; electron donor character; N-heterocyclic carbene; rhodium; Introduction N-Heterocyclic carbenes form a ligand class that is typically characterized by a strong σ-donor and a weak or even negligible π-acceptor effect [1][2][3], although Meyer has shown pronounced π-acceptor ability in Cu complexes [4][5][6
  • -conjugated 14 πe− system into which the “empty” pπ-orbital of the carbene is embedded and therefore, could also act as a π-electron donor. To obtain further experimental evidence for this unusually weak π-acceptor (or already weak π-donor character), we determined the 77Se NMR chemical shift of the
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Published 23 Aug 2016

Practical synthetic strategies towards lipophilic 6-iodotetrahydroquinolines and -dihydroquinolines

  • David R. Chisholm,
  • Garr-Layy Zhou,
  • Ehmke Pohl,
  • Roy Valentine and
  • Andrew Whiting

Beilstein J. Org. Chem. 2016, 12, 1851–1862, doi:10.3762/bjoc.12.174

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  • suitability of general structure 1 as an electron donor for the design of charge transfer fluorophores. Finally, crystallographic analysis of the boronic esters 29 and 30 highlighted a subtle flattening of the DHQ structure when compared to the saturated THQ; a structural characteristic that was found to
  • cause fluorescence in 30, indicating that the DHQ may be a more effective electron donor than the THQ. We are currently utilising the optimised syntheses of these interesting compounds in a range of novel fluorophores, and their applications will be communicated in due course. Experimental Synthetic
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Published 16 Aug 2016

Synthesis and properties of fluorescent 4′-azulenyl-functionalized 2,2′:6′,2″-terpyridines

  • Adrian E. Ion,
  • Liliana Cristian,
  • Mariana Voicescu,
  • Masroor Bangesh,
  • Augustin M. Madalan,
  • Daniela Bala,
  • Constantin Mihailciuc and
  • Simona Nica

Beilstein J. Org. Chem. 2016, 12, 1812–1825, doi:10.3762/bjoc.12.171

Graphical Abstract
  • introducing conjugated moieties at the 4′-position [10][11][12]. In this context, the synthesis of tailored terpyridine derivatives with appropriate electron-donor/acceptor moieties may allow for a further improvement of their spectroscopic and electrochemical properties. Owing to its unique fluorescent and
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Published 11 Aug 2016

Effect of the π-conjugation length on the properties and photovoltaic performance of A–π–D–π–A type oligothiophenes with a 4,8-bis(thienyl)benzo[1,2-b:4,5-b′]dithiophene core

  • Ni Yin,
  • Lilei Wang,
  • Yi Lin,
  • Jinduo Yi,
  • Lingpeng Yan,
  • Junyan Dou,
  • Hai-Bo Yang,
  • Xin Zhao and
  • Chang-Qi Ma

Beilstein J. Org. Chem. 2016, 12, 1788–1797, doi:10.3762/bjoc.12.169

Graphical Abstract
  • levels increased (from −5.68 to −5.34 eV) with the increase of the length of the π-conjugated bridge. Organic solar cells using the synthesized compounds as the electron donor and PC61BM as the electron acceptor were fabricated and tested. Results showed that compounds with longer oligothiophene π
  • for constructing high-performance A–π–D–π–A-type organic semiconductors for organic solar cells, where A represents the terminal electron acceptor unit, D represents the core electron donor unit, and π represents the conjugated π-bridge [13][14], and a maximum PCE of 9.95% was reported for a
  • . Organic solar cells based these conjugated small molecules as the electron donor were fabricated and tested. In addition, long-term stability of these solar cells was also studied, and a general structure–property–performance relationship of these type of molecules is evaluated, which could serve as a
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Published 10 Aug 2016

Synthesis and characterization of benzodithiophene and benzotriazole-based polymers for photovoltaic applications

  • Desta Gedefaw,
  • Marta Tessarolo,
  • Margherita Bolognesi,
  • Mario Prosa,
  • Renee Kroon,
  • Wenliu Zhuang,
  • Patrik Henriksson,
  • Kim Bini,
  • Ergang Wang,
  • Michele Muccini,
  • Mirko Seri and
  • Mats R. Andersson

Beilstein J. Org. Chem. 2016, 12, 1629–1637, doi:10.3762/bjoc.12.160

Graphical Abstract
  • a blend of π-conjugated polymer (electron donor) and fullerene derivative (electron acceptor) sandwiched between two electrodes (anode and cathode) [1][2][3][4]. Noticeable achievements have been recorded in terms of the power conversion efficiency (PCE) of lab-scale single junction BHJ PSCs
  • alkylthiophene side chains on the properties of the resulting pristine and blended films are collected and discussed. Solution-processed BHJ PSCs using PTzBDT-1 or PTzBDT-2 as electron-donor materials and PC61BM as electron-acceptor counterpart were fabricated, optimized, and fully characterized. PCEs of 3.3
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Published 01 Aug 2016
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