Beilstein J. Org. Chem.2009,5, No. 52, doi:10.3762/bjoc.5.52
, liquid crystal oligomers provide and stabilize a variety of fluid phases with fascinating functions and oligomeric approach provides a wide flexibility in the molecular design.
The hybridization of above mentioned two varieties of liquid crystals may lead to novel nanostructured materials with
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Graphical Abstract
Scheme 1:
Synthesis of banana bridged discotic dimer. Reagents and conditions; (i) Br(CH2)12Br, Cs2CO3, MEK, ...
Beilstein J. Org. Chem.2009,5, No. 25, doi:10.3762/bjoc.5.25
the rise of an intense band centered at ~460 nm (Figure 1a/b). The spectral signature of this band allows an assignment to the open forms with a more planar structure due to the sp2-hybridization at the formerly sp3-hybridized carbon carrying the aryl residues. The π-system now extends over a