Synthesis, photophysical and electrochemical characterization of terpyridine-functionalized dendritic oligothiophenes and their Ru(II) complexes

• Amaresh Mishra,
• Elena Mena-Osteritz and
• Peter Bäuerle

Beilstein J. Org. Chem. 2013, 9, 866–876, doi:10.3762/bjoc.9.100

• Amaresh Mishra Elena Mena-Osteritz Peter Bauerle Institute of Organic Chemistry II and Advanced Materials, Ulm University, Albert-Einstein-Allee 11, 89081 Ulm, Germany 10.3762/bjoc.9.100 Abstract Pd-catalyzed Sonogashira cross-coupling reactions were used to synthesize novel π-conjugated

• oligomers and polymers are amongst the best-studied π-conjugated systems in the past few decades because of their tunable optoelectronic properties [6][7][8]. Furthermore, transition-metal complexes offer significant advantages such as long-lived luminescent excited states, high chemical and photochemical

• the tpy-ethynyl type have proven to be very useful and provide a library of photoresponsive complexes derived from the basic Ru(II)-tpy type module [23][24][25][26][27]. Recently, tpy-complexes that incorporate π-conjugated thiophene or thienylene-ethynylene units became available, and the study of

Superstructures of fluorescent cyclodextrin via click-reaction

• Arkadius Maciollek,
• Helmut Ritter and
• Rainer Beckert

Beilstein J. Org. Chem. 2013, 9, 827–831, doi:10.3762/bjoc.9.94

• fluorescent nature [1][2]. These optical properties can be used for the development of sensor molecules, blue emitting dyes, luminescent materials or as donor–(π-conjugated-bridge)–acceptor-type dyes in dye-sensitized solar cells [3][4][5]. The etherification of 4-hydroxythiazole by using propargyl bromide

Synthesis of meso-substituted dihydro-1,3-oxazinoporphyrins

• Satyasheel Sharma and
• Mahendra Nath

Beilstein J. Org. Chem. 2013, 9, 496–502, doi:10.3762/bjoc.9.53

• of a new series of dihydro-1,3-oxazinoporphyrins in moderate to good yields. These novel porphyrin-dihydro-1,3-oxazine hybrids may be considered as potential candidates not only for biological evaluations but also for the development of newer π-conjugated molecules for various material applications

Highly stereocontrolled synthesis of trans-enediynes via carbocupration of fluoroalkylated diynes

• Tsutomu Konno,
• Misato Kishi and
• Takashi Ishihara

Beilstein J. Org. Chem. 2012, 8, 2207–2213, doi:10.3762/bjoc.8.249

• ; carbometallation; diyne; enediyne; fluorine; highly regioselective; highly stereoselective; Introduction trans-Enediynes (trans-hex-3-ene-1,5-diynes), as shown in Figure 1, are well-recognized as one of the most important building blocks because they are frequently utilized for the synthesis of π-conjugated

The chemistry of bisallenes

• Henning Hopf and
• Georgios Markopoulos

Beilstein J. Org. Chem. 2012, 8, 1936–1998, doi:10.3762/bjoc.8.225

Synthesis and characterization of low-molecular-weight π-conjugated polymers covered by persilylated β-cyclodextrin

• Aurica Farcas,
• Ana-Maria Resmerita,
• Andreea Stefanache,
• Mihaela Balan and
• Valeria Harabagiu

Beilstein J. Org. Chem. 2012, 8, 1505–1514, doi:10.3762/bjoc.8.170

• several known host molecules, e.g., crown ethers [32], cyclodextrins (CDs) have been employed for the synthesis of polyrotaxanes with π-conjugated polymers. As a result, many CD-based rotaxanes and polyrotaxanes have been reported until now [5][11][12][19][20][21][22][23][24][25][26][27][28][29][30][31

Imidazole as a parent π-conjugated backbone in charge-transfer chromophores

• Jiří Kulhánek and
• Filip Bureš

Beilstein J. Org. Chem. 2012, 8, 25–49, doi:10.3762/bjoc.8.4

• devices, etc [1][2][3]. A typical one-component organic D-π-A chromophore consists of a π-conjugated system end-capped with strong electron donors D (e.g. NR2 or OR groups) and strong electron acceptors A (e.g. NO2 or CN groups). This D-π-A arrangement assures efficient intramolecular charge transfer (ICT

• electronic behavior of the appended donors and acceptors and the character and length of the π-conjugated linker [4][5][6][7]. Recently, it was also recognized that push–pull systems applicable as organic materials should possess high chemical and thermal robustness, good solubility in common organic

• solvents, and should be available in reasonable quantities. Hence, various five- and six-membered heterocycles were utilized as suitable π-conjugated chromophore backbones. Moreover, heteroatoms may act as auxiliary donors or acceptors and improve the overall polarizability of the chromophore. In this

Conjugated polymers containing diketopyrrolopyrrole units in the main chain

• Bernd Tieke,
• A. Raman Rabindranath,
• Kai Zhang and
• Yu Zhu

Beilstein J. Org. Chem. 2010, 6, 830–845, doi:10.3762/bjoc.6.92

• ; photoluminescence; solar cell; Introduction A useful strategy in the design of new polymers for electronic applications is to incorporate chromophores which are highly absorbing and emitting in the visible and near infrared region into π-conjugated polymers chains. Potentially useful chromophores for electronic

Chromo- and fluorophoric water-soluble polymers and silica particles by nucleophilic substitution reaction of poly(vinyl amine)

• Katja Hofmann,
• Ingolf Kahle,
• Frank Simon and
• Stefan Spange

Beilstein J. Org. Chem. 2010, 6, No. 79, doi:10.3762/bjoc.6.79

• explained by two factors: Firstly, the fluorophore is a very rigid and planar molecule and secondly, the fluorophore contains both strongly electron-withdrawing and electron-donating groups along the axis of the π-conjugated system. Therefore, an efficient intramolecular charge transfer (ICT) system is

Synthesis of indolo[3,2-b]carbazole-based new colorimetric receptor for anions: A unique color change for fluoride ions

• Ajit Kumar Mahapatra,
• Giridhari Hazra and
• Prithidipa Sahoo

Beilstein J. Org. Chem. 2010, 6, No. 12, doi:10.3762/bjoc.6.12

• OH subunit of 1, while an excess of F− induces the deprotonation of the catechol moieties and NH proton, which brings electron density onto the π-conjugated framework through bond propagation, thus causing a shielding effect and inducing upfield shift of aromatic protons. The above mentioned results

Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry

• Jiří Kulhánek,
• Filip Bureš and
• Miroslav Ludwig

Beilstein J. Org. Chem. 2009, 5, No. 11, doi:10.3762/bjoc.5.11

• π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further

• ], organic light-emitting diodes (OLED) [9] or functional polymers [10][11][12][13]. A typical push-pull chromophore consists of a polar A-π-D system with a planar π-system end-capped by a strong electron donor (D) and a strong electron acceptor (A). The π-conjugated system ensuring charge-transfer (CT

• the extension or shortening of the π-conjugated path between the donor and acceptor [19][21][23][24][25]. Thus, the latter modular synthetic approach seems to be more suitable for the property tuning described above. The final combination, C–C bond formation, of the donor and acceptor chromophore

Synthesis and redox behavior of new ferrocene- π-extended- dithiafulvalenes: An approach for anticipated organic conductors

• Abdelwareth A. O. Sarhan,
• Omar F. Mohammed and
• Taeko Izumi

Beilstein J. Org. Chem. 2009, 5, No. 6, doi:10.3762/bjoc.5.6

• multicomponent electron donor systems by the Wittig–Horner reaction of the respective phosphonate ester 6 with different ferreocenylketones using the modifications introduced onto the reaction. The redox chemistry of the ferreocenylketones and these new π-conjugated hybrids 8, 10 and 11 has been studied using