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Search for "bathochromic shift" in Full Text gives 108 result(s) in Beilstein Journal of Organic Chemistry.
Chromo- and fluorophoric water-soluble polymers and silica particles by nucleophilic substitution reaction of poly(vinyl amine)
- Katja Hofmann,
- Ingolf Kahle,
- Frank Simon and
- Stefan Spange
Beilstein J. Org. Chem. 2010, 6, No. 79, doi:10.3762/bjoc.6.79
- both compounds, the shortest UV–vis absorption maxima were observed at λmax(1-M) = 568 nm and λmax(1-P) = 513 nm in HFIP. 1-M shows the longest wavelength UV–vis absorption band at λmax = 580 nm in DMSO, whereas 1-P has the strongest bathochromic shift in ethanol at λmax = 538 nm. These band shifts
- coefficients r are greater than 0.92 for LSERs, which indicates a high quality of the two multi-parameter equations and allows significant conclusions to be drawn. When increasing the HBA strength of the solvent, a bathochromic shift of the UV–vis absorption maxima of 1-M is observed, which is readily
- . In contrast to the results of the regression analysis obtained from the UV–vis absorption spectra, the HBD ability of the solvents shows a significant influence on the emission maxima of 1-P. With increasing HBD strength of the solvent a bathochromic shift of the emission maximum was observed
Graphical Abstract
Scheme 1: Synthesis of carbonitrile 1.
Scheme 2: Coupling of the β-DMCD-caged carbonitrile derivative 1-DMCD with PVAm to yield the fluorophore-func...
Figure 1: Solid state 13C-{1H}-CP-MAS NMR spectra of pure PVAm (a), functionalized PVAm 1-P (b) and the model...
Scheme 3: Synthesis of 1-Si by nucleophilic aromatic substitution of 1 adsorbed onto silica particles.
Figure 2: Wide-scan X-ray photoelectron spectra (left), C 1s and N 1s high-resolution spectra (right) of bare...
Figure 3: Pore-size distribution of bare silica, PVAm/silica and 1-Si.
Figure 4: UV–vis absorption and emission diffuse reflectance spectra of sample 1-Si.
Figure 5: Normalized absorption and emission spectra of 1-M (a) and 1-P (b).
Figure 6: Normalized emission spectra of 1-P in water at four different pH values and a sketch of the assumed...
RAFT polymers for protein recognition
- Alan F. Tominey,
- Julia Liese,
- Sun Wei,
- Klaus Kowski,
- Thomas Schrader and
- Arno Kraft
Beilstein J. Org. Chem. 2010, 6, No. 66, doi:10.3762/bjoc.6.66
- characteristic second derivative spectra, similar to those observed in the titrations of microgels into protein solutions [16]. Isosbestic points are clearly visible along with a bathochromic shift of the absorbance peak (Figure 2a). A dissociation constant of 1.6 × 103 M−1 could be fitted to the binding
Graphical Abstract
Figure 1: Structures of monomers 1–7 and chain transfer agent 8 used in the RAFT polymerizations.
Figure 2: a) Second derivative UV–vis spectra [17-19] observed during a full titration of a stock solution of RAFT c...
Figure 3: Isothermal calorimetric binding curves for selected polymer/protein host–guest pairs. a) Typical bi...
Figure 4: Graphical illustration of the potential binding mode on hemoglobin tetramer (represented as electro...
A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
- Falk Wehmeier and
- Jochen Mattay
Beilstein J. Org. Chem. 2010, 6, No. 53, doi:10.3762/bjoc.6.53
- ), Co(II), Ni(II) and Zn(II). The UV–vis-spectra of the iron(II) complex [Fe2+@10a], obtained by reaction of 10a with ferric chloride tetrahydrate, are shown in Figure 4. Apart from the expected bathochromic shift of the UV-bands of the ligand [18], an MLCT band at λ = 570 nm was observed. While the UV
Graphical Abstract
Scheme 1: Synthesis of twofold iodinated bis(benzo[b]thiophenyl)perfluorocyclopentene 4.
Scheme 2: Synthesis of terpyridinyl boronic acids 9a and 9b.
Scheme 3: Synthesis of the bis(terpyridinyl)diarylethenes 10a and 10b.
Scheme 4: Photochromic reaction of the free ligand 10a.
Figure 1: UV–vis-spectra of 10a before (solid), after UV-irradiation (dashed) and after irradiation with vis ...
Scheme 5: Synthesis of the binuclear Ru(II)-complex 12.
Figure 2: UV–vis-spectra of 12 before (solid), after UV-irradiation (dashed) and after irradiation with vis l...
Figure 3: UV–vis-spectra of 12 before (dashed), after UV-irradiation (dotted), the difference (solid) and fre...
Figure 4: UV–vis-spectra of [Fe2+@10a] before (solid), after UV-irradiation (dashed) and after irradiation wi...
Figure 5: UV–vis-spectra of [Zn2+@10a] before (solid), after UV-irradiation (dashed) and after irradiation wi...
Preparation of pyridine-3,4-diols, their crystal packing and their use as precursors for palladium-catalyzed cross-coupling reactions
- Tilman Lechel,
- Irene Brüdgam and
- Hans-Ulrich Reissig
Beilstein J. Org. Chem. 2010, 6, No. 42, doi:10.3762/bjoc.6.42
- phenyl substituent at C-2 of pyridine 4c, the π-system is slightly more extended and obviously influences the absorption and emission maxima with a bathochromic shift of 10 nm. Conclusion In conclusion, we have successfully demonstrated that 3-alkoxypyridines are ideal precursors for the synthesis of
Graphical Abstract
Scheme 1: Deprotection of 3-alkoxypyridinols 1 to pyridine-3,4-diols 2. aMethod a: Pd/C, H2, MeOH, rt, 1 d; b...
Figure 1: X-ray crystal structure of compound 2c/2c′.
Scheme 2: Conversion of pyridine-3,4-diols 2 into pyridinediyl bistriflates or -nonaflates 3. a) Et3N, Rf2O, ...
Scheme 3: Sonogashira couplings of pyridinediyl bis(perfluoroalkanesulfonates) 3. a) Pd(PPh3)4 [or Pd(OAc)2/P...
Figure 2: Absorption and fluorescence spectra of compounds 4b and 4c.
Molecular recognition of organic ammonium ions in solution using synthetic receptors
- Andreas Späth and
- Burkhard König
Beilstein J. Org. Chem. 2010, 6, No. 32, doi:10.3762/bjoc.6.32
Graphical Abstract
Figure 1: Biologically important amines and quaternary ammonium salts: histamine (1), dopamine (2) and acetyl...
Figure 2: Crown ether 18-crown-6.
Figure 3: Conformations of 18-crown-6 (4) in solvents of different polarity.
Figure 4: Binding topologies of the ammonium ion depending on the crown ring size.
Figure 5: A “pseudorotaxane” structure consisting of 24-crown-8 and a secondary ammonium ion (5); R = Ph.
Figure 6: Typical examples of azacrown ethers, cryptands and related aza macrocycles.
Figure 7: Binding of ammonium to azacrown ethers and cryptands [111-113].
Figure 8: A 19-crown-6-ether with decalino blocking groups (11) and a thiazole-dibenzo-18-crown-6-ether (12).
Figure 9: 1,3-Bis(6-oxopyridazin-1-yl)propane derivatives 13 and 14 by Campayo et al.
Figure 10: Fluorescent azacrown-PET-sensors based on coumarin.
Figure 11: Two different pyridino-cryptands (17 and 18) compared to a pyridino-crown (19); chiral ammonium ion...
Figure 12: Pyridino-18-crown-6 ligand (21), a similar acridino-18-crown-6 ligand (22) and a structurally relat...
Figure 13: Ciral pyridine-azacrown ether receptors 24.
Figure 14: Chiral 15-crown-5 receptors 26 and an analogue 18-crown-6 ligand 27 derived from amino alcohols.
Figure 15: C2-symmetric chiral 18-crown-6 amino alcohol derivatives 28 and related macrocycles.
Figure 16: Macrocycles with diamide-diester groups (30).
Figure 17: C2-symmetric chiral aza-18-crown-6 ethers (31) with phenethylamine residues.
Figure 18: Chiral C-pivot p-methoxy-phenoxy-lariat ethers.
Figure 19: Chiral lariat crown ether 34.
Figure 20: Sucrose-based chiral crown ether receptors 36.
Figure 21: Permethylated fructooligosaccharide 37 showing induced-fit chiral recognition.
Figure 22: Biphenanthryl-18-crown-6 derivative 38.
Figure 23: Chiral lariat crown ethers derived from binol by Fuji et al.
Figure 24: Chiral phenolic crown ether 41 with “aryl chiral barriers” and guest amines.
Figure 25: Chiral bis-crown receptor 43 with a meso-ternaphthalene backbone.
Figure 26: Chromogenic pH-dependent bis-crown chemosensor 44 for diamines.
Figure 27: Triamine guests for binding to receptor 44.
Figure 28: Chiral bis-crown phenolphthalein chemosensors 46.
Figure 29: Crown ether amino acid 47.
Figure 30: Luminescent receptor 48 for bis-alkylammonium guests.
Figure 31: Luminescent CEAA (49a), a bis-CEAA receptor for amino acids (49b) and the structure of lysine bindi...
Figure 32: Luminescent CEAA tripeptide for binding small peptides.
Figure 33: Bis crown ether 51a self assembles co-operatively with C60-ammonium ion 51b.
Figure 34: Triptycene-based macrotricyclic dibenzo-[24]-crown-8 ether host 52 and guests.
Figure 35: Copper imido diacetic acid azacrown receptor 53a and the suggested His-Lys binding motif; a copper ...
Figure 36: Urea (54) and thiourea (55) benzo crown receptor for transport and extraction of amino acids.
Figure 37: Crown pyryliums ion receptors 56 for amino acids.
Figure 38: Ditopic sulfonamide bridged crown ether receptor 57.
Figure 39: Luminescent peptide receptor 58.
Figure 40: Luminescent receptor 59 for the detection of D-glucosamine hydrochloride in water/ethanol and lumin...
Figure 41: Guanidinium azacrown receptor 61 for simple amino acids and ditopic receptor 62 with crown ether an...
Figure 42: Chiral bicyclic guanidinium azacrown receptor 63 and similar receptor 64 for the enantioselective t...
Figure 43: Receptors for zwitterionic species based on luminescent CEAAs.
Figure 44: 1,10-Azacrown ethers with sugar podand arms and the anticancer agent busulfan.
Figure 45: Benzo-18-crown-6 modified β-cyclodextrin 69 and β-cyclodextrin functionalized with diaza-18-crown-6...
Figure 46: Receptors for colorimetric detection of primary and secondary ammonium ions.
Figure 47: Porphyrine-crown-receptors 72.
Figure 48: Porphyrin-crown ether conjugate 73 and fullerene-ammonium ion guest 74.
Figure 49: Calix[4]arene (75a), homooxocalix[4]arene (75b) and resorcin[4]arene (75c) compared (R = H, alkyl c...
Figure 50: Calix[4]arene and ammonium ion guest (R = H, alkyl, OAcyl etc.), possible binding sites; A: co-ordi...
Figure 51: Typical guests for studies with calixarenes and related molecules.
Figure 52: Lower rim modified p-tert-butylcalix[5]arenes 82.
Figure 53: The first example of a water soluble calixarene.
Figure 54: Sulfonated water soluble calix[n]arenes that bind ammonium ions.
Figure 55: Displacement assay for acetylcholine (3) with a sulfonato-calix[6]arene (84b).
Figure 56: Amino acid inclusion in p-sulfonatocalix[4]arene (84a).
Figure 57: Calixarene receptor family 86 with upper and lower rim functionalization.
Figure 58: Calix[6]arenes 87 with one carboxylic acid functionality.
Figure 59: Sulfonated calix[n]arenes with mono-substitution at the lower rim systematically studied on their r...
Figure 60: Cyclotetrachromotropylene host (91) and its binding to lysine (81c).
Figure 61: Calixarenes 92 and 93 with phosphonic acids groups.
Figure 62: Calix[4]arene tetraphosphonic acid (94a) and a double bridged analogue (94b).
Figure 63: Calix[4]arene tetraphosphonic acid ester (92c) for surface recognition experiments.
Figure 64: Calixarene receptors 95 with α-aminophosphonate groups.
Figure 65: A bridged homocalix[3]arene 95 and a distally bridged homocalix[4]crown 96.
Figure 66: Homocalix[3]arene ammonium ion receptor 97a and the Reichardt’s dye (97b) for colorimetric assays.
Figure 67: Chromogenic diazo-bridged calix[4]arene 98.
Figure 68: Calixarene receptor 99 by Huang et al.
Figure 69: Calixarenes 100 reported by Parisi et al.
Figure 70: Guest molecules for inclusion in calixarenes 100: DAP × 2 HCl (101a), APA (101b) and Lys-OMe × 2 HC...
Figure 71: Different N-linked peptido-calixarenes open and with glycol chain bridges.
Figure 72: (S)-1,1′-Bi-2-naphthol calixarene derivative 104 published by Kubo et al.
Figure 73: A chiral ammonium-ion receptor 105 based on the calix[4]arene skeleton.
Figure 74: R-/S-phenylalaninol functionalized calix[6]arenes 106a and 106b.
Figure 75: Capped homocalix[3]arene ammonium ion receptor 107.
Figure 76: Two C3 symmetric capped calix[6]arenes 108 and 109.
Figure 77: Phosphorous-containing rigidified calix[6]arene 110.
Figure 78: Calix[6]azacryptand 111.
Figure 79: Further substituted calix[6]azacryptands 112.
Figure 80: Resorcin[4]arene (75c) and the cavitands (113).
Figure 81: Tetrasulfonatomethylcalix[4]resorcinarene (114).
Figure 82: Resorcin[4]arenes (115a/b) and pyrogallo[4]arenes (115c, 116).
Figure 83: Displacement assay for acetylcholine (3) with tetracyanoresorcin[4]arene (117).
Figure 84: Tetramethoxy resorcinarene mono-crown-5 (118).
Figure 85: Components of a resorcinarene based displacement assay for ammonium ions.
Figure 86: Chiral basket resorcin[4]arenas 121.
Figure 87: Resorcinarenes with deeper cavitand structure (122).
Figure 88: Resorcinarene with partially open deeper cavitand structure (123).
Figure 89: Water-stabilized deep cavitands with partially structure (124, 125).
Figure 90: Charged cavitands 126 for tetralkylammonium ions.
Figure 91: Ditopic calix[4]arene receptor 127 capped with glycol chains.
Figure 92: A calix[5]arene dimer for diammonium salt recognition.
Figure 93: Calixarene parts 92c and 129 for the formation molecular capsules.
Figure 94: Encapsulation of a quaternary ammonium cation by two resorcin[4]arene molecules (NMe4+@[75c]2 × Cl−...
Figure 95: Encapsulation of a quaternary ammonium cation by six resorcin[4]arene molecules (NMe3D+@[130]6 × Cl−...
Figure 96: Structure and schematic of cucurbit[6]uril (CB[6], 131a).
Figure 97: Cyclohexanocucurbit[6]uril (CB′[6], 132) and the guest molecule spermine (133).
Figure 98: α,α,δ,δ-Tetramethylcucurbit[6]uril (134).
Figure 99: Structure of the cucurbituril-phthalhydrazide analogue 135.
Figure 100: Organic cavities for the displacement assay for amine differentiation.
Figure 101: Displacement assay methodology for diammonium- and related guests involving cucurbiturils and some ...
Figure 102: Nor-seco-Cucurbituril (±)-bis-ns-CB[6] (140) and guest molecules.
Figure 103: The cucurbit[6]uril based complexes 141 for chiral discrimination.
Figure 104: Cucurbit[7]uril (131c) and its ferrocene guests (142) opposed.
Figure 105: Cucurbit[7]uril (131c) guest inclusion and representative guests.
Figure 106: Cucurbit[7]uril (131c) binding to succinylcholine (145) and different bis-ammonium and bis-phosphon...
Figure 107: Paraquat-cucurbit[8]uril complex 149.
Figure 108: Gluconuril-based ammonium receptors 150.
Figure 109: Examples of clefts (151a), tweezers (151b, 151c, 151d) and clips (151e).
Figure 110: Kemp’s triacid (152a), on example of Rebek’s receptors (152b) and guests.
Figure 111: Amino acid receptor (154) by Rebek et al.
Figure 112: Hexagonal lattice designed hosts by Bell et al.
Figure 113: Bell’s amidinium receptor (156) and the amidinium ion (157).
Figure 114: Aromatic phosphonic acids.
Figure 115: Xylene phosphonates 159 and 160a/b for recognition of amines and amino alcohols.
Figure 116: Bisphosphonate recognition motif 161 for a colorimetric assay with alizarin complexone (163) for ca...
Figure 117: Bisphosphonate/phosphate clip 164 and bisphosphonate cleft 165.
Figure 118: N-Methylpyrazine 166a, N-methylnicotinamide iodide (166b) and NAD+ (166c).
Figure 119: Bisphosphate cavitands.
Figure 120: Bisphosphonate 167 of Schrader and Finocchiaro.
Figure 121: Tweezer 168 for noradrenaline (80b).
Figure 122: Different tripods and heparin (170).
Figure 123: Squaramide based receptors 172.
Figure 124: Cage like NH4+ receptor 173 of Kim et al.
Figure 125: Ammonium receptors 174 of Chin et al.
Figure 126: 2-Oxazolin-based ammonium receptors 175a–d and 176 by Ahn et al.
Figure 127: Racemic guest molecules 177.
Figure 128: Tripods based on a imidazole containing macrocycle (178) and the guest molecules employed in the st...
Figure 129: Ammonium ion receptor 180.
Figure 130: Tetraoxa[3.3.3.3]paracyclophanes 181 and a cyclophanic tetraester (182).
Figure 131: Peptidic bridged paraquat-cyclophane.
Figure 132: Shape-selective noradrenaline host.
Figure 133: Receptor 185 for binding of noradrenaline on surface layers from Schrader et al.
Figure 134: Tetraphosphonate receptor for binding of noradrenaline.
Figure 135: Tetraphosphonate 187 of Schrader and Finocchiaro.
Figure 136: Zinc-Porphyrin ammonium-ion receptors 188 and 189 of Mizutani et al.
Figure 137: Zinc porphyrin receptor 190.
Figure 138: Zinc porphyrin receptors 191 capable of amino acid binding.
Figure 139: Zinc-porphyrins with amino acid side chains for stereoinduction.
Figure 140: Bis-zinc-bis-porphyrin based on Tröger’s base 193.
Figure 141: BINAP-zinc-prophyrin derivative 194 and it’s guests.
Figure 142: Bisaryl-linked-zinc-porphyrin receptors.
Figure 143: Bis-zinc-porphyrin 199 for diamine recognition and guests.
Figure 144: Bis-zinc-porphyrin crown ether 201.
Figure 145: Bis-zinc-porphyrin 202 for stereodiscrimination (L = large substituent; S = small substituent).
Figure 146: Bis-zinc-porphyrin[3]rotaxane and its copper complex and guests.
Figure 147: Dien-bipyridyl ligand 206 for co-ordination of two metal atoms.
Figure 148: The ligand and corresponding tetradentate co-complex 207 serving as enantioselective receptor for a...
Figure 149: Bis(oxazoline)–copper(II) complex 208 for the recognition of amino acids in aqueous solution.
Figure 150: Zinc-salen-complexes 209 for the recognition tertiary amines.
Figure 151: Bis(oxazoline)–copper(II) 211 for the recognition of amino acids in aqueous solution.
Figure 152: Zn(II)-complex of a C2 terpyridine crown ether.
Figure 153: Displacement assay and receptor for aspartate over glutamate.
Figure 154: Chiral complex 214 for a colorimetric displacement assay for amino acids.
Figure 155: Metal complex receptor 215 with tripeptide side arms.
Figure 156: A sandwich complex 216 and its displaceable dye 217.
Figure 157: Lanthanide complexes 218–220 for amino acid recognition.
Figure 158: Nonactin (221), valinomycin (222) and vancomycin (223).
Figure 159: Monesin (224a) and a chiral analogue for enantiodiscrimination of ammonium guests (224b).
Figure 160: Chiral podands (226) compared to pentaglyme-dimethylether (225) and 18-crown-6 (4).
Figure 161: Lasalocid A (228).
Figure 162: Lasalocid derivatives (230) of Sessler et al.
Figure 163: The Coporphyrin I tetraanion (231).
Figure 164: Linear and cyclic peptides for ammonium ion recognition.
Figure 165: Cyclic and bicyclic depsipeptides for ammonium ion recognition.
Figure 166: α-Cyclodextrin (136a) and novocaine (236).
Figure 167: Helical diol receptor 237 by Reetz and Sostmann.
Figure 168: Ammonium binding spherand by Cram et al. (238a) and the cyclic[6]metaphenylacetylene 238b in compar...
Figure 169: Receptor for peptide backbone and ammonium binding (239).
Figure 170: Anion sensor principle with 3-hydroxy-2-naphthanilide of Jiang et al.
Figure 171: 7-bromo-3-hydroxy-N-(2-hydroxyphenyl)naphthalene 2-carboxamide (241) and its amine binding.
Figure 172: Naturally occurring catechins with affinity to quaternary ammonium ions.
Figure 173: Spiropyran (244) and merocyanine form (244a) of the amino acid receptors of Fuji et al.
Figure 174: Coumarin aldehyde (245) and its iminium species with amino acid bound (245a) by Glass et al.
Figure 175: Coumarin aldehyde appended with boronic acid.
Figure 176: Quinolone aldehyde dimers by Glass et al.
Figure 177: Chromogenic ammonium ion receptors with trifluoroacetophenone recognition motifs.
Figure 178: Chromogenic ammonium ion receptor with trifluoroacetophenone recognition motif bound on different m...
Synthetic incorporation of Nile Blue into DNA using 2′-deoxyriboside substitutes: Representative comparison of (R)- and (S)-aminopropanediol as an acyclic linker
- Daniel Lachmann,
- Sina Berndl,
- Otto S. Wolfbeis and
- Hans-Achim Wagenknecht
Beilstein J. Org. Chem. 2010, 6, No. 13, doi:10.3762/bjoc.6.13
- and the corresponding modified oligonucleotides in the visible range are the loss of one absorption band and a red-shift from 633 nm to 653 nm for the second absorption signal. A further small bathochromic shift of ca. 5 nm is observed upon hybridization of the modified single strands DNA1 and DNA2 to
Graphical Abstract
Scheme 1: Chirality of C-3 of natural 2′-deoxyribofuranosides (left) in comparison with the acyclic D-threoni...
Scheme 2: Synthesis of the R-configured DNA building block 3 and postsynthetic click ligation of the Nile Blu...
Figure 1: UV–vis absorption spectra of single-stranded DNA1 and DNA2, and the corresponding duplexes DNA1Y an...
Figure 2: Fluorescence spectra of single-stranded DNA1 and DNA2, and corresponding duplexes DNA1Y and DNA2Y (...
Figure 3: Models for DNA1A bearing the (R)-3-amino-1,2-propanediol linker (left) and the corresponding duplex...
An enantiomerically pure siderophore type ligand for the diastereoselective 1 : 1 complexation of lanthanide(III) ions
- Markus Albrecht,
- Olga Osetska,
- Thomas Abel,
- Gebhard Haberhauer and
- Eva Ziegler
Beilstein J. Org. Chem. 2009, 5, No. 78, doi:10.3762/bjoc.5.78
- wavelengths exhibit a positive Cotton effect. As the calculated maximum of the UV spectrum (530 nm) shows a bathochromic shift relative to the measured UV spectrum (470 nm), the corresponding peak in the calculated CD spectrum (540 nm) is shifted to higher wavelengths relative to the experimentally measured
Graphical Abstract
Figure 1: Structural formula of the siderophore enterobactine.
Scheme 1: Preparation of the compound 1a-H3 by utilization of a multiple Claisen-rearrangement.
Figure 2: 1H NMR spectra (300 MHz, CDCl3) of the ether compound 4 (top) and the ligand 1a-H3 (bottom).
Figure 3: Positive ESI MS of [(1a)La] in chloroform showing the peaks of {K[(1a)La]}+ (m/z = 1600.8) as well ...
Figure 4: CD and UV absorption titration curves for complexation of ligand 1a-H3 with lanthanum(III)nitrate h...
Figure 5: Titration curve observed for ligand 1a-H3 upon addition of lanthanum(III) nitrate hexahydrate.
Figure 6: Molecular structures of the Λ2 (left) and Δ2 (right) isomers of complex 1b·La calculated by using B...
Figure 7: UV and CD spectra of the complex (Λ)-1·La. Blue and violet curve: experimentally determined spectra...
New diarylmethanofullerene derivatives and their properties for organic thin- film solar cells
- Daisuke Sukeguchi,
- Surya Prakash Singh,
- Mamidi Ramesh Reddy,
- Hideyuki Yoshiyama,
- Rakesh A. Afre,
- Yasuhiko Hayashi,
- Hiroki Inukai,
- Tetsuo Soga,
- Shuichi Nakamura,
- Norio Shibata and
- Takeshi Toru
Beilstein J. Org. Chem. 2009, 5, No. 7, doi:10.3762/bjoc.5.7
- decrease of that at 140 °C. The P3HT:1a-based cell showed a maximum at around 550 nm, whereas the P3HT:PCBM annealed at 100 and 130 °C exhibited the maxima at around 505 nm as shown in Figure 4(B). Since these responsivities are definitely derived from the absorption of P3HT, this notable bathochromic
- shift in the responsivity maxima of P3HT:1a in comparison with P3HT:PCBM can be ascribed to the change in the alignment of the P3HT polymer chain induced by the long octyloxy chains of 1a. A change of the annealing temperature may also be related to the growth of the domain size of derivative 1a, as
Graphical Abstract
Figure 1: Diarylmethanofullerene derivatives.
Scheme 1: Synthesis of diarylmethanofullerene derivatives.
Figure 2: Device layout of the solar cell.
Figure 3: (A) J–V characteristics of the P3HT:1a-blended device annealed at 100–140 °C (black: 100 °C, red: 1...
Figure 4: (A) Spectral responsivity of the P3HT:1a-blended film on the ITO glass annealed at 100–140 °C (100 ...
Figure 5: The AFM images of the P3HT:1a- and P3HT:PCBM-blended films annealed at different temperatures. (A) ...
