Beilstein J. Org. Chem.2005,1, No. 16, doi:10.1186/1860-5397-1-16
molecular plane. Four of the six methyl groups are directed towards the molecular cavity. They are situated in pairs slightly above and below the cavity due to the crystallographic symmetry. The remaining two methyl groups are exo-oriented along the long molecular axis.
No π-πinteractions occur in the
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Graphical Abstract
Scheme 1:
Formulas of macrocyclic amines, 1: 1,5,9,18,22,26-hexaaza [11.11]-p-cyclophane and 2: 1,4,7,16,19,2...