Beilstein J. Org. Chem.2009,5, No. 6, doi:10.3762/bjoc.5.6
[(1,3-dithiol-2-ylidene)alkyl]ferrocenes (2) was shown to form 1:1 CT complexes with tetracyano-p-quinodimethane (TCNQ, 3) and dichlorodicyanoquinone (DDQ) 4, see Figure 1 [24][25][26]. Subsequently, a number of reports have appeared dealing with the electrochemical properties of these CT complexes of
Beilstein J. Org. Chem.2007,3, No. 2, doi:10.1186/1860-5397-3-2
and α-epoxyketones have also occurred thermally or photochemically by the presence of various electron acceptors. These reactions have been observed thermally by ceric ammonium nitrate (CAN), [28][29] 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) [30] and iron(III) chloride [31] or photo-induced
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Graphical Abstract
Scheme 1:
Ultrasound-assisted photocatalytic ring opening of α-epoxyketones.