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Search for "free radical" in Full Text gives 152 result(s) in Beilstein Journal of Organic Chemistry.

Effect of transannular interaction on the redox- potentials in a series of bicyclic quinones

  • Grigoriy Sereda,
  • Jesse Van Heukelom,
  • Miles Koppang,
  • Sudha Ramreddy and
  • Nicole Collins

Beilstein J. Org. Chem. 2006, 2, No. 26, doi:10.1186/1860-5397-2-26

Graphical Abstract
  • to the free radical redox-processes, involving triptycene-quinones and reactive oxygen species [2]. Better understanding of the transannular influence of a substituent on the redox-potentials of bicyclo[2.2.2]octane-derived quinones will help in the design of new compounds with controlled biological
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Full Research Paper
Published 08 Dec 2006

The Elbs and Boyland- Sims peroxydisulfate oxidations

  • E. J. Behrman

Beilstein J. Org. Chem. 2006, 2, No. 22, doi:10.1186/1860-5397-2-22

Graphical Abstract
  • solvent. The sulfate ester remains in the aqueous phase. Hydrolysis of the sulfate ester in aqueous acid produces the (usually) organic-soluble dihydric phenol. Reactions are usually run at room temperature or below to reduce the incursion of free radical reactions. The rates are rather slow with typical
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Review
Published 07 Nov 2006
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