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Search for "supramolecular chemistry" in Full Text gives 212 result(s) in Beilstein Journal of Organic Chemistry. Showing first 200.

Multivalent polyglycerol supported imidazolidin-4-one organocatalysts for enantioselective Friedel–Crafts alkylations

  • Tommaso Pecchioli,
  • Manoj Kumar Muthyala,
  • Rainer Haag and
  • Mathias Christmann

Beilstein J. Org. Chem. 2015, 11, 730–738, doi:10.3762/bjoc.11.83

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  • and biochemistry [2] to supramolecular chemistry [3][4] and materials sciences [5]. However, applications in catalysis are still limited [6][7][8]. Recently, the use of polymeric support has stimulated the development of multivalent architectures for catalytic applications [9]. In general, both linear
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Published 12 May 2015

Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting

  • Christian Benkhäuser and
  • Arne Lützen

Beilstein J. Org. Chem. 2015, 11, 693–700, doi:10.3762/bjoc.11.79

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  • social self-sorting manner as evidenced by NMR spectroscopy and mass spectrometry. Keywords: metal complexes; multivalency; self-assembly; self-sorting; supramolecular chemistry; Tröger's base; Introduction Self-assembly of defined aggregates from multicomponent mixtures through self-sorting effects
  • has become an important issue in supramolecular chemistry [1][2][3][4][5]. Such self-sorting can either occur in a social self-discriminating or a narcissistic self-recognition manner (Scheme 1). In general, geometrical size and shape complementarity are used to ensure high-fidelity self-sorting. This
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Published 08 May 2015

TTFs nonsymmetrically fused with alkylthiophenic moieties

  • Rafaela A. L. Silva,
  • Bruno J. C. Vieira,
  • Marta M. Andrade,
  • Isabel C. Santos,
  • Sandra Rabaça,
  • Dulce Belo and
  • Manuel Almeida

Beilstein J. Org. Chem. 2015, 11, 628–637, doi:10.3762/bjoc.11.71

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  • ; supramolecular chemistry; tetrathiafulvalene (TTF); thiophene; Introduction Since the discovery of the first organic metals and superconductors the field of electronic molecular materials has been largely dominated by derivatives of the organic donor tetrathiafulvalene (TTF) [1]. More than one thousand TTF
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Published 05 May 2015

Bis(vinylenedithio)tetrathiafulvalene analogues of BEDT-TTF

  • Erdal Ertas,
  • İlknur Demirtas and
  • Turan Ozturk

Beilstein J. Org. Chem. 2015, 11, 403–415, doi:10.3762/bjoc.11.46

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  • chemistry, materials chemistry, supramolecular chemistry and polymer chemistry. 1,8-Diketones have been demonstrated to be versatile starting materials for the synthesis of various challenging analogues of ET, possessing dithiin and thiophene moieties. This chemistry not only led to the production of the
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Published 27 Mar 2015

Efficient deprotection of F-BODIPY derivatives: removal of BF2 using Brønsted acids

  • Mingfeng Yu,
  • Joseph K.-H. Wong,
  • Cyril Tang,
  • Peter Turner,
  • Matthew H. Todd and
  • Peter J. Rutledge

Beilstein J. Org. Chem. 2015, 11, 37–41, doi:10.3762/bjoc.11.6

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  • facilitate chromatographic purification. The parent dipyrrins are more difficult to handle but have a range of potential applications in dye and porphyrin syntheses, metal ion coordination and supramolecular chemistry [12]. Methods to enable the functionalization of dipyrrins by temporarily complexing with
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Published 09 Jan 2015

Inclusion of trans-resveratrol in methylated cyclodextrins: synthesis and solid-state structures

  • Lee Trollope,
  • Dyanne L. Cruickshank,
  • Terence Noonan,
  • Susan A. Bourne,
  • Milena Sorrenti,
  • Laura Catenacci and
  • Mino R. Caira

Beilstein J. Org. Chem. 2014, 10, 3136–3151, doi:10.3762/bjoc.10.331

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  • Lee Trollope Dyanne L. Cruickshank Terence Noonan Susan A. Bourne Milena Sorrenti Laura Catenacci Mino R. Caira Centre for Supramolecular Chemistry Research (CSCR), Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa Department of Drug Sciences, University of Pavia, Via
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Published 29 Dec 2014

Self-assembled monolayers of shape-persistent macrocycles on graphite: interior design and conformational polymorphism

  • Joscha Vollmeyer,
  • Friederike Eberhagen,
  • Sigurd Höger and
  • Stefan-S. Jester

Beilstein J. Org. Chem. 2014, 10, 2774–2782, doi:10.3762/bjoc.10.294

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  • ; solid/liquid interface; supramolecular surface patterning; template; Introduction One of the ultimate aims in supramolecular chemistry on solid surfaces is the formation of two-dimensional (2D) nanostructures that are capable of performing highly specific tasks as an effect of functional units that are
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Published 26 Nov 2014

Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids

  • Roman Matthessen,
  • Jan Fransaer,
  • Koen Binnemans and
  • Dirk E. De Vos

Beilstein J. Org. Chem. 2014, 10, 2484–2500, doi:10.3762/bjoc.10.260

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  • are grateful to KU Leuven for support through the Methusalem grant CASAS, in the frame of IAP 7 Supramolecular Chemistry and Catalysis.
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Published 27 Oct 2014

Molecular recognition of AT-DNA sequences by the induced CD pattern of dibenzotetraaza[14]annulene (DBTAA)–adenine derivatives

  • Marijana Radić Stojković,
  • Marko Škugor,
  • Łukasz Dudek,
  • Jarosław Grolik,
  • Julita Eilmes and
  • Ivo Piantanida

Beilstein J. Org. Chem. 2014, 10, 2175–2185, doi:10.3762/bjoc.10.225

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  • /RNA sites [2][3], frequently relying upon new knowledge gained from supramolecular chemistry [4]. Among the large number of DNA/RNA sequences of biochemical interest, long homogeneous AT tracts have attracted significant attention as small molecule targets. An illustrative natural example can be found
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Published 12 Sep 2014

Macrocyclic bis(ureas) as ligands for anion complexation

  • Claudia Kretschmer,
  • Gertrud Dittmann and
  • Johannes Beck

Beilstein J. Org. Chem. 2014, 10, 1834–1839, doi:10.3762/bjoc.10.193

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  • rather weak complexing agent, the large ring of 2 binds anions with association constants up to log K = 7.93 for chloride ions. Keywords: anion binding; macrocyclic compounds; NMR spectra; supramolecular chemistry; template; urea; Introduction Supramolecular chemistry – the “chemistry beyond the
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Published 12 Aug 2014

Influence of perylenediimide–pyrene supramolecular interactions on the stability of DNA-based hybrids: Importance of electrostatic complementarity

  • Christian B. Winiger,
  • Simon M. Langenegger,
  • Oleg Khorev and
  • Robert Häner

Beilstein J. Org. Chem. 2014, 10, 1589–1595, doi:10.3762/bjoc.10.164

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  • well as van der Waals, electrostatic and charge transfer interactions that can lead to a thermodynamically favourable association [8]. It is an important interaction in biological systems, drug receptor interactions, materials sciences, and supramolecular chemistry [8][9][10][11][12]. Such interactions
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Published 11 Jul 2014

Molecular recognition of surface-immobilized carbohydrates by a synthetic lectin

  • Melanie Rauschenberg,
  • Eva-Corrina Fritz,
  • Christian Schulz,
  • Tobias Kaufmann and
  • Bart Jan Ravoo

Beilstein J. Org. Chem. 2014, 10, 1354–1364, doi:10.3762/bjoc.10.138

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  • as drugs in various therapies and as recognition units in diagnostics and sensing. However, the development of synthetic lectins poses a phenomenal challenge for supramolecular chemistry [37] because a carbohydrate receptor in order to be useful must not only compete with the strong hydration of
  • (SFB 858). This work was supported by COST CM1005 “Supramolecular Chemistry in Water”.
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Published 16 Jun 2014

Homochiral BINOL-based macrocycles with π-electron-rich, electron-withdrawing or extended spacing units as receptors for C60

  • Marco Caricato,
  • Silvia Díez González,
  • Idoia Arandia Ariño and
  • Dario Pasini

Beilstein J. Org. Chem. 2014, 10, 1308–1316, doi:10.3762/bjoc.10.132

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  • ; supramolecular chemistry; Introduction Shape persistent macrocycles are carbon-based nanomaterials and are more and more in demand. They enrich the molecular toolkit available to a variety of disciplines, e.g., supramolecular chemistry and materials science [1][2][3][4]. Shape persistency properties are
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Published 06 Jun 2014

Substitution effect and effect of axle’s flexibility at (pseudo-)rotaxanes

  • Friedrich Malberg,
  • Jan Gerit Brandenburg,
  • Werner Reckien,
  • Oldamur Hollóczki,
  • Stefan Grimme and
  • Barbara Kirchner

Beilstein J. Org. Chem. 2014, 10, 1299–1307, doi:10.3762/bjoc.10.131

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  • binding is weakened by approximately 10 kcal/mol, and hydrogen bonds are slightly shortened (by up to 0.2 Å). Keywords: dispersion interaction; hydrogen bond; supramolecular chemistry; template; theoretical chemistry; Introduction Rotaxanes are prototypes for molecular machines and molecular switches [1
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Published 05 Jun 2014

Synthesis, characterization and DNA interaction studies of new triptycene derivatives

  • Sourav Chakraborty,
  • Snehasish Mondal,
  • Rina Kumari,
  • Sourav Bhowmick,
  • Prolay Das and
  • Neeladri Das

Beilstein J. Org. Chem. 2014, 10, 1290–1298, doi:10.3762/bjoc.10.130

Graphical Abstract
  • organic molecules having terminal ethynyl functional groups are very useful synthons for the design of interesting materials in polymer and supramolecular chemistry [20][21][22][23][24][25]. Herein we report, the syntheses of 2,6,14- and 2,7,14-triazido and 2,6,14- and 2,7,14-triethynyl substituted
  • interaction of triptycene derivatives with DNA in more detail, and the use of triptycene derivatives as building blocks in supramolecular chemistry. Experimental Methods of preparation of compounds 1–8 and their characterization data are given in Supporting Information File 1. Biological studies General
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Published 05 Jun 2014

The influence of intraannular templates on the liquid crystallinity of shape-persistent macrocycles

  • Joscha Vollmeyer,
  • Ute Baumeister and
  • Sigurd Höger

Beilstein J. Org. Chem. 2014, 10, 910–920, doi:10.3762/bjoc.10.89

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  • planar. Keywords: discotic liquid crystals; shape-persistent macrocycles; templates; X-ray scattering; Introduction The supramolecular chemistry of shape-persistent macrocycles has enormously expanded during the past several years [1][2][3][4][5][6]. It covers the non-covalent interaction between the
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Published 23 Apr 2014

Molecular recognition of isomeric protonated amino acid esters monitored by ESI-mass spectrometry

  • Andrea Liesenfeld and
  • Arne Lützen

Beilstein J. Org. Chem. 2014, 10, 825–831, doi:10.3762/bjoc.10.78

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  • . However, mass spectrometry has become a major analytical tool in supramolecular chemistry in recent years [19][20][21] and seemed to be perfectly suited in this case, since we were planning to recognise the amino acid derivatives in form of their protonated alkyl esters anyway. Thus, the host–guest
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Published 09 Apr 2014

Towards allosteric receptors – synthesis of β-cyclodextrin-functionalised 2,2’-bipyridines and their metal complexes

  • Christopher Kremer,
  • Gregor Schnakenburg and
  • Arne Lützen

Beilstein J. Org. Chem. 2014, 10, 814–824, doi:10.3762/bjoc.10.77

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  • bringing together or separating the cyclodextrin moieties from each other. Keywords: allosteric receptors; 2,2’-bipyridines; β-cyclodextrin; supramolecular chemistry; metal complexes; Introduction In biological systems, recognition events play a major role to guarantee the selectivity of essential
  • ) or hampering (negative allosteric cooperativity) the binding of another substrate at a second binding site. This powerful regulatory concept has become quite interesting in supramolecular chemistry, and the development of artificial receptor systems which can be controlled by allosteric effects comes
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Published 09 Apr 2014
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  • functionalization is supported by 1H NMR-, SEC-, FTIR- and MALDI–TOF measurements. Keywords: chain-transfer polymerization; cyclodextrins; end-group functionalization; host–guest interaction; lower critical solution temperature (LCST); poly(N,N-diethylacrylamide); Introduction Supramolecular chemistry was first
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Published 19 Mar 2014

Self-assembly of metallosupramolecular rhombi from chiral concave 9,9’-spirobifluorene-derived bis(pyridine) ligands

  • Rainer Hovorka,
  • Sophie Hytteballe,
  • Torsten Piehler,
  • Georg Meyer-Eppler,
  • Filip Topić,
  • Kari Rissanen,
  • Marianne Engeser and
  • Arne Lützen

Beilstein J. Org. Chem. 2014, 10, 432–441, doi:10.3762/bjoc.10.40

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  • . Keywords: concave templates; metal complexes; self-assembly; self-sorting; 9,9’-spirobifluorene; supramolecular chemistry; Introduction Concave templates are versatile tools to achieve self-sorting behaviour in the self-assembly of defined aggregates from multicomponent mixtures in a social self
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Published 18 Feb 2014

Continuous-flow Heck synthesis of 4-methoxybiphenyl and methyl 4-methoxycinnamate in supercritical carbon dioxide expanded solvent solutions

  • Phei Li Lau,
  • Ray W. K. Allen and
  • Peter Styring

Beilstein J. Org. Chem. 2013, 9, 2886–2897, doi:10.3762/bjoc.9.325

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  • these cross-coupling methods has undoubtedly revolutionalised the protocols for the construction of natural products, building blocks for supramolecular chemistry, self-assembly of organic materials and polymers, and lead compounds in medicinal chemistry from simpler entities [1]. These include the
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Published 17 Dec 2013

Charge-transfer interaction mediated organogels from 18β-glycyrrhetinic acid appended pyrene

  • Jun Hu,
  • Jindan Wu,
  • Qian Wang and
  • Yong Ju

Beilstein J. Org. Chem. 2013, 9, 2877–2885, doi:10.3762/bjoc.9.324

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  • ; Introduction The creation of one-dimensional (1D) nanostructures is one of the focused fields in supramolecular chemistry [1][2][3][4]. In order to control the molecular arrangement in 1D structures, low molecular weight gelators (LMWGs) have generated considerable interest during the past decade [5][6]. The
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Published 16 Dec 2013

Novel supramolecular affinity materials based on (−)-isosteviol as molecular templates

  • Christina Lohoelter,
  • Malte Brutschy,
  • Daniel Lubczyk and
  • Siegfried R. Waldvogel

Beilstein J. Org. Chem. 2013, 9, 2821–2833, doi:10.3762/bjoc.9.317

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  • particular as templates for tracing air-borne arenes at low concentration. The affinities of the synthesized materials towards different air-borne arenes were determined by 200 MHz quartz crystal microbalances. Keywords: affinity materials; (−)-Isosteviol; supramolecular chemistry; triphenylene ketals
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Published 09 Dec 2013

Synthesis of enantiopure sugar-decorated six-armed triptycene derivatives

  • Paola Bonaccorsi,
  • Maria Luisa Di Gioia,
  • Antonella Leggio,
  • Lucio Minuti,
  • Teresa Papalia,
  • Carlo Siciliano,
  • Andrea Temperini and
  • Anna Barattucci

Beilstein J. Org. Chem. 2013, 9, 2410–2416, doi:10.3762/bjoc.9.278

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  • geometric features of its skeleton with a D3h symmetry have attracted a lot of attention and its derivatives have been used for applications in supramolecular chemistry, material chemistry, and as molecular machines [1][2]. The interest in this three-dimensional rigid platform is also due to the easy
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Published 08 Nov 2013

Structure elucidation of β-cyclodextrin–xylazine complex by a combination of quantitative 1H–1H ROESY and molecular dynamics studies

  • Syed Mashhood Ali,
  • Kehkeshan Fatma and
  • Snehal Dhokale

Beilstein J. Org. Chem. 2013, 9, 1917–1924, doi:10.3762/bjoc.9.226

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  • ; Introduction The emergence and establishment of supramolecular chemistry as an important domain of science has fueled the development of complex chemical systems from components, interacting by non-covalent intermolecular forces. This field transcends the traditional barriers separating many disciplines of
  • science and is the basis for most of the vital biological processes [1]. The basis of supramolecular chemistry is molecular recognition where host and guest species interact with each other and exist as a single system. These host–guest systems symbolize simplest examples of supramolecular systems in
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Published 23 Sep 2013
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