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Search for "Müller hydrocarbon" in Full Text gives 1 result(s) in Beilstein Journal of Organic Chemistry.

On the photoluminescence in triarylmethyl-centered mono-, di-, and multiradicals

Daniel Straub,
Markus Gross,
Mona E. Arnold,
Julia Zolg and
Alexander J. C. Kuehne

Beilstein J. Org. Chem. 2025, 21, 964–998, doi:10.3762/bjoc.21.80

unresolved questions that must be addressed to unlock the full potential of trityl-based radicals in advanced technological applications. Keywords: Chichibabin hydrocarbon; COF; Gomberg radical; MOF; Müller hydrocarbon; Thiele hydrocarbon; Introduction Gomberg-type, triarylmethyl-centered radicals

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Figure 1: a) Tris(trichlorophenyl)methyl (TTM) radical and related trityl radicals, b) HDMO, SOMO, LUMO orbit...

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Figure 2: Mixed halide tri- and perhalogenated triphenylmethyl radicals: a) Molecular structures of homo- and...

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Figure 3: Pyridine-functionalized triarylmethyl radicals. a) Chemical structures of X₂PyBTM, Py₂MTM, and Au-F₂...

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Figure 4: Pyridine-functionalized triarylmethyl radicals. a) Molecular structure of Mes₂F₂PyBTM, and b) its f...

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Figure 5: Carbazole functionalized triarylmethyl radical. a) Chemical structure of Cz-BTM and b) its energy d...

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Figure 6: Donor-functionalized triphenylmethyl radicals. Molecular structures of TTM-Cz, DTM-Cz, TTM-3PCz, PT...

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Figure 7: Tuning of the donor strength. Functionalization with electron-donating and electron-withdrawing gro...

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Figure 8: Tuning of the donor strength, by varying the Cz-derived donor (1–36) on a TTM radical fragment. a) ...

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Figure 9: Three-state model and Marcus theory: q is the charge transfer coordinate and G the free energy. Gro...

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Figure 10: Dendronized carbazole donors on TTM radicals. a) Molecular structures of G3TTM and G4TTM. b) Photol...

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Figure 11: Electronic extension of the Cz donor. a) Molecular structures and optoelectronic properties of TTM-...

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Figure 12: Kekulé diradicals: a) hexadeca- and perchlorinated Thiele (TTH, PTH), Chichibabin (TTM-TTM, PTM-PTM...

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Figure 13: Non-Kekulé diradicals: perchlorinated Schlenk–Brauns radical (m-PTH), meta-coupled TTM radicals in ...

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Figure 14: UV–vis absorption and photoluminescence spectra of a) TTH in solvents of different polarity, b) dir...

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Figure 15: Molecular structures of m-4BTH (meta-butylated Thiele hydrocarbon), m-4TTH (meta-trichlorinated Thi...

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Figure 16: a) Polystyrene-based TTM-Cz polymer. b) Molecular structure of radical particles with backbone thro...

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Figure 17: Molecular structures of polyradicals. a) Molecular structures of p-TBr₆Cl₃M-F8, p-TBr₆Cl₃M-acF8 and ...

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Figure 18: Structures of coordination and metal-organic frameworks. a) Carboxylic acid functionalized monomers...

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Figure 19: Structures of coordination and metal-organic frameworks. a) Molecular structures of monomers TTMDI, ...

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Figure 20: Molecular structures of covalent organic frameworks m-TPM-Ph-COF, m-PTM-Ph-COF, p-TPH-COF, p-PTH-COF...

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Figure 21: Molecular structures of covalent organic frameworks PTMAc-COF, oxTAMAc-COF, TOTAc-COF, PTMTAz-COF, p...

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Published 21 May 2025

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