Microwave-enhanced additive-free C–H amination of benzoxazoles catalysed by supported copper

• Andrei Paraschiv,
• Valentina Maruzzo,
• Filippo Pettazzi,
• Stefano Magliocco,
• Paolo Inaudi,
• Daria Brambilla,
• Gloria Berlier,
• Giancarlo Cravotto and
• Katia Martina

Beilstein J. Org. Chem. 2025, 21, 1462–1476, doi:10.3762/bjoc.21.108

• classical Buchwald–Hartwig amination reaction [16] or the Ullman reaction [17][18]) which require pre-functionalisation steps and harsh conditions [19]. Many protocols for C–H aminations have been applied to heteroaromatic compounds, mainly 5-membered heteroarenes, and a great deal of attention has been

Total synthesis of ochnaflavone

• Monica M. Ndoile and
• Fanie R. van Heerden

Beilstein J. Org. Chem. 2013, 9, 1346–1351, doi:10.3762/bjoc.9.152

• ]. The Ullman reaction is often used to prepare diaryl ethers, but this reaction has the disadvantages of high reaction temperatures and intolerance to a wide variety of functional groups, with the major weakness being the inconsistency in the products obtained by the use of different copper sources [22

A convenient method for preparing rigid-core ionic liquid crystals

• Julien Fouchet,
• Laurent Douce,
• Benoît Heinrich,
• Richard Welter and
• Alain Louati

Beilstein J. Org. Chem. 2009, 5, No. 51, doi:10.3762/bjoc.5.51

• , differential scanning calorimetry and X-ray diffraction. In addition its lamellar crystal structure, electrochemical behaviour and UV (absorption and emission) properties are reported. Keywords: imidazolium; ionic liquid crystals; Ullman reaction; Introduction Over the past decade extensive studies of ionic