Beilstein J. Org. Chem.2025,21, 2456–2464, doi:10.3762/bjoc.21.187
equilibrium lie outside the carbohydrate ring system. Consideration of such effects is essential to rationalize the reactivity of structurally complex and densely protected carbohydrate compounds.
Keywords: benzoylatedgalactofuranosides; DFT; DLPNO-CCSD(T); pyranoside-into-furanoside rearrangement
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Graphical Abstract
Figure 1:
Isomerization of pyranoside and furanoside forms of unprotected ᴅ-galactose in an aqueous solution.