Spin and charge interactions between nanographene host and ferrocene

• Akira Suzuki,
• Yuya Miyake,
• Ryoga Shibata and
• Kazuyuki Takai

Beilstein J. Org. Chem. 2024, 20, 1011–1019, doi:10.3762/bjoc.20.89

• diamagnetic molecule (S = 0, no spin magnetism) compared with other metallocenes [17]. However, FeCp2 is easily oxidized to a monovalent cation, the electronic structure of which is magnetic (S = 1/2). Electron spin resonance (ESR) spectroscopy revealed the spin magnetism of cationic FeCp2 accommodated in

Solvent-free copper-catalyzed click chemistry for the synthesis of N-heterocyclic hybrids based on quinoline and 1,2,3-triazole

• Martina Tireli,
• Silvija Maračić,
• Stipe Lukin,
• Marina Juribašić Kulcsár,
• Dijana Žilić,
• Mario Cetina,
• Ivan Halasz,
• Silvana Raić-Malić and
• Krunoslav Užarević

Beilstein J. Org. Chem. 2017, 13, 2352–2363, doi:10.3762/bjoc.13.232

• milling CuAAC reaction pathway when using different catalysts. The electronic structure of Cu catalysts after the reaction completion was assayed by electron spin resonance (ESR) spectroscopy. All milling reactions, except the one using copper(0) as catalyst, were compared to solution procedures to

• -free click reactions. Electron spin resonance (ESR) spectroscopy ESR is an ideal technique for validating the oxidation and spin state of copper cations. Elemental copper and copper(I) are ESR silent, whereas the copper(II) shows strong and characteristic lines revealing local properties of this ion

• spin resonance (ESR) spectroscopy; in situ Raman monitoring; mechanochemistry; quinoline; solid-state click chemistry; Introduction The copper-catalyzed azide–alkyne cycloaddition (CuAAC) represents a prime example of click chemistry. Click chemistry describes “a set of near-perfect” reactions [1] for

Kinetic analysis of mechanoradical formation during the mechanolysis of dextran and glycogen

• Naoki Doi,
• Yasushi Sasai,
• Yukinori Yamauchi,
• Tetsuo Adachi,
• Masayuki Kuzuya and
• Shin-ichi Kondo

Beilstein J. Org. Chem. 2017, 13, 1174–1183, doi:10.3762/bjoc.13.116

• of a polymer at a temperature below its glass-transition temperature (Tg) due to the disruption of the polymer main chain [1]. Although most pulverization operations for a practical use are carried out at room temperature, electron spin resonance (ESR) spectroscopy analyses of mechanoradical