Beilstein J. Org. Chem.2024,20, 321–330, doi:10.3762/bjoc.20.32
of the UngA NRPS were analyzed in an attempt to understand the lack of substrate specificity observed.
Keywords: adenylation domain; condensation domain; fungalnon-ribosomalpeptidesynthetase; heptapeptide; unguisin biosynthesis; Introduction
Unguisins are a small family of fungal cyclic