Search results

Search for "metal-driven" in Full Text gives 2 result(s) in Beilstein Journal of Organic Chemistry.

Tailored charge-neutral self-assembled L2Zn2 container for taming oxalate

  • David Ocklenburg and
  • David Van Craen

Beilstein J. Org. Chem. 2024, 20, 3007–3015, doi:10.3762/bjoc.20.250

Graphical Abstract
  • ready receptor preparation by metal complexation. The reason for the underrepresentation is the competitive nature and excellent ligand properties of oxalate which not only is associated with the aforementioned diseases but also poses a serious hazard for metal-driven self-assemblies because the dianion
  • metallocontainers which are formed by metal-driven self-assembly have become especially popular to bind various kinds of anions since such systems offer easy to tune confinements. Usually, the utilized complexes are net positive which makes them ideal hosts for anions [56][57][58][59][60][61][62][63]. However, the
  • positively charged or charge-neutral, is their metal-driven self-assembly. Unfortunately, this can also be their Achilles' heel, as the underlying coordination bonds are fragile compared to covalent bonds. For example, metallocages can easily break apart by the addition of competitive anions which are highly
PDF
Album
Supp Info
Full Research Paper
Published 18 Nov 2024

Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring

  • Sébastien Bivaud,
  • Sébastien Goeb,
  • Vincent Croué,
  • Magali Allain,
  • Flavia Pop and
  • Marc Sallé

Beilstein J. Org. Chem. 2015, 11, 966–971, doi:10.3762/bjoc.11.108

Graphical Abstract
  • allows for modulating the size and the shape of the resulting discrete self-assembly, which therefore incorporate two (M4L2) or three (M6L3) electroactive exTTF sidewalls. Keywords: coordination; metal-driven; redox; self-assembly; tetrathiafulvalene; Findings The coordination-driven approach is a well
PDF
Album
Supp Info
Letter
Published 05 Jun 2015
Other Beilstein-Institut Open Science Activities