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Search for "organo phosphorus" in Full Text gives 2 result(s) in Beilstein Journal of Organic Chemistry.

Recent advances in the electrochemical synthesis of organophosphorus compounds

Babak Kaboudin,
Milad Behroozi,
Sepideh Sadighi and
Fatemeh Asgharzadeh

Beilstein J. Org. Chem. 2025, 21, 770–797, doi:10.3762/bjoc.21.61

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Graphical Abstract

Scheme 1: Electrosynthesis of phenanthridine phosphine oxides.

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Scheme 2: Electrosynthesis of 1-aminoalkylphosphine oxides.

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Scheme 3: Various electrochemical C–P coupling reactions.

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Scheme 4: Electrochemical C–P coupling reaction of indolines.

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Scheme 5: Electrochemical C–P coupling reaction of ferrocene.

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Scheme 6: Electrochemical C–P coupling reaction of acridines with phosphites.

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Scheme 7: Electrochemical C–P coupling reaction of alkenes.

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Scheme 8: Electrochemical C–P coupling reaction of arenes in a flow system.

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Scheme 9: Electrochemical C–P coupling reaction of heteroarenes.

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Scheme 10: Electrochemical C–P coupling reaction of thiazoles.

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Scheme 11: Electrochemical C–P coupling reaction of indole derivatives.

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Scheme 12: Electrosynthesis of 1-amino phosphonates.

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Scheme 13: Electrochemical C–P coupling reaction of aryl and vinyl bromides.

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Scheme 14: Electrochemical C–P coupling reaction of phenylpyridine with dialkyl phosphonates in the presence o...

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Scheme 15: Electrochemical P–C bond formation of amides.

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Scheme 16: Electrochemical synthesis of α-hydroxy phosphine oxides.

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Scheme 17: Electrochemical synthesis of π-conjugated phosphonium salts.

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Scheme 18: Electrochemical phosphorylation of indoles.

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Scheme 19: Electrochemical synthesis of phosphorylated propargyl alcohols.

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Scheme 20: Electrochemical synthesis of phosphoramidates.

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Scheme 21: Electrochemical reaction of carbazole with diphenylphosphine.

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Scheme 22: Electrochemical P–N coupling of carbazole with phosphine oxides.

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Scheme 23: Electrochemical P–N coupling of indoles with a trialkyl phosphite.

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Scheme 24: Electrochemical synthesis of iminophosphoranes.

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Scheme 25: Electrochemical P–O coupling of phenols with dialkyl phosphonate.

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Scheme 26: Electrochemical P–O coupling of alcohols with diphenylphosphine.

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Scheme 27: Electrochemical P–S coupling of thiols with dialkylphosphines.

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Scheme 28: Electrochemical thiophosphorylation of indolizines.

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Scheme 29: Electrosynthesis of S-heteroaryl phosphorothioates.

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Scheme 30: Electrochemical phosphorylation reactions.

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Scheme 31: Electrochemical P–Se formation.

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Scheme 32: Electrochemical selenation/halogenation of alkynyl phosphonates.

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Scheme 33: Electrochemical enantioselective aryl C–H bond activation.

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Review

Published 16 Apr 2025

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Relay cross metathesis reactions of vinylphosphonates

Raj K. Malla,
Jeremy N. Ridenour and
Christopher D. Spilling

Beilstein J. Org. Chem. 2014, 10, 1933–1941, doi:10.3762/bjoc.10.201

reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism. Keywords: centrolobine; metathesis; organo

phosphorus; relay; vinyl phosphonate; Introduction Over the last two decades, we have developed reactions for the formation of chiral non-racemic γ-substituted vinylphosphonates [1][2][3][4][5][6][7][8][9]. In particular, carbonate derivatives 1 (phosphono allylic carbonates) of allylic hydroxy phosphonates

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