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Search for "oxidative C–C coupling" in Full Text gives 2 result(s) in Beilstein Journal of Organic Chemistry.

Strategies in the synthesis of dibenzo[b,f]heteropines

  • David I. H. Maier,
  • Barend C. B. Bezuidenhoudt and
  • Charlene Marais

Beilstein J. Org. Chem. 2023, 19, 700–718, doi:10.3762/bjoc.19.51

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  • % yield via a gold/silver catalyst system (Scheme 27). 4 Oxidative CC coupling Whereas oxidative CC coupling precedes amination in the industrial route to 5H-dibenzo[b,f]azepine, oxidative CC coupling may also be the final step in the construction of the dibenzo[b,f]heteropine skeleton. Comber and
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Published 22 May 2023

Synthesis of functionalized diazocines for application as building blocks in photo- and mechanoresponsive materials

  • Widukind Moormann,
  • Daniel Langbehn and
  • Rainer Herges

Beilstein J. Org. Chem. 2019, 15, 727–732, doi:10.3762/bjoc.15.68

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  • oxidative CC coupling of 2-nitrotoluenes (75–82% yield) and a reductive ring closure to form the diazocines (56–60% yield). The cyclization of the dinitro compound to the azo compound was improved in yield and reproducibility, by over-reduction to the hydrazine and reoxidation to the azo unit. In contrast
  • molecular switches in photo and mechanoresponsive macromolecules and other smart materials. Keywords: bridged azobenzene; diazocine; mechanophor; oxidative CC coupling; photochrome; reductive azo cyclization; Introduction The field of photoresponsive materials is of growing interest [1][2][3]. Several
  • step the hydroxy groups in 8a and 8b were protected as tert-butyl ethers (Scheme 2) to prevent oxidation in the following oxidative CC coupling [31]. The tert-butyl ether was chosen as the protecting group because it is stable towards the oxidizing conditions of the C–C coupling reactions and the
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Published 20 Mar 2019
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