Upcycling agroindustrial waste into graphene oxide supports for gold nanoparticles: toward sustainable nanomaterials

• Juan Marcos Castro-Tapia,
• Selene Acosta,
• Hiram Joazet Ojeda-Galván,
• Elsie Evelyn Araujo-Palomo,
• Edgar Giovanni Villabona-Leal and
• Mildred Quintana

Beilstein J. Nanotechnol. 2026, 17, 489–504, doi:10.3762/bjnano.17.32

• , ozone-free emission in the 310–450 nm range, λmax = 360 nm) for 60 min under continuous stirring. A purple dispersion was obtained, confirming the formation of AuNPs. Characterization techniques The optical properties of the samples were analyzed by ultraviolet–visible (UV–vis) spectroscopy with a Cary

• , with an acquisition time of 30 s and two accumulations, yielding a spectral resolution of 0.8 cm−1 per pixel. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy was performed using a Nicolet Nexus 470 FTIR spectrometer (Nicolet, Madison, WI, USA). Spectra were collected at

• room temperature in the 4000–540 cm−1 range with a spectral resolution of 4 cm−1, averaging 80 scans per sample. The surface chemical composition was assessed by X-ray photoelectron spectroscopy (XPS) using a SPECS spectrometer equipped with a PHOIBOS 100 energy analyzer and an Al Kα X-ray source (hν

Defects and defect-mediated engineering of two-dimensional materials: challenges and open questions

• Arkady V. Krasheninnikov,
• Matthias Batzill,
• Anouar-Akacha Delenda,
• Marija Drndić,
• Chris Ewels,
• Katharina J. Franke,
• Mahdi Ghorbani-Asl,
• Alexander Holleitner,
• Ado Jorio,
• Ute Kaiser,
• Daria Kieczka,
• Hannu-Pekka Komsa,
• Jani Kotakoski,
• Manuel Längle,
• David Lamprecht,
• Yun Liu,
• Steven G. Louie,
• Janina Maultzsch,
• Thomas Michely,
• Katherine Milton,
• Anna Niggas,
• Hanako Okuno,
• Joshua A. Robinson,
• Marika Schleberger,
• Bruno Schuler,
• Alexander Shluger,
• Kazu Suenaga,
• Kristian S. Thygesen,
• Richard A. Wilhelm,
• E. Harriet Åhlgren and
• Carla Bittencourt

Beilstein J. Nanotechnol. 2026, 17, 454–488, doi:10.3762/bjnano.17.31

• spectroscopy has led to metrological procedures to access defect concentration in graphene. Well-established formulae are available to determine defect quantity based on the D/G ratio and the linewidth of the G band (see Figure 2) [86][87][88][89]. In a wider context, while Raman-active local vibrational modes

• been computationally prohibitively costly, but modern machine learning models have enabled such simulations for non-resonant Raman experiments. Therefore, the great challenge is the development of higher-precision measurements utilizing nano-Raman spectroscopy (see Figure 3). When nano-Raman is

• implemented in the tip-enhanced Raman spectroscopy (TERS) configuration, the well-established D/G ratio depends on the TERS tip enhancement [95] and whether the distance among defects is larger or smaller than the tip apex size [96][97]. As shown in Figure 3, the D/G ratio exhibits three different tendencies

Eco-efficient materials for agricultural crops based on a mineral rich in MOR- and HEU-type zeolites

• Esperanza Yamile de la Nuez-Pantoja,
• Inocente Rodríguez-Iznaga,
• Gerardo Rodríguez-Fuentes,
• Vitalii Petranovskii,
• Ariel Martínez García,
• José Juan Calvino Gámez and
• Daniel Goma Jiménez

Beilstein J. Nanotechnol. 2026, 17, 381–395, doi:10.3762/bjnano.17.26

• urea arranged on the surface so that it covers the material and interacts with the zeolitic frameworks, was evidenced by Fourier-transform IR spectroscopy, adsorption measurements, scanning electron microscopy, scanning transmission electron microscopy, and other methods, as well as through culture

• ) and other elements (Si) important for agricultural crops. Particular attention was paid to the analysis of the interaction of nitrogen and phosphorus species on this complex multiphase zeolitic carrier, applying Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron

• exchanged in both zeolite phases, and urea arranged as a layer that covers the material and interacts with the zeolitic frameworks were confirmed by using FTIR spectroscopy, XRD, nitrogen adsorption measurements, SEM, STEM and other research methods, as well as culture tests. The complexity of the zeolitic

Interconnection morphology effects on the radio frequency response of carbon nanotube sponges

• Manuela Scarselli,
• Javad Rezvani,
• Zeno Zuccari,
• Mattia Scagliotti and
• Simone Tocci

Beilstein J. Nanotechnol. 2026, 17, 343–351, doi:10.3762/bjnano.17.23

• . In particular, we observed that the response of S11 = −22.6 dB around 4.8 GHz from the CNS antenna improved after a mild treatment with ethanol, reaching S11 = −32.6 dB measured after 10 min of waiting. This observed effect is studied in detail with scanning electron microscopy and Raman spectroscopy

• treatment. We also investigated the chemical state of the carbon atoms by acquiring X-ray photoelectron spectroscopy (XPS) spectra from the as-grown and ethanol-treated CNS samples. The survey spectra are reported in Supporting Information File 1 (Figure S2). Figure 5 shows that the C1 s spectra are

Beam shaping techniques for pulsed laser ablation in liquids: Unlocking tunable control of nanoparticle synthesis in liquids

• Sergio Molina-Prados,
• Nadezhda M. Bulgakova,
• Alexander V. Bulgakov,
• Jesus Lancis,
• Gladys Mínguez Vega and
• Carlos Doñate-Buendia

Beilstein J. Nanotechnol. 2026, 17, 309–342, doi:10.3762/bjnano.17.22

• controllability. The latter refers to the ability to fully automate and operate the process under closed-loop control. PLAL lends itself naturally to remote monitoring and automation through computer-controlled lasers, scanning systems, and online spectroscopy [15], although similar automation can also be

• ][77] and colorimetric sensors [78][79], surface-enhanced Raman spectroscopy detection [71][80][81], nanofluids for thermal applications [82][83][84], additive manufacturing [85][86][87], or catalysis [88][89]. The previously mentioned applications of PLAL-derived NPs can be grouped into four major

• inductively coupled plasma-based (ICP) techniques (ICP mass spectrometry or ICP optical emission spectroscopy) and atomic absorption spectroscopy, particularly for metallic targets, as they determine the concentration in a representative colloidal aliquot. Complementary methods include UV–vis spectroscopy

Advancing nanolithography: a comprehensive review of materials for local anodic oxidation with AFM

• Matteo Lorenzoni

Beilstein J. Nanotechnol. 2026, 17, 275–291, doi:10.3762/bjnano.17.19

• due to reduced electronic interactions between layers. Raman spectroscopy and micro-XPS studies confirm these effects, revealing oxygen incorporation patterns and changes in chemical composition. In summary, the versatility in achieving selective oxidation or ablation expands the potential for device

Durable antimicrobial activity of fabrics functionalized with zeolite ion-exchanged nanomaterials against Staphylococcus aureus and Escherichia coli

• Perla Sánchez-López,
• Kendra Ramirez Acosta,
• Sergio Fuentes Moyado,
• Ruben Dario Cadena-Nava and
• Elena Smolentseva

Beilstein J. Nanotechnol. 2026, 17, 262–274, doi:10.3762/bjnano.17.18

• plasma optical emission spectroscopy (ICP-OES). The results confirmed silver, copper, and zinc contents of around 1.0–1.5 atom % [4]. Energy-dispersive X-ray spectroscopy (EDS) analysis performed on the functionalized fabrics in the present work confirmed the presence of silver (1.3 wt %), as well as

Multilayered hyperbolic Au/TiO₂ nanostructures for enhancing the nonlinear response around the epsilon-near-zero point

• Fernando Arturo Araiza-Sixtos,
• Mauricio Gomez-Robles,
• Rafael Salas-Montiel and
• Raúl Rangel-Rojo

Beilstein J. Nanotechnol. 2026, 17, 251–261, doi:10.3762/bjnano.17.17

• layered Ag/TiO2 and determined via spectroscopy that its ENZ point laid within the visible spectrum [7]. Since then, a wide array of layered metal–dielectric configurations have been demonstrated, including silver-based combinations such as Ag/SiO2 [1], Ag/Al2O3 [6], Ag/LiF [8], Ag/TiO2 [9], Ag/Ge [10

Gold nanoparticle-decorated reduced graphene oxide as a highly effective catalyst for the selective α,β-dehydrogenation of N-alkyl-4-piperidones

• Brenda Flore Kenyim,
• Mihir Tzalis,
• Marilyn Kaul,
• Robert Oestreich,
• Aysenur Limon,
• Chancellin Pecheu Nkepdep and
• Christoph Janiak

Beilstein J. Nanotechnol. 2026, 17, 218–238, doi:10.3762/bjnano.17.15

• diffraction (PXRD) (see Supporting Information File 1). An ice-cold solution of sodium borohydride (NaBH4) was added dropwise to an aqueous solution containing KAuCl4 and the sodium salt of SiW9, resulting in the formation of an orange-brown dispersion (Figure 1b). UV–vis spectroscopy revealed the

• the average size of nanoparticles based on X-ray diffraction data. To verify the gold loading in the Au-SiW9/rGO composite, a carefully weighed aliquot was dissolved in a microwave digestion system using conc. HNO3 (70%) and diluted HCl (5%) for atomic absorption spectroscopy (AAS). The measured gold

• functionalities of rGO were investigated by X-ray photoelectron spectroscopy (XPS) in the composite Au-SiW9/rGO. The Au 4f region (Figure 11a) shows two dominant peaks at 84.1 eV (Au 4f7/2) and 87.8 eV (Au 4f5/2), which correspond to metallic Au0, which is the initial catalytically active form in oxidative

Time of flight secondary ion mass spectrometry imaging of contaminant species in chemical vapour deposited graphene on copper

• Barry Brennan,
• Vlad-Petru Veigang-Radulescu,
• Philipp Braeuninger-Weimer,
• Stephan Hofmann and
• Andrew J. Pollard

Beilstein J. Nanotechnol. 2026, 17, 200–213, doi:10.3762/bjnano.17.13

• single crystals [3][20][21][22][23], utilising Raman spectroscopy to confirm the physical structure of the graphene [24][25][26] and X-ray photoelectron spectroscopy (XPS) to confirm the sp2 bonding configuration [27][28]. However, there is typically little consideration given to possible chemical

• of 30 nA were used for sputtering cycles. The interleaved image spectra were acquired using 25 keV Bi3+ ions from a liquid metal ion gun, orientated at 45° to the sample surface. This was operated at an ion current of 0.1 pA, in an interlaced mode with a cycle time of 100 µs, in spectroscopy mode to

• of copper or copper oxide. However, as recent studies have shown through energy-dispersive X-ray spectroscopy mapping [30], there are significant other contaminants detectable on high-purity Cu foils that can influence graphene nucleation and can remain after growth [31]. A more detailed examination

Structure-dependent thermochromism of PAZO thin films: theory and experiment

• Georgi Mateev,
• Dean Dimov,
• Nataliya Berberova-Buhova,
• Nikoleta Kircheva,
• Todor Dudev,
• Ludmila Nikolova,
• Elena Stoykova,
• Keehoon Hong,
• Dimana Nazarova,
• Silvia Angelova and
• Lian Nedelchev

Beilstein J. Nanotechnol. 2026, 17, 186–199, doi:10.3762/bjnano.17.12

• other molecules (the interactions between polymer chains can be considered as major factors in the case of a polymer thin film). Infrared (IR) spectroscopy is a powerful tool for understanding the effects of thermal treatment on polymers that can cause significant changes in their IR spectra, revealing

Development and in vitro evaluation of liposomes and immunoliposomes containing 5-fluorouracil and R-phycoerythrin as a potential phototheranostic system for colorectal cancer

• Raissa Rodrigues Camelo,
• Vivianne Cortez Sombra Vandesmet,
• Octavio Vital Baccallini,
• José de Brito Vieira Neto,
• Thais da Silva Moreira,
• Luzia Kalyne Almeida Moreira Leal,
• Claudia Pessoa,
• Daniel Giuliano Cerri,
• Maria Vitória Lopes Badra Bentley,
• Josimar O. Eloy,
• Ivanildo José da Silva Júnior and
• Raquel Petrilli

Beilstein J. Nanotechnol. 2026, 17, 97–121, doi:10.3762/bjnano.17.7

• from [e.g., n = 507] HSPC-50-R-PE control liposomes and [e.g., n = 788] HSPC-IM-R-PE immunoliposomes, which were obtained from six and eight independent AFM images, respectively. 2.4 Fourier transform infrared spectroscopy Drug–nanoparticle interactions were studied by subjecting the previously

• lyophilized samples to Fourier-transform infrared (FTIR) spectroscopy in an FTIR spectrophotometer (IRTracer-100, Shimazdzu, Japan), with a horizontal attenuated total reflectance accessory. The scan was performed in the range of 500 to 4000 cm−1 [27]. 2.5 Stability study After physicochemical

• protein corona formation under physiological conditions [63]. These findings highlight the importance of surface characterization by AFM in the development and optimization of nanoparticles. 3.4 Fourier-transform infrared spectroscopy assays The FTIR spectra obtained for the formulations showed the

Functional surface engineering for cultural heritage protection: the role of superhydrophobic and superoleophobic coatings – a comprehensive review

• Giuseppe Cesare Lama,
• Marino Lavorgna,
• Letizia Verdolotti,
• Federica Recupido,
• Giovanna Giuliana Buonocore and
• Bharat Bhushan

Beilstein J. Nanotechnol. 2026, 17, 63–96, doi:10.3762/bjnano.17.6

• formulation allows for the creation of thick, durable coatings (up to 80 µm) without sacrificing polymerization efficiency, as confirmed by Raman spectroscopy. Because of its UV-curing capability, the coating forms a hardened, protective layer within just 1–2 min. By incorporating vinylated alkyd oligomers

Reduced graphene oxide paper electrode for lithium-ion cells – towards optimized thermal reduction

• Agata Pawłowska,
• Magdalena Baran,
• Stefan Marynowicz,
• Aleksandra Izabela Banasiak,
• Adrian Racki,
• Adrian Chlanda,
• Tymoteusz Ciuk,
• Marta Wolczko and
• Andrzej Budziak

Beilstein J. Nanotechnol. 2026, 17, 24–37, doi:10.3762/bjnano.17.3

• samples per material, that is, M300, T400, T600, and T800. Raman spectroscopy The structural properties of the rGO paper sheets were studied with Raman spectroscopy (InVia Renishaw spectrometer). The spectra were collected with three accumulations, a 10 s exposure time, and 1% laser power (laser

• functionalities within the rGO paper, Fourier-transform infrared (FTIR) spectroscopy was applied in attenuated total reflectance mode. The equipment involved a Perkin Elmer Frontier FTIR spectrometer. The spectra were obtained in the 520–4000 cm−1 wavenumber range with baseline calibration and normalized (0 to

• 100). XPS X-ray photoelectron spectroscopy was applied to determine the surface concentrations of chemical bonds. The equipment applied was a PHI VersaProbeII Scanning XPS system with monochromatic Al Kα (1486.6 eV) X-rays (100 μm spot focused). High-energy-resolution spectra were obtained with 46.95

Terahertz-range on-chip local oscillator based on Josephson junction arrays for superconducting quantum-limited receivers

• Fedor V. Khan,
• Lyudmila V. Filippenko,
• Andrey B. Ermakov,
• Mikhail Yu. Fominsky and
• Valery P. Koshelets

Beilstein J. Nanotechnol. 2025, 16, 2296–2305, doi:10.3762/bjnano.16.158

• proven itself for many times both in laboratory and in real-life conditions. The terahertz SIS-mixer integrated on the same chip with the LO based on a flux-flow oscillator (FFO) and a receiving antenna [13] was used to study the irradiation of the human body [15], gas spectroscopy [16], and the

• ]. The measurements from the previous section show that this requirement is confidently met. Second, the LO radiation must be sufficiently monochromatic (spectral ratio ≥90%) in order to prevent signal spectra change while down-conversion to IF. Furthermore, for applications in spectroscopy, phase

Improving magnetic properties of Mn- and Zn-doped core–shell iron oxide nanoparticles by tuning their size

• Dounia Louaguef,
• Ghouti Medjahdi,
• Sébastien Diliberto,
• Klaus M. Seemann,
• Thomas Gries,
• Joelle Bizeau,
• Damien Mertz,
• Eric Gaffet and
• Halima Alem

Beilstein J. Nanotechnol. 2025, 16, 2285–2295, doi:10.3762/bjnano.16.157

• least tenfold). The designed core NPs are composed of a Zn0.4Fe2.6O4 core and a MnFe2O4 shell. Their size and morphology were determined by transmission electron microscopy, Fourier-transform infrared spectroscopy was used to investigate their chemical composition. The iron oxide phase was confirmed by

• while expecting good biocompatibility. The use of size-controlled synthesis enables the exploration of size-dependent magnetic properties, while the direct characterization of the core–shell structure using Fourier-transform infrared spectroscopy (FTIR) and high-resolution transmission electron

• on a JEOL JEM-ARM 200F cold-FEG microscope operating at 200 kV and equipped with a spherical aberration probe corrector (Cs). The chemical compositions were determined by energy-dispersive X-ray spectroscopy The elemental maps were recorded on a SDD, Jeol DRY SD 30 GV X-ray spectrometer. NP shapes

Visualizing nanostructures in supramolecular hydrogels: a correlative study using confocal and cryogenic scanning electron microscopy

• Shaun M. Smith,
• Ferdinando Malagreca,
• Jacqueline Hicks,
• Giuseppe Mantovani,
• David B. Amabilino,
• Christopher Parmenter and
• Lluïsa Pérez-García

Beilstein J. Nanotechnol. 2025, 16, 2274–2284, doi:10.3762/bjnano.16.156

• observed upon mixing aqueous and ethanolic solutions, and gelation generally occurred in less than one minute (as judged by vial inversion) to yield the gel materials containing the chosen fluorophore. Photophysical characterization of fluorophore@Gels UV–visible absorption spectroscopy was performed using

• a Cary 5000 UV–visible spectrophotometer (Agilent). Fluorescence spectroscopy and absolute fluorescence quantum yield measurements (given in Supporting Information File 1) were carried out on a FLS 980 spectrometer (Edinburgh Instruments) equipped with a front face sample holder or integrating

Geometry-controlled engineering of the low-temperature proximity effect in normal metal–superconductor junctions

• Munisa A. Tomayeva,
• Vyacheslav D. Neverov,
• Andrey V. Krasavin,
• Alexei Vagov and
• Mihail D. Croitoru

Beilstein J. Nanotechnol. 2025, 16, 2265–2273, doi:10.3762/bjnano.16.155

• experiments, where the DOS remains nonzero at low energies. This broadening arises from inelastic scattering, interface imperfections, and finite quasiparticle lifetimes [46][53][57]. Experimentally, the proximity gap can be probed by tunneling spectroscopy by measuring the differential conductance dI/dV on

Chiral plasmonic nanostructures fabricated with circularly polarized light

• Tian Qiao and
• Ming Lee Tang

Beilstein J. Nanotechnol. 2025, 16, 2245–2264, doi:10.3762/bjnano.16.154

• reported. The authors of [59] conducted single-particle circular differential scattering spectroscopy (CDS) on their Au nanocubes. In a recent study, enhanced structural chirality of all-metal PNSs was achieved through galvanic replacement reactions (GRRs) modulated by CPL when achiral seeds were

• field. This section will cover the experimental methods for observing the near fields of cPNSs. Advanced techniques, such as near-field scanning optical microscopy (NSOM), cathodoluminescence (CL), electron energy loss spectroscopy (EELS), and photoemission electron microscopy (PEEM), offer spatial

• optical spectroscopy, such as CD. However, characterizing local chiral domains can be more challenging. References [21][22] have offered valuable insights through simulations, crystallographic analysis, and high-resolution TEM. A more general model would be desirable through further in-depth studies. 4.2

Optical bio/chemical sensors for vitamin B₁₂ analysis in food and pharmaceuticals: state of the art, challenges, and future outlooks

• Seyed Mohammad Taghi Gharibzahedi and
• Zeynep Altintas

Beilstein J. Nanotechnol. 2025, 16, 2207–2244, doi:10.3762/bjnano.16.153

• different food and pharma formulations include high-performance liquid chromatography (HPLC) [14], HPLC coupled with inductively coupled plasma-mass spectrometry (ICP-MS) [15], and a diode array detector [16], atomic absorption spectroscopy [17], surface-enhanced Raman spectroscopy [18][19], capillary

Electromagnetic study of a split-ring resonator metamaterial with cold-electron bolometers

• Ekaterina A. Matrozova,
• Alexander V. Chiginev,
• Leonid S. Revin and
• Andrey L. Pankratov

Beilstein J. Nanotechnol. 2025, 16, 2199–2206, doi:10.3762/bjnano.16.152

• achieve an optimal balance between power load, responsivity, and total noise [17][22]. This capability is particularly critical for applications like cosmic microwave background polarimetry or high-resolution spectroscopy, where the detector must operate photon-noise-limited under a specific background

Ultrathin water layers on mannosylated gold nanoparticles

• Maiara A. Iriarte Alonso,
• Jorge H. Melillo,
• Silvina Cerveny,
• Yujin Tong and
• Alexander M. Bittner

Beilstein J. Nanotechnol. 2025, 16, 2183–2198, doi:10.3762/bjnano.16.151

• light scattering, and infrared spectroscopy. We probed particles adsorbed on hydrophilic and hydrophobic surfaces with atomic force microscopy (AFM) and vibrational sum frequency generation (VSFG) spectroscopy, both operated under variable air humidity. For AFM, we additionally tested hydrophilic and

• transmission of airborne viruses, such as influenza. Keywords: AFM; humidity; hydrophilicity; hydrophobicity; nanoparticles; sum frequency generation spectroscopy; viruses; water; wetting; Introduction Gold nanoparticles (AuNPs) have been a staple in biomedical and biophysical research [1][2] for almost a

• inorganic surfaces, usually modified with organic layers, and probed by Fourier-transform infrared spectroscopy (FTIR), vibrational sum frequency generation (VSFG), and atomic force microscopy (AFM). For VSFG and AFM, we systematically varied the relative air humidity (RH). DLS and ZP yield particle size

Microplastic pollution in Himalayan lakes: assessment, risks, and sustainable remediation strategies

• Sameeksha Rawat,
• S. M. Tauseef and
• Madhuben Sharma

Beilstein J. Nanotechnol. 2025, 16, 2144–2167, doi:10.3762/bjnano.16.148

• isolated locations is, however, limited by factors such as harsh climatic conditions, logistical challenges, and the need for expert analytical techniques like microscopy and spectroscopy. The present review considers sources, pathways, and ecological impacts of microplastics in Himalayan lakes compared to

• understanding the full contamination profile in remote ecosystems [33]. An overview of MP sampling and analysis methods is given in Figure 3. 4.2 Analytical techniques for microplastic characterization 4.2.1 Spectroscopy. One of the key methods of analyzing MPs is spectroscopy. Fourier-transform infrared (FTIR

• ) spectroscopy is used regularly to identify the chemical structure of MPs [34]. One of the most important developments for nanoplastic detection in complex environmental matrices is micro-FTIR to analyze particles smaller than 10 µm [35]. Raman spectroscopy improves on FTIR by using higher resolution and the

Quality by design optimization of microemulsions for topical delivery of Passiflora setacea seed oil

• Daniel T. Pereira,
• Douglas Dourado,
• Danielle T. Freire,
• Dayanne L. Porto,
• Cícero F. S. Aragão,
• Myla L. de Souza,
• Guilherme R. S. de Araujo,
• Ana Maria Costa,
• Wógenes N. Oliveira,
• Anne Sapin-Minet,
• Éverton N. Alencar and
• Eryvaldo Sócrates T. Egito

Beilstein J. Nanotechnol. 2025, 16, 2116–2131, doi:10.3762/bjnano.16.146

• ), followed by gas chromatography coupled with mass spectroscopy (GC–MS) analysis. The relative composition of fatty acids is presented in Table 1, and the corresponding chromatogram is provided in Figure S1 (Supporting Information File 1). The major constituents identified in OPS were linoleic acid (64.69

Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• necessary to reach separation is an important point. We have employed the two enantiomers of a chiral, nitroxide-based spin probe as guests in organo-modified macroporous host materials and applied ESR spectroscopy as a tool to investigate their rotational mobility. Using a well-established and commercially

• chemistry; ESR spectroscopy; organic inorganic hybrids; porous materials; Introduction Chiral materials represent an evolving research field that focuses on materials whose structures lack mirror symmetry [1][2][3]. The materials exhibit chirality, and a good overview of important developments was given by

• measurements more difficult. There are other valuable methods for investigating transport in porous media such as gas-adsorption methods, X-ray tomography [24][25], neutron imaging techniques [26][27], optical imaging techniques [27][28], or impedance spectroscopy [29][30]. For all of them, it is difficult to