Comprehensive review on ultrasound-responsive theranostic nanomaterials: mechanisms, structures and medical applications

• Sepand Tehrani Fateh,
• Lida Moradi,
• Elmira Kohan,
• Michael R. Hamblin and
• Amin Shiralizadeh Dezfuli

Beilstein J. Nanotechnol. 2021, 12, 808–862, doi:10.3762/bjnano.12.64

High-yield synthesis of silver nanowires for transparent conducting PET films

• Gul Naz,
• Hafsa Asghar,
• Muhammad Ramzan,
• Muhammad Arshad,
• Rashid Ahmed,
• Muhammad Bilal Tahir,
• Bakhtiar Ul Haq,
• Nadeem Baig and
• Junaid Jalil

Beilstein J. Nanotechnol. 2021, 12, 624–632, doi:10.3762/bjnano.12.51

• , carbon nanotubes (CNT), conductive polymers, and metallic nanowires, have been tested commercially as alternative to ITO films for flexible optoelectronic devices [6][7][8][9]. Amongst them, graphene and carbon materials, particularly CNTs, display low optical transparency and high sheet resistance owing

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• ][158]. Improving the luster and the quality of silkworm silk is imperative and studies are being carried out in this direction. Feeding silkworms with nanomaterials, such as carbon nanotubes (CNTs), titanium dioxide, copper, and graphene has been reported to improve the mechanical properties and

• feeding silkworm larvae with unpurified composites of CNTs and lignosulfonate composite (LGS) resulted in excess LGS coating, which blocked CNTs from being embedded into the silk fiber. The purification of CNT/LGS composites resulted in a higher CNT content, which led to an ordered graphitic structure in

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• layer and PDMS as the negative friction layer. The modified CNTs embedded into a thin layer of PANI by the TENG electrochemical system showed a larger diameter compared with the pristine CNTs, as shown in Figure 10b. The electropolymerization of PANI on a CNT electrode is also identified by the Raman

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• used, for example, in water purification, as electrochemical actuators, as transparent conductive electrodes, and as biosensors [21][22][28]. To enhance the performance of MXene supercapacitors, a variety of materials, such as graphene and carbon nanotubes (CNTs), tin(IV) oxide (SnO2), and iron(III

• retention [30]. Yan et al. used a composite material comprising MXene family Ti3C and CNTs as an electrode material to enhance the performance of a supercapacitor. They reported a high volumetric capacitance of 393 F·cm−3 and increased rate capability, as well as excellent cycling stability [31

• ]. Dall’Agnese et al. showed how the electrochemical performance of a supercapacitor was affected by the architecture and composition of the electrode. The electrode material was made up of a composite of Ti3C2 along with CNTs. A maximum capacitance value of 85 F·g−1 was reported with high rate capability and

Free and partially encapsulated manganese ferrite nanoparticles in multiwall carbon nanotubes

• Saja Al-Khabouri,
• Salim Al-Harthi,
• Toru Maekawa,
• Mohamed E. Elzain,
• Ashraf Al-Hinai,
• Ahmed D. Al-Rawas,
• Abbsher M. Gismelseed,
• Ali A. Yousif and
• Myo Tay Zar Myint

Beilstein J. Nanotechnol. 2020, 11, 1891–1904, doi:10.3762/bjnano.11.170

• carbon nanotubes (CNTs), researchers have been interested in functionalizing, inserting, and encapsulating materials inside their inner cavities. Processes related to functionalizing and inserting nanomaterials (i.e., directly implanting as-synthesized nanomaterials into CNTs) have been widely reported

• were attributed to an increase in the dipolar interparticle interactions due to the close packing of nanoparticles within the tubes [7]. There are several potential applications that use metal–metal oxide/CNTs hybrid systems. Carbon nanostructures decorated with titania and silica are used for the

• semiconducting structures [31][32]. The valence edge of the CNTs correspond to the work function [33]. The well-known features of three-fold coordination of C atoms are the deep-lying σ band, corresponding to a strong in-plane bonding located at 8.1 eV, and delocalized π bands, representing the weak bonding

Kondo effects in small-bandgap carbon nanotube quantum dots

• Patryk Florków,
• Damian Krychowski and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2020, 11, 1873–1890, doi:10.3762/bjnano.11.169

• , mechanical, and magnetic properties carbon nanotubes (CNTs) are of great interest in molecular electronics and spintronics with potential applications, for example, as field-effect transistors, nanoelectromechanical devices, logic gates, spin valves, spin diodes, and spin batteries [1][2][3][4][5][6][7][8][9

• ][10][11]. CNTs are also interesting for fundamental science. Their study allows for the examination of many basic properties in ranges often not reachable in other systems. Many of the fundamental transport properties were observed in nanotubes, including Coulomb blockade [12][13], Fabry–Perot

• single-walled carbon nanotube is a hollow cylinder formed of graphene. A CNT can be either metallic or semiconducting, depending on the way graphene is rolled up [37][38]. In the simple “zone folding” picture [39][40], the band structure of CNTs is obtained from the band structure of graphene by imposing

Towards 3D self-assembled rolled multiwall carbon nanotube structures by spontaneous peel off

• Jonathan Quinson

Beilstein J. Nanotechnol. 2020, 11, 1865–1872, doi:10.3762/bjnano.11.168

• ; multiwall carbon nanotubes; nitrogen doping; peel off; rolled carbon nanotubes; Introduction Carbon nanotubes (CNTs) are popular materials used in various applications [1]. These tubular hollow carbon nanomaterials have proven to be useful in multiple scientific fields [2][3][4][5][6]. Complex structures

• with increasingly controlled properties are obtained having CNTs as building blocks. For instance, 3D structures made of CNTs can be synthesized on supports as self-assembled “forests” [7]. These structures have been employed in biomedical applications [7], chromatography [8], or filtration [9

• ]. However, support-free 3D structures typically require extra synthesis steps. “Sponges” or “cages” can be produced by freeze-drying preformed CNTs [10] or by etching template materials [11]. A way to tune CNT properties further is to introduce other elements in the carbon network (e.g., nitrogen [12][13

PEG/PEI-functionalized single-walled carbon nanotubes as delivery carriers for doxorubicin: synthesis, characterization, and in vitro evaluation

• Shuoye Yang,
• Zhenwei Wang,
• Yahong Ping,
• Yuying Miao,
• Yongmei Xiao,
• Lingbo Qu,
• Lu Zhang,
• Yuansen Hu and
• Jinshui Wang

Beilstein J. Nanotechnol. 2020, 11, 1728–1741, doi:10.3762/bjnano.11.155

• . In this study, raw SWCNTs were purified with different oxidizing acids, and the resulting shortened CNTs were conjugated with poly(ethylene glycol) (PEG) and polyethylenimine (PEI). The different nanocarriers, that is, CNTs-COOH (CNTs), CNTs-PEG and CNTs-PEG-PEI, were systematically characterized and

• evaluated in terms of drug loading, in vitro release, cytotoxicity towards MCF-7 cells and cellular uptake. The results showed that all CNT carriers had a high drug loading capacity. In comparison with CNTs-COOH and CNTs-PEG, CNTs-PEG-PEI showed a more rapid drug release under acidic conditions and a higher

• antitumor activity. Furthermore, fluorescence detection and flow cytometry (FCM) analysis results indicated that the internalization into cells of CNTs-PEG-PEI was significantly enhanced, thus inducing tumor cell death through apoptosis more efficiently. The above series of benefits of CNTs-PEG-PEI may be

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

Wet-spinning of magneto-responsive helical chitosan microfibers

• Dorothea Brüggemann,
• Johanna Michel,
• Naiana Suter,
• Matheus Grande de Aguiar and
• Michael Maas

Beilstein J. Nanotechnol. 2020, 11, 991–999, doi:10.3762/bjnano.11.83

• organic templates are examples of alternative ways to synthesize helical nano- or microfibers from various materials like carbon nanotubes (CNTs), ZnO or different polymers [8][48][49]. Here, we present a simple method for synthesizing helical chitosan microfibers with embedded magnetic nanoparticles

A novel dry-blending method to reduce the coefficient of thermal expansion of polymer templates for OTFT electrodes

• Xiangdong Ye,
• Bo Tian,
• Yuxuan Guo,
• Fan Fan and
• Anjiang Cai

Beilstein J. Nanotechnol. 2020, 11, 671–677, doi:10.3762/bjnano.11.53

• in a polymer to obtain a composite. Shokrieh et al. [10] carried out a systematic theoretical study to investigate the influence of carbon nanotubes (CNTs) on the CTE of CNT/epoxy, and the results indicate that the addition of 1 wt % CNT causes a significant decrease of the CTE of the matrix

Identification of physicochemical properties that modulate nanoparticle aggregation in blood

• Ludovica Soddu,
• Duong N. Trinh,
• Eimear Dunne,
• Dermot Kenny,
• Giorgia Bernardini,
• Ida Kokalari,
• Arianna Marucco,
• Marco P. Monopoli and
• Ivana Fenoglio

Beilstein J. Nanotechnol. 2020, 11, 550–567, doi:10.3762/bjnano.11.44

• (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) can induce platelet activation by inducing depletion of intracellular Ca2+ [10][11], an effect that was hypothesised to be caused by the interaction of CNTs with plasma and dense tubular system membranes likely related to the fibrous shape [12]. On the

• ], while platelet aggregation was observed for amorphous CNPs but not for the small-sized fullerenes [10]. Note however that limited information relating to the physicochemical properties of the materials was given in these studies, making a critical analysis of the results difficult. Moreover, while CNTs

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

• Varsha Sharma and
• Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

• mechanical properties, carbon-based materials were also reported for the functionalization of hollow capsules. When the microcapsules were embedded with carbon nanotubes (CNTs) in the shell, the rigidity of the shell was improved upon drying and resulted in freestanding structures. The capsules modified with

• CNTs ruptured upon laser light irradiation [115]. The introduction of graphene oxide (GO) nanosheets with PDDA as multilayers caused the migration and rearrangement of chains compared to PDDA/PAA multilayers [116]. The PDDA/GO multilayers showed improved resistance to damage and maintained a defect

Electrochemically derived functionalized graphene for bulk production of hydrogen peroxide

• Munaiah Yeddala,
• Pallavi Thakur,
• Anugraha A and
• Tharangattu N. Narayanan

Beilstein J. Nanotechnol. 2020, 11, 432–442, doi:10.3762/bjnano.11.34

• metal-based technologies [28][29]. For example, carbon nanotubes (CNTs) have been well studied for their catalytic activity, although conflicting reports exist due to the presence of unavoidable metallic impurities present [30][31][32][33]. With the emergence of graphene, heteroatom doping in sp2

• CNTs, graphene, etc. can be oxidized via chemical treatment, and these oxidized forms of sp2–sp3 carbon systems prefer peroxide formation in alkaline ORR process [25]. Such studies are supported by reports from other groups, where McCloskey et al. showed that sp2-hybridized carbon near-ring ether

pH-Controlled fluorescence switching in water-dispersed polymer brushes grafted to modified boron nitride nanotubes for cellular imaging

• Saban Kalay,
• Yurij Stetsyshyn,
• Volodymyr Donchak,
• Khrystyna Harhay,
• Ostap Lishchynskyi,
• Halyna Ohar,
• Yuriy Panchenko,
• Stanislav Voronov and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2019, 10, 2428–2439, doi:10.3762/bjnano.10.233

• in several fields [1][2][3][4][6][7][11][12][13][14][15][16]. BNNTs were first synthesized by Chopra et al. [20] in 1995 and they are considered as the structural analog to CNTs. BNNTs are of particular interest due to their remarkable mechanical properties (e.g., Young’s modulus of 1.22 TPa) and low

Multiwalled carbon nanotube based aromatic volatile organic compound sensor: sensitivity enhancement through 1-hexadecanethiol functionalisation

• Nadra Bohli,
• Meryem Belkilani,
• Juan Casanova-Chafer,
• Eduard Llobet and
• Adnane Abdelghani

Beilstein J. Nanotechnol. 2019, 10, 2364–2373, doi:10.3762/bjnano.10.227

• decoration of MWCNTs Prior to their deposition on the interdigitated electrode surface, the MWCNTs were treated by oxygen plasma to create oxygen vacancies on the walls of the CNTs in order to enhance their surface reactivity [14][15]. The detailed description of the experimental steps undertaken is

• openings efficiently [23][24]. In fact, in Figure 2a we see that CNTs with a higher number of Au nanoparticles were at the surface of the CNT mat while those showing fewer particles were deeper in the CNT film. Also, in Figure 2c, we can observe a nanotube that crosses the centre of the image where all of

Ultrathin Ni_1−xCo_xS₂ nanoflakes as high energy density electrode materials for asymmetric supercapacitors

• Xiaoxiang Wang,
• Teng Wang,
• Rusen Zhou,
• Lijuan Fan,
• Shengli Zhang,
• Feng Yu,
• Tuquabo Tesfamichael,
• Liwei Su and
• Hongxia Wang

Beilstein J. Nanotechnol. 2019, 10, 2207–2216, doi:10.3762/bjnano.10.213

• graphene, graphene oxide (GO) or carbon nanotubes (CNTs) in order to improve the charge–discharge process stability [11][12][13]. There are limited reports regarding a comparison of the intrinsic performance between these Ni–Co chalcogenides materials. Even pure Ni–Co chalcogenide nanomaterials have been

Facile synthesis of carbon nanotube-supported NiO//Fe₂O₃ for all-solid-state supercapacitors

• Shengming Zhang,
• Xuhui Wang,
• Yan Li,
• Xuemei Mu,
• Yaxiong Zhang,
• Jingwei Du,
• Guo Liu,
• Xiaohui Hua,
• Yingzhuo Sheng,
• Erqing Xie and
• Zhenxing Zhang

Beilstein J. Nanotechnol. 2019, 10, 1923–1932, doi:10.3762/bjnano.10.188

• . deposited iron oxide on CNTs by atomic layer deposition (ALD) and the obtained CNTs@Fe2O3 presented a specific capacitance of 580.6 F·g−1 at 5 A·g−1 [21]. Zhang et al. used magnetron sputtering to prepare sandwich-like CNT@Fe2O3@C structures, and the composite exhibited a specific capacitance of 787.5 F·g−1

• cathode were prepared. CNTs significantly improved the conductivity and enhanced the capacity of Fe2O3 up to 226 mAh·g−1 at 2 A·g−1, and capacity of NiO to 527 mAh·g−1 at 2 A·g−1. Furthermore, by assembling the two electrodes, an asymmetric supercapacitor (ASC) with a high energy density of 63.3 Wh·kg−1

• Discussion Figure 1 shows the process of synthesizing cathode and anode, and finally, the asymmetric supercapacitor. The details can be seen in the Experimental section. Anode material CC-CNT@Fe2O3 CNTs were grown on CC by chemical vapour deposition (CVD). As shown in Figure 2a, CNTs grow homogeneously with

Flexible freestanding MoS₂-based composite paper for energy conversion and storage

• Florian Zoller,
• Jan Luxa,
• Thomas Bein,
• Dina Fattakhova-Rohlfing,
• Daniel Bouša and
• Zdeněk Sofer

Beilstein J. Nanotechnol. 2019, 10, 1488–1496, doi:10.3762/bjnano.10.147

• . Moreover, an appropriate heat management scheme has to be taken into account in real applications as it has been already shown for other nanomaterials [30][31]. Introducing support materials, such as graphene or carbon nanotubes (CNTs) can alleviate these problems and improve the performance of the

Hierarchically structured 3D carbon nanotube electrodes for electrocatalytic applications

• Pei Wang,
• Katarzyna Kulp and
• Michael Bron

Beilstein J. Nanotechnol. 2019, 10, 1475–1487, doi:10.3762/bjnano.10.146

• Pei Wang Katarzyna Kulp Michael Bron Martin-Luther-University Halle-Wittenberg, Faculty of Natural Sciences II, Department of Chemistry, 06120 Halle, Germany 10.3762/bjnano.10.146 Abstract Hierarchically structured 3-dimensional electrodes based on branched carbon nanotubes (CNTs) are prepared on

• a glassy carbon (GC) substrate in a sequence of electrodeposition and chemical vapor deposition (CVD) steps as follows: Primary CNTs are grown over electrodeposited iron by CVD followed by a second Fe deposition and finally the CVD growth of secondary CNTs. The prepared 3-dimensional CNT structures

• (CNT/CNT/GC) exhibit enhanced double-layer capacitance and thus larger surface area compared to CNT/GC. Pt electrodeposition onto both types of electrodes yields a uniform and homogeneous Pt nanoparticle distribution. Each preparation step is followed by scanning electron microscopy, while the CNTs

Magnetic segregation effect in liquid crystals doped with carbon nanotubes

• Danil A. Petrov,
• Pavel K. Skokov,
• Alexander N. Zakhlevnykh and
• Dmitriy V. Makarov

Beilstein J. Nanotechnol. 2019, 10, 1464–1474, doi:10.3762/bjnano.10.145

• [1][11][12]. Thus, the idea of controlling the features of composites by adding a small amount of nanoparticles to an LC matrix is of great interest from a physical point of view. Carbon nanotubes (CNTs) [13] are a popular material to be embedded in LCs [9][14][15][16][17]. Due to a large aspect

• ratio the physical properties of this carbon nanomaterial vary greatly in different directions. In this sense, the anisotropic properties of CNTs (for example, thermal and electrical conductivities) are attractive for a wide range of applications, including nanoelectronics and optics [2]. A distinctive

• feature of CNTs is their strong diamagnetism ( ≈ 10−5 to 10−4) [18][19][20][21][22][23]. In the majority of experimental publications [7][16][24][25][26] the planar type of anchoring between the nanotubes and the LC matrix is noted. For CNT suspensions based on nematic liquid crystals (NLCs) with positive

Multicomponent bionanocomposites based on clay nanoarchitectures for electrochemical devices

• Giulia Lo Dico,
• Bernd Wicklein,
• Lorenzo Lisuzzo,
• Giuseppe Lazzara,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2019, 10, 1303–1315, doi:10.3762/bjnano.10.129

• instance, graphene, CNTs, and buckypapers (10–25 µA·mM−1) [46][66][67], the external surface of functionalised HNTs (5.2 µA·mM−1) [20], a polymeric matrix (5 µA·mM−1) [68] or a chitosan-modified matrix (1.2 µA·mM−1) [69]. The crucial role of HNTs as protective containers for the enzymes was underlined by

Alloyed Pt₃M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction

• Stéphane Louisia,
• Yohann R. J. Thomas,
• Pierre Lecante,
• Marie Heitzmann,
• M. Rosa Axet,
• Pierre-André Jacques and
• Philippe Serp

Beilstein J. Nanotechnol. 2019, 10, 1251–1269, doi:10.3762/bjnano.10.125

• , 31055 Toulouse Cedex 4, France 10.3762/bjnano.10.125 Abstract Sulfur- (S-CNT) and nitrogen-doped (N-CNT) carbon nanotubes have been produced by catalytic chemical vapor deposition (c-CVD) and were subject to an annealing treatment. These CNTs were used as supports for small (≈2 nm) Pt3M (M = Co or Ni

• support, in combination with ILs, is also important to achieve high Pt dispersion, and functionalized carbons should be preferred, presumably because of their stronger interaction with the IL [28]. Carbon nanotubes (CNTs) are well known for their remarkable chemical and physical properties and appear to

• be an interesting alternative to replace CB in fuel cell applications [29][30]. It has been described that CNTs could be used as resistant material to support nanostructured PtNi hollow particles, but it appears that the structure of the used CNT might be responsible for the large external diameter