Beilstein J. Nanotechnol.2016,7, 758–766, doi:10.3762/bjnano.7.67
, Damanhour, Egypt 10.3762/bjnano.7.67 Abstract Carbonization of tomatoes at 240 °C using 30% (w/v) NaOH as catalyst produced carbon onions (C-onions), while solely carbondots (C-dots) were obtained at the same temperature in the absence of the catalyst. Other natural materials, such as carrots and tree
versatile materials for chemical sensing of metal ions. The high content of lycopene in tomatoes may explain the formation of C-onions in alkaline media and a possible formation mechanism for such structures was outlined.
Keywords: carbondots; carbon onions; metal-ion sensing; photoluminescence; thermal
sensors. The more popular and extensively investigated carbon-based nanomaterials include carbondots (C-dots), fullerenes, nanotubes and graphene, while others, such as nanodiamonds and carbon onions, stayed forgotten for a long time, in spite of the fact that these carbon nanoparticles (C-NPs) were
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Figure 1:
HRTEM images of C-dots obtained by carbonization in aqueous environment, using as carbon source a) ...
Beilstein J. Nanotechnol.2014,5, 696–710, doi:10.3762/bjnano.5.82
for more detailed information [106].
Carbon nanodots are a new class of carbon nanomaterials and consist of discrete, quasipherical nanoparticles with sizes below 10 nm [107][108][109][110]. Since they have been reported on in 2004 for the first time [111], carbondots have gradually become an
important member in the nanocarbon family due to their benign, abundant and low-cost nature. As carbonaceous quantum dots, carbon nanodots display PL behavior dependent on their size and the excitation wavelength. In addition, carbondots are also characterized by water solubility, chemical inertness and
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Figure 1:
Schematic steps for the photocatalytic reactions occuring on the surface of a semiconductor. Adapte...