Synthesis, characterization, monolayer assembly and 2D lanthanide coordination of a linear terphenyl-di(propiolonitrile) linker on Ag(111)

• Zhi Chen,
• Svetlana Klyatskaya,
• José I. Urgel,
• David Écija,
• Olaf Fuhr,
• Willi Auwärter,
• Johannes V. Barth and
• Mario Ruben

Beilstein J. Nanotechnol. 2015, 6, 327–335, doi:10.3762/bjnano.6.31

• the remarkable coordination reactivity of carbonitrile groups, which are very well known in bulk coordination chemistry. The linker 2 was deposited by organic molecular beam epitaxy onto an atomically clean and flat Ag(111) surface kept at 300 K, followed by the controlled co-deposition of Gd atoms

Spontaneous dissociation of Co₂(CO)₈ and autocatalytic growth of Co on SiO₂: A combined experimental and theoretical investigation

• Kaliappan Muthukumar,
• Harald O. Jeschke,
• Roser Valentí,
• Evgeniya Begun,
• Johannes Schwenk,
• Fabrizio Porrati and
• Michael Huth

Beilstein J. Nanotechnol. 2012, 3, 546–555, doi:10.3762/bjnano.3.63

• different pretreatment conditions of the substrate [33]. In the present work, we report on experimental results of Co deposition by spontaneous dissociation of the precursor Co2(CO)8 on untreated and two differently pretreated SiO2 surfaces (by an air plasma cleaning process and a pregrowth electron