Green synthesis of carbon dot structures from Rheum Ribes and Schottky diode fabrication

• Muhammed Taha Durmus and
• Ebru Bozkurt

Beilstein J. Nanotechnol. 2024, 15, 1369–1375, doi:10.3762/bjnano.15.110

• substrate was cut to approximately 1 cm2 in size and cleaned by washing it in acetone, methanol, and pure water for 10 min each. An ohmic contact was made with aluminum on the cleaned sample at 1 × 10−7 Torr vacuum in a PVD thermal evaporation device. Approximately 30 μL of the CDs stock solution was taken

Investigation of Hf/Ti bilayers for the development of transition-edge sensor microcalorimeters

• Victoria Y. Safonova,
• Anna V. Gordeeva,
• Anton V. Blagodatkin,
• Dmitry A. Pimanov,
• Anton A. Yablokov and
• Andrey L. Pankratov

Beilstein J. Nanotechnol. 2024, 15, 1353–1361, doi:10.3762/bjnano.15.108

• compared to the full-size films. This is because at the edges of the structure, the film thickness may differ from that at the center. Smooth edges are also necessary for good contact with subsequent layers. For this reason, special attention is paid to the development of technology for creating structures

• in different transition temperatures at heating and cooling. The presumed reason is the heating of the film sample C1 through the measuring pogo pin contacts made of gold-coated brass and the contact resistance between the contacts and the film. Samples A1–A4 and B1 were measured through the same

• clamp contacts as sample C1, but the measured area was further away from the contact points. This way, the current first flows through the superconducting electrodes with low thermal conductivity in the superconducting state, and only then goes to the bridge. Nevertheless, non-equilibrium heating

Hymenoptera and biomimetic surfaces: insights and innovations

• Vinicius Marques Lopez,
• Carlo Polidori and
• Rhainer Guillermo Ferreira

Beilstein J. Nanotechnol. 2024, 15, 1333–1352, doi:10.3762/bjnano.15.107

• ). The arolium may be structured in lines perpendicular to the longitudinal axis of the pretarsus [126]. When extended (actively or passively) [127], the arolium comes into contact with the surface, thereby enhancing its adhesive contact area. Hymenopteran species serve as valuable sources of inspiration

• for artificial adhesive surfaces because of their rapid stepping frequencies [127]. For instance, weaver ants (Oecophylla smaragdina) can swiftly adjust and control their contact areas in less than a millisecond, a capability that helps prevent unexpected detachment and enables efficient locomotion

• with a smaller contact area [128]. In honeybees, these pads function in response to specific drag activities, even without neuromuscular reflexes [129]. This passive mechanism is attributed to the structural characteristics of the soft pads, which work in concert with hierarchical structures supported

Mn-doped ZnO nanopowders prepared by sol–gel and microwave-assisted sol–gel methods and their photocatalytic properties

• Cristina Maria Vlăduț,
• Crina Anastasescu,
• Silviu Preda,
• Oana Catalina Mocioiu,
• Simona Petrescu,
• Jeanina Pandele-Cusu,
• Dana Culita,
• Veronica Bratan,
• Ioan Balint and
• Maria Zaharescu

Beilstein J. Nanotechnol. 2024, 15, 1283–1296, doi:10.3762/bjnano.15.104

• to examine the photocatalytic mechanism under different irradiation sources. Also by the sol–gel method, the active materials can be deposited in future studies as films on different supports for better surface contact and recovery degree, enhancing the scale-up opportunity for water cleaning

Functional morphology of cleaning devices in the damselfly Ischnura elegans (Odonata, Coenagrionidae)

• Silvana Piersanti,
• Gianandrea Salerno,
• Wencke Krings,
• Stanislav Gorb and
• Manuela Rebora

Beilstein J. Nanotechnol. 2024, 15, 1260–1272, doi:10.3762/bjnano.15.102

• ), with the tibial flag-shaped structures kept in contact first with the eye and afterwards with the dorsal side of the antenna. The action was repeated several times with both legs acting synchronously or with separate movements (Figure 3a–f). A series of eye and antennae scraping was almost always

• hairs, while the soft tips ensure effective contact between the attachment system and the substrate. Similarly, the material gradient in grooming devices may enhance adhesion to foreign materials for grooming body surfaces. The soft tip and soft lateral cuticular lamina adapt to various surface

Dual-functionalized architecture enables stable and tumor cell-specific SiO₂NPs in complex biological fluids

• Iris Renata Sousa Ribeiro,
• Raquel Frenedoso da Silva,
• Romênia Ramos Domingues,
• Adriana Franco Paes Leme and
• Mateus Borba Cardoso

Beilstein J. Nanotechnol. 2024, 15, 1238–1252, doi:10.3762/bjnano.15.100

• anticancer nanomedicines are administered intravenously. This route is fast and precise as the drug enters directly into the systemic circulation, without undergoing absorption processes. When nanoparticles come into direct contact with the blood, however, they interact with physiological components that can

• of NPs accumulates in tumors and <0.0014% are internalized by the cells [8][9][10][11]. Once in contact with blood, NPs interact with a series of physiological components (e.g., amino acids, salts, and proteins), which can induce poor colloidal stability or changes in the original chemical and

Introducing third-generation periodic table descriptors for nano-qRASTR modeling of zebrafish toxicity of metal oxide nanoparticles

• Supratik Kar and
• Siyun Yang

Beilstein J. Nanotechnol. 2024, 15, 1142–1152, doi:10.3762/bjnano.15.93

• radius of the nanomaterial components but positively by the molecular bulk of the nanomaterials. Electronegativity and atomic size determine the reactivity and contact strength of nanomaterials with biological systems, whereas the molecule bulk affects the mechanism of inhibition through steric effects

Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• are highly susceptible to mechanical failure because of their brittle nature; in contrast, the etched SiNW arrays exhibit superior optical absorption and enhanced surface catalytic reaction properties. The intimate contact between 1D Si NWs and thin TiO2 layers reduces the recombination rate of

• surface interaction with gases during photocatalytic oxidative coupling can be analyzed using water contact angle analysis (as shown in Supporting Information File 1, Figure S2). The wettability of pure p-Si and the p-Si NW array are illustrated in Figure S3 (Supporting Information File 1). Pure p-Si had

• a water contact angle of 50.24°. Because of the nanowire array morphology, the p-Si NWs were more hydrophilic nature with a water contact angle of 3.36°, which manifests superior photocatalytic oxidative coupling. Raman spectra were conducted to confirm the surface composition of the synthesized

Local work function on graphene nanoribbons

• Daniel Rothhardt,
• Amina Kimouche,
• Tillmann Klamroth and
• Regina Hoffmann-Vogel

Beilstein J. Nanotechnol. 2024, 15, 1125–1131, doi:10.3762/bjnano.15.91

• exotic nature of the charge carriers and to local confinement as well as atomic-scale structural details. The local work function provides evidence for such structural, electronic, and chemical variations at surfaces. Kelvin prove force microscopy can be used to measure the local contact potential

• nanoribbons; Kelvin probe force microscopy; local contact potential difference; Introduction Graphene’s electronic properties are determined by its two-dimensionality as well as by its semimetallic gapless conical band structure [1]. Its electronic behavior depends strongly on the location of the Fermi level

• acquisition [21][22]. In this way, an image of the local contact potential difference between tip and sample is obtained. This has been shown not only for general surfaces, for example, insulating surfaces, but also for molecules and molecular layers [18][23][24][25]. Here, we study the local work function

Direct electron beam writing of silver using a β-diketonate precursor: first insights

• Katja Höflich,
• Krzysztof Maćkosz,
• Chinmai S. Jureddy,
• Aleksei Tsarapkin and
• Ivo Utke

Beilstein J. Nanotechnol. 2024, 15, 1117–1124, doi:10.3762/bjnano.15.90

• (Strem Chemicals, CAS 148630-66-4), with a stoichiometry of Ag/P/F/O/C = 1:1:6:2:8 was evaporated using a fully integrated custom-built gas injection system (GIS) consisting of chemically inert steel [28]. No injection needles were used. The components of the GIS that were in direct contact with the

Signal generation in dynamic interferometric displacement detection

• Knarik Khachatryan,
• Simon Anter,
• Michael Reichling and
• Alexander von Schmidsfeld

Beilstein J. Nanotechnol. 2024, 15, 1070–1076, doi:10.3762/bjnano.15.87

• . In a non-contact atomic force microscope (NC-AFM), it facilitates the force measurement by recording the periodic displacement of an oscillating microcantilever. To understand signal generation in a NC-AFM-based Michelson-type interferometer, we evaluate the non-linear response of the interferometer

• highly stable interferometer can detect displacements with an accuracy far beyond nanometer resolution [3], where the final physical limit is set by the photon emission statistics of the light source [4]. In non-contact atomic force microscopy (NC-AFM), interferometry is used to measure the periodic

Interface properties of nanostructured carbon-coated biological implants: an overview

• Mattia Bartoli,
• Francesca Cardano,
• Erik Piatti,
• Stefania Lettieri,
• Andrea Fin and
• Alberto Tagliaferro

Beilstein J. Nanotechnol. 2024, 15, 1041–1053, doi:10.3762/bjnano.15.85

• biocompatibility because the implant interfaces are the first line of contact between a foreign body and living organisms. The bulk materials used in implants are carefully chosen to minimize adverse reactions, but the immune system may still recognize them as external entities and trigger inflammatory responses

• bone tissues [137] to reduce wear. Such layers have been widely studied as coating agents onto several metal surfaces directly in contact with bone, including steel [138], titanium [139], and magnesium [140]. As reported by Deenoi et al. [141], CNT coatings on titanium nitride at the interface with

Bolometric IR photoresponse based on a 3D micro-nano integrated CNT architecture

• Yasameen Al-Mafrachi,
• Sandeep Yadav,
• Sascha Preu,
• Jörg J. Schneider and
• Oktay Yilmazoglu

Beilstein J. Nanotechnol. 2024, 15, 1030–1040, doi:10.3762/bjnano.15.84

• presented in the conference proceedings [12]. This configuration 1 (called sample 1) had additional parasitic contact resistances to the M-shaped CNT block. The new configuration 2 (called sample 2) used direct Au whisker contacts to the CNT block with much lower contact resistances for reliable

• was deposited by atomic layer deposition to support the elongated growth of CNTs (Figure 1a). The contact pad regions were opened by an optical lithography process prior to the evaporation of Cr/Au (20 nm, e-beam/100 nm, thermal) (Figure 1b). The overall M-shape for the CNT growth as shown in Figure

•  1c was defined by overlapping two tantalum-based growth stop strips (150 nm, sputtering) with a rectangular Fe layer (2 nm, e-beam) on the Si wafer. Only regions with direct Fe/AlOx contact were active for CNT growth. This combination allows for the definition of any shape, offering versatility for

Recent progress on field-effect transistor-based biosensors: device perspective

• Billel Smaani,
• Fares Nafa,
• Mohamed Salah Benlatrech,
• Ismahan Mahdi,
• Hamza Akroum,
• Mohamed walid Azizi,
• Khaled Harrar and
• Sayan Kanungo

Beilstein J. Nanotechnol. 2024, 15, 977–994, doi:10.3762/bjnano.15.80

• sensing membrane is accommodated between the contact of the metal gate and the insulator part. The carrier concentration in the body channel might change as a result of an accumulation, depletion, or inversion process when an external voltage is applied [51]. This results in the formation of a band

• in human urine and serum. 2.2.11 Organic TFET-based biosensors. Jain et al. [111] proposed a concept of bilayer electrodes for top-contact organic tunnel FET (BE TC OTFT)-based biosensors aiming for enhanced detection of charged and neutral biomolecules. Figure 15 shows the schematic view of a BE TC

Beyond biomimicry – next generation applications of bioinspired adhesives from microfluidics to composites

• Dan Sameoto

Beilstein J. Nanotechnol. 2024, 15, 965–976, doi:10.3762/bjnano.15.79

• functional in contact with these liquids and have enabled for a variety of flexible electronics applications. While the geckofluidics project was an example of a traditional application enhanced through the use of an improved bonding solution, the key to advancing the utility of biomimetic adhesives lies in

• contact with surfaces and achieve large adhesive strength [21]. A material that was soft when making contact and rigid when supporting a load would be ideal, and in fact this is still an area where modern efforts continue [31][44][45]. Our closest demonstration at the time to achieve this stiffness tuning

• perfectly suited for biomimetic adhesives, as their coefficient of friction could be significantly higher than one, and our work on geckofluidics with rigid backing materials was already indicating similar capabilities. Once in contact with a smooth surface, isotropic biomimetic adhesives do not require

Effects of cutting tool geometry on material removal of a gradient nanograined CoCrNi medium entropy alloy

• Yu-Sheng Lu,
• Yu-Xuan Hung,
• Thi-Xuyen Bui and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2024, 15, 925–940, doi:10.3762/bjnano.15.76

• damage is limited to a shallow layer at the surface. Since thermal energy is generated in the high grain boundary density, the temperature of the contact zone between the substrate and the cutting tool increases as the GNG size decreases. The cutting chips removed from the GNG CoCrNi MEA substrates will

• because, as the material pile-up increases, the contact area between the cutting tool and the specimen also increases. This leads to a rise in the average resultant force. Thicker chips result in higher cutting resistance strength. The sample with a grain size gradient of 15-13-10 nm with the thinnest

• . The temperature is proportional to the kinetic energy, so the system releases much kinetic energy when the deformation process changes from elastic to plastic deformation. The kinetic energy of the atoms in the contact area between the cutting tool and the substrate is the highest, leading to the

The effect of age on the attachment ability of stick insects (Phasmatodea)

• Marie Grote,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 867–883, doi:10.3762/bjnano.15.72

• sign of ageing is the loss of locomotory functions due to neuronal disorders or tissue wear. Soft and pliable attachment pads on the tarsi of insects adapt to the substrate texture to maximize their real contact area and, thereby, generate attachment during locomotion. In the majority of stick insects

• the pads, scarring of the cuticle, and alteration of the autofluorescence, likely indicating stiffening of the cuticle, were observed to accumulate over time. This would reduce the attachment ability of the insect, as pads lose their pliant properties and cannot properly maintain sufficient contact

• different attachment mechanisms evolved in insects, namely, hairy pads consisting of flexible setae, which adapt to the surface topography, and smooth pads possessing a soft and deformable cuticle to comply with the substrate profile [9]. Both pad types, hairy and smooth, aim to maximize contact area with

Investigation on drag reduction on rotating blade surfaces with microtextures

• Qinsong Zhu,
• Chen Zhang,
• Fuhang Yu and
• Yan Xu

Beilstein J. Nanotechnol. 2024, 15, 833–853, doi:10.3762/bjnano.15.70

• mm, which has a processing residue at the corner of the bottom rib area (Figure 20a). Figure 19b indicates slight height fluctuations on the surface of the smooth blade, reaching a maximum deviation of 0.007 mm. This can be attributed to the point contact nature of the ball tip tool during the

Exploring surface charge dynamics: implications for AFM height measurements in 2D materials

• Mario Navarro-Rodriguez,
• Andres M. Somoza and
• Elisa Palacios-Lidon

Beilstein J. Nanotechnol. 2024, 15, 767–780, doi:10.3762/bjnano.15.64

• oscillation amplitudes, the tip mechanically touches the surface during part of the oscillation. This mode is known as “intermittent contact” or tapping mode, and incorrect height measurements are usually ascribed to variations in the local elasticity [32][33] or differences in the local adhesion, related to

• differences of the wetting properties [34]. At moderate oscillation amplitudes, intimate tip–sample contact is avoided, and the energy dissipation takes place at the lower turning point of the oscillation cycle because of the formation and rupture of liquid necks [35][36][37]. When operating in this less

• be overestimated, especially in comparison to those obtained in contact mode [8][47][48][49][50][51][52]. As discussed above, the extent of the discrepancy depends on the operation mode [53][54] and environmental conditions [8] and is notably pronounced in samples grown on insulating substrates [55

Effect of repeating hydrothermal growth processes and rapid thermal annealing on CuO thin film properties

• Monika Ozga,
• Eunika Zielony,
• Aleksandra Wierzbicka,
• Anna Wolska,
• Marcin Klepka,
• Marek Godlewski,
• Bogdan J. Kowalski and
• Bartłomiej S. Witkowski

Beilstein J. Nanotechnol. 2024, 15, 743–754, doi:10.3762/bjnano.15.62

• silicon nitride probe, ScanAsyst-AIR (Bruker). Scanning capacitance microscopy (SCM) measurements were conducted in contact mode using a silicon probe coated with a PtIr layer, SCM-PIT-V2 (Bruker). Capacitance measurements were taken with VAC = 2 V and VDC = 1 V applied. The carrier distribution maps at a

• resolution of 256 × 256 pixels presented in the paper were derived from the “SCM data” channel. Contact potential difference (VCPD) measurements were carried out using Kelvin probe force microscopy (KPFM) in amplitude modulation mode, also employing SCM-PIT-V2 probes from Bruker. These measurements were

• crystal quality among the studied structures because they have well-resolved and the most exposed CuO-like Ag, , and phonon modes in their Raman spectra. The surface potential (i.e., contact potential difference, VCPD) and work function (ϕ) variations resulting from the HT+RTA sequencing were examined

Enhancing higher-order modal response in multifrequency atomic force microscopy with a coupled cantilever system

• Wendong Sun,
• Jianqiang Qian,
• Yingzi Li,
• Yanan Chen,
• Zhipeng Dou,
• Rui Lin,
• Peng Cheng,
• Xiaodong Gao,
• Quan Yuan and
• Yifan Hu

Beilstein J. Nanotechnol. 2024, 15, 694–703, doi:10.3762/bjnano.15.57

• beam. They are shown in Figure 1a. The Bode plots of the non-contact tip–sample interaction [12] and the contact tip–sample interaction [23] can be obtained through transfer function analysis. The results indicate that the higher-order modal response of the traditional rectangular cantilever gradually

Comparative analysis of the ultrastructure and adhesive secretion pathways of different smooth attachment pads of the stick insect Medauroidea extradentata (Phasmatodea)

• Julian Thomas,
• Stanislav N. Gorb and
• Thies H. Büscher

Beilstein J. Nanotechnol. 2024, 15, 612–630, doi:10.3762/bjnano.15.52

• enhance the actual contact area between the pad and the substrate for the realisation of efficient attachment due to adhesion and friction forces [3][9][12][13][14]. Smooth attachment pads have independently evolved in most large insect groups, possessing multiple specialized types of pads on the same leg

• that are adapted to attachment through the division of labour by preferably generating more adhesion or friction [5]. Adhesive secretion in the contact zone between the attachment pad and substrate supports the functionality of the pads [15]. The adhesive secretion can fill the gaps in the substrate

• roughness and thereby increase the contact area [14][16][17][18][19]. It can aid in the enhancement of viscous and capillary forces further increasing the attachment strength [9][14][20][21][22][23][24]. The adhesive secretion can be essential for the self-cleaning mechanism by binding smaller contamination

AFM-IR investigation of thin PECVD SiO_x films on a polypropylene substrate in the surface-sensitive mode

• Hendrik Müller,
• Hartmut Stadler,
• Teresa de los Arcos,
• Adrian Keller and
• Guido Grundmeier

Beilstein J. Nanotechnol. 2024, 15, 603–611, doi:10.3762/bjnano.15.51

• /bjnano.15.51 Abstract Thin silicon oxide films deposited on a polypropylene substrate by plasma-enhanced chemical vapor deposition were investigated using atomic force microscopy-based infrared (AFM-IR) nanospectroscopy in contact and surface-sensitive mode. The focus of this work is the comparison of

• the different measurement methods (i.e., contact mode and surface-sensitive mode) with respect to the chemical surface sensitivity. The use of the surface-sensitive mode in AFM-IR shows an enormous improvement for the analysis of thin films on the IR-active substrate. As a result, in this mode, the

• signal of the substrate material could be significantly reduced. Even layers that are so thin that they could hardly be measured in the contact mode can be analyzed with the surface-sensitive mode. Keywords: AFM-IR; polypropylene; surface-sensitive mode; silicon oxide; thin films; XPS; Introduction

Stiffness calibration of qPlus sensors at low temperature through thermal noise measurements

• Laurent Nony,
• Sylvain Clair,
• Daniel Uehli,
• Aitziber Herrero,
• Jean-Marc Themlin,
• Andrea Campos,
• Franck Para,
• Alessandro Pioda and
• Christian Loppacher

Beilstein J. Nanotechnol. 2024, 15, 580–602, doi:10.3762/bjnano.15.50

• University, CNRS, Centrale Marseille, FSCM (FR1739), CP2M, 13397 Marseille, France 10.3762/bjnano.15.50 Abstract Non-contact atomic force microscopy (nc-AFM) offers a unique experimental framework for topographical imaging of surfaces with atomic and/or sub-molecular resolution. The technique also permits

• the framework focuses on a particular kind of sensor, it may be adapted to any high-k, high-Q nc-AFM probe used under similar conditions, such as silicon cantilevers and LERs. Keywords: low temperature; non-contact atomic force microscopy; qPlus sensors; quartz tuning fork; stiffness calibration

• ; thermal noise; ultrahigh vacuum; Introduction Since the 2000s, non-contact atomic force microscopy (nc-AFM) has established itself as a scanning probe method for the topographical, chemical, and electrical mapping of the surface of a sample down to the atomic scale [1][2][3]. When used in an ultrahigh

Photocatalytic degradation of methylene blue under visible light by cobalt ferrite nanoparticles/graphene quantum dots

• Vo Chau Ngoc Anh,
• Le Thi Thanh Nhi,
• Le Thi Kim Dung,
• Dang Thi Ngoc Hoa,
• Nguyen Truong Son,
• Nguyen Thi Thao Uyen,
• Nguyen Ngoc Uyen Thu,
• Le Van Thanh Son,
• Le Trung Hieu,
• Tran Ngoc Tuyen and
• Dinh Quang Khieu

Beilstein J. Nanotechnol. 2024, 15, 475–489, doi:10.3762/bjnano.15.43

• of CF and CF/GQDs-200, respectively, and the corresponding particle size distribution. CF has very fine particles of around 15–20 nm. The intimate interfacial contact between GQDs sheets and the CF nanoparticle is further depicted in the TEM image (Figure 4e). In this image, the deposited

• nanoparticles of around 9.2 nm are obvious on the GQDs. Such a good interfacial contact between CF and GQDs is favourable for the separation of the photogenerated charge carriers in the CF/GQDs. The elemental distribution of CF/GQDs was studied by EDX mapping. The elements Fe, Co, O, and C are present, as