Interaction of graphene oxide with tannic acid: computational modeling and toxicity mitigation in C. elegans

• Romana Petry,
• James M. de Almeida,
• Francine Côa,
• Felipe Crasto de Lima,
• Diego Stéfani T. Martinez and
• Adalberto Fazzio

Beilstein J. Nanotechnol. 2024, 15, 1297–1311, doi:10.3762/bjnano.15.105

• mechanisms against pathogens, heating stress, and oxidative stress, which may increase the resistance against the hazardous effects of GO. TA upregulates natural protective pathways against oxidative stress, increasing the expression of antioxidant systems such as reduced glutathione, superoxide dismutase

Mn-doped ZnO nanopowders prepared by sol–gel and microwave-assisted sol–gel methods and their photocatalytic properties

• Cristina Maria Vlăduț,
• Crina Anastasescu,
• Silviu Preda,
• Oana Catalina Mocioiu,
• Simona Petrescu,
• Jeanina Pandele-Cusu,
• Dana Culita,
• Veronica Bratan,
• Ioan Balint and
• Maria Zaharescu

Beilstein J. Nanotechnol. 2024, 15, 1283–1296, doi:10.3762/bjnano.15.104

• -efficient than conventional heating methods [12][13][14]. This approach is particularly advantageous in technology applications, as it significantly reduces reaction times from days to mere hours or minutes and enables the production of nanocrystalline oxides in the form of powders and films on various

• substrates [3][15][16]. While traditional heating methods cause inhomogeneities by slowly distributing the heat from the surface to the core of the material or within the entire volume of the solution, microwaves allow for quick and uniform heating because they can penetrate to a depth depending on the

• for 10 min at 60 °C, 200 W power and a frequency of 2.45 GHz. Gelation took place at room temperature. All resulting gels were dried at 100 °C for 24 h and then thermally treated at 350 °C for 1 h with a heating speed of 1 °C/min followed by a treatment at 500 °C for 1 h with a heating speed of 5 °C

The role of a tantalum interlayer in enhancing the properties of Fe₃O₄ thin films

• Hai Dang Ngo,
• Vo Doan Thanh Truong,
• Van Qui Le,
• Hoai Phuong Pham and
• Thi Kim Hang Pham

Beilstein J. Nanotechnol. 2024, 15, 1253–1259, doi:10.3762/bjnano.15.101

• ) substrates were prepared by immersing them in a methanol bath at a temperature of 60 °C and drying them in N2 gas flow. Subsequently, the purified substrates were moved into an ultrahigh vacuum (UHV) chamber and underwent a pre-heating process at 600 °C for 30 min in order to eliminate any remaining

Dual-functionalized architecture enables stable and tumor cell-specific SiO₂NPs in complex biological fluids

• Iris Renata Sousa Ribeiro,
• Raquel Frenedoso da Silva,
• Romênia Ramos Domingues,
• Adriana Franco Paes Leme and
• Mateus Borba Cardoso

Beilstein J. Nanotechnol. 2024, 15, 1238–1252, doi:10.3762/bjnano.15.100

• solution (without purification) was transferred to a flask kept in a bath at 80 °C. Then, 26.0 mg of ZW, previously solubilized in 2.0 mL of water, was added. The solution was stirred and heated for 4 h. Subsequently, the heating was removed and 0.98 µL of APTES was added. The reaction was stirred for 24 h

• ) and was repeated four times. Then, Laemmli buffer (1610737, Bio-Rad) containing 50 mM of dithiothreitol (DTT, 1610611, Bio-Rad) was added to the final precipitate, followed by heating at 95 °C for 5 min, and 10 μL of this suspension was applied in a 12% SDS-PAGE gel. The gel was run at a voltage of

Enhanced catalytic reduction through in situ synthesized gold nanoparticles embedded in glucosamine/alginate nanocomposites

• Chi-Hien Dang,
• Le-Kim-Thuy Nguyen,
• Minh-Trong Tran,
• Van-Dung Le,
• Nguyen Minh Ty,
• T. Ngoc Han Pham,
• Hieu Vu-Quang,
• Tran Thi Kim Chi,
• Tran Thi Huong Giang,
• Nguyen Thi Thanh Tu and
• Thanh-Danh Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1227–1237, doi:10.3762/bjnano.15.99

• g·mL−1). The reduction process was initiated through heating the mixture and visually confirmed by a change in color of the reaction mixture indicating the formation of AuNPs on the GluN/Alg composite. UV–vis spectroscopy within the range of 300 to 600 nm was employed to monitor this process

• ) using a nanoPartica Horiba SZ-100 instrument. Thermal analysis through thermogravimetry (TGA) was performed using a LabSys evo S60/58988 Thermoanalyzer (Setaram, France). The oven-dried powder of both blank nanocomposite GluN/Alg and synthesized composite AuNPs@GluN/Alg underwent heating from 30 to 800

•  2E,F demonstrates the profound effect of the reaction time on AuNP formation under heating at 70 °C. The SPR band of the AuNPs only becomes evident after 40 min of heating, with the absorbance values peaking at 100 min, and the λmax values stabilize after this duration. Thus, the optimal conditions

A low-kiloelectronvolt focused ion beam strategy for processing low-thermal-conductance materials with nanoampere currents

• Annalena Wolff,
• Nico Klingner,
• William Thompson,
• Yinghong Zhou,
• Jinying Lin and
• Yin Xiao

Beilstein J. Nanotechnol. 2024, 15, 1197–1207, doi:10.3762/bjnano.15.97

• heating effects that lead to noticeable changes in nanostructure deposition geometry during FEBID processes have recently been published [19]. These approaches, a thorough understanding of the parameters that govern the beam-induced heat damage as well as open source software, would also be beneficial for

• working at cryogenic sample temperatures, [16], short beam dwell times [16], as well as employing different scan strategies [16]. This work builds on previously reported experiments [17] and looks at the effect of the ion energy on the ion beam-induced sample heating to maintain nanoampere beam currents

• 160 ps, just before the arrival of the next ion in a 1 nA beam, the central region below the impact point of that ion, has cooled down to 80 °C. Figure 2 shows the contour plots of the mid-plane collagen sample temperature at t = 160 ps for a 5 keV ion. The ion cascade cumulative and adjacent heating

Direct electron beam writing of silver using a β-diketonate precursor: first insights

• Katja Höflich,
• Krzysztof Maćkosz,
• Chinmai S. Jureddy,
• Aleksei Tsarapkin and
• Ivo Utke

Beilstein J. Nanotechnol. 2024, 15, 1117–1124, doi:10.3762/bjnano.15.90

• , a good deposition rate was observed. After several hours, condensation became visible, which could be avoided by heating the substrate to a temperature of 60 °C. At this substrate temperature, the spatial selectivity of the direct writing was maintained with only a very weak contribution of purely

• for experiments to roughly 2 h since the evaporated precursor would start to crystallize at the crucible cap. Heating of the sample was realized with a Kleindiek MHS (Micro Heating Stage), which allowed us to keep the substrate temperature constant at 60 °C throughout the whole experiment. The

• energy for migration. The difference between planar and spot deposit is the thickness of the deposit itself. While the silicon substrate suppresses beam-induced heating because of its high thermal conductivity, the deposit itself is most probably a bad heat conductor [39]. Consequently, a temperature

Unveiling the potential of alginate-based nanomaterials in sensing technology and smart delivery applications

• Shakhzodjon Uzokboev,
• Khojimukhammad Akhmadbekov,
• Ra’no Nuritdinova,
• Salah M. Tawfik and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2024, 15, 1077–1104, doi:10.3762/bjnano.15.88

• a plasmonic nanoparticle lattice regulates wrinkling by plasmonic heating [119]. Another study compared the humidity sensing capabilities of ZnO nanoparticles and nanotetrapods and found that the nanotetrapods were five times more sensitive to humidity than the nanoparticles [120]. The humidity

Effect of wavelength and liquid on formation of Ag, Au, Ag/Au nanoparticles via picosecond laser ablation and SERS-based detection of DMMP

• Sree Satya Bharati Moram,
• Chandu Byram and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1054–1069, doi:10.3762/bjnano.15.86

• size and composition, making it a preferred choice for nanomaterials synthesis [2][3][4][5]. The process involves laser plasma interacting with a metal in a liquid; it excites electrons, which then generates atomic vibrations within a few picoseconds, causing rapid heating, melting, and explosive

Atomistic insights into the morphological dynamics of gold and platinum nanoparticles: MD simulations in vacuum and aqueous media

• Evangelos Voyiatzis,
• Eugenia Valsami-Jones and
• Antreas Afantitis

Beilstein J. Nanotechnol. 2024, 15, 995–1009, doi:10.3762/bjnano.15.81

• spectrum of possible applications, NPs have the potential to profoundly influence society [14]. Despite the numerous studies and advances [15][16][17][18][19][20], the rational design of NPs, especially the prediction of their structural modifications in industrial processes, such as rapid heating or

• (2100 K), that is, the melting point of bulk Au (Pt), in the isothermal-isobaric (NPT) ensemble at 101.3 kPa with a constant heating rate of 10 K/ns. The Langevin thermostat and the Nosè–Hoover barostat [61] are employed with coupling times of 0.1 and 1.0 ps, respectively. When the heating stage is

• high heating and cooling rates compared to the experimental ones, it has been shown to yield representative structures that are in good agreement with the ones observed via X-ray diffraction for a number of nanomaterials such as CuO NPs [62], TiO2 NPs [63], as well as carbon [64] and Ag [65

Synthesis of silver–palladium Janus nanoparticles using co-sputtering of independent sources: experimental and theorical study

• Maria J. Martínez-Carreón,
• Francisco Solís-Pomar,
• Abel Fundora,
• Claudio D. Gutiérrez-Lazos,
• Sergio Mejía-Rosales,
• Hector N. Fernández-Escamilla,
• Jonathan Guerrero-Sánchez,
• Manuel F. Meléndrez and
• Eduardo Pérez-Tijerina

Beilstein J. Nanotechnol. 2024, 15, 808–816, doi:10.3762/bjnano.15.67

• nanoparticles, by the wet reduction method using palladium and silver hydroxide colloids as precursors, to study hydrogen absorption; the size of these BNPs was 6–7 nm. However, inhomogeneous nanoparticles were obtained because Ag fractions were found on the surface, which were increased by heating the samples

Effect of repeating hydrothermal growth processes and rapid thermal annealing on CuO thin film properties

• Monika Ozga,
• Eunika Zielony,
• Aleksandra Wierzbicka,
• Anna Wolska,
• Marcin Klepka,
• Marek Godlewski,
• Bogdan J. Kowalski and
• Bartłomiej S. Witkowski

Beilstein J. Nanotechnol. 2024, 15, 743–754, doi:10.3762/bjnano.15.62

• (Chempur) with a concentration of Cu(II) ions of 1 mM was prepared. The mixture was then precipitated by adding NaOH until a pH of 6.5 was attained. Subsequently, the so-prepared solution along with the substrate was placed in a reaction vessel and uniformly heated utilizing an induction cooker (heating

• , AccuThermo AW610, Allwin21) at 450 °C for 5 min. The heating rate was 45 °C/s. This thermal processing took place in an O2/N2 atmosphere at a 1:1 ratio. The complete sequence of the hydrothermal growth process and rapid thermal annealing steps is referred to as the HT+RTA cycle. Samples that underwent this

Gold nanomakura: nanoarchitectonics and their photothermal response in association with carrageenan hydrogels

• Nabojit Das,
• Vikas,
• Akash Kumar,
• Sanjeev Soni and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 678–693, doi:10.3762/bjnano.15.56

• hydrogels) is shown in Figure 8. The net temperature rise of the gold nanomakura suspension and deionized water during visible broadband irradiation ON (heating) and OFF (cooling) for 1200 seconds each, measured using a “K-type” thermocouple is shown in Figure 8. Figure 8a shows the heating and cooling of

• gold nanoparticle suspensions of CTAB-AuNM, MTAB-AuNM, and DTAB-AuNM, respectively, whereas Figure 8b shows heating and cooling of DTAB-AuNR and CTAB-AuNR, respectively. From Figure 8a, it was observed that the temperature of deionized water reached up to ≈3 °C under irradiation with a light source

• Figure 8b. Further, in the OFF case (cooling), the exponential decay of the temperature in the nanoparticle suspension was observed. The rise in temperature of the powdered nanoparticles and of nanoparticles incorporated in hydrogel beads during visible broadband irradiation in the ON case (heating) for

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

Radiofrequency enhances drug release from responsive nanoflowers for hepatocellular carcinoma therapy

• Yanyan Wen,
• Ningning Song,
• Yueyou Peng,
• Weiwei Wu,
• Qixiong Lin,
• Minjie Cui,
• Rongrong Li,
• Qiufeng Yu,
• Sixue Wu,
• Yongkang Liang,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2024, 15, 569–579, doi:10.3762/bjnano.15.49

• was used to characterize the CUR-Fe@MnO2 NFs, which appeared flower-like with a size of 96.27 nm. The in vitro experimental data showed that RF enhanced the degradation of CUR-Fe@MnO2 NFs to release Mn2+ and CUR. The cytotoxicity test results indicated that after RF heating, the CUR-Fe@MnO2 NFs

• degrading MnO2 to release Mn2+ and lysing the CUR layer to release CUR. Mn2+ was completely released under the simulated TME condition by RF heating to 41 ± 1 °C for 20 min (Figure 4b). Up to 80% of the Mn2+ was released without RF heating. Additionally, only 7.3% of the Mn2+ was released at pH 7.4, but

• this percentage increased to 42% at pH 5.0 (Figure 4a). These results indicate that RF heating enhances degradation of NFs. Due to their structure, CUR-Fe@MnO2 NFs efficiently increased the drug loading efficiency (DLE) of CUR and improved its stability. The drug encapsulation efficiency (DEE) and DLE

Electron-induced deposition using Fe(CO)₄MA and Fe(CO)₅ – effect of MA ligand and process conditions

• Hannah Boeckers,
• Atul Chaudhary,
• Petra Martinović,
• Amy V. Walker,
• Lisa McElwee-White and
• Petra Swiderek

Beilstein J. Nanotechnol. 2024, 15, 500–516, doi:10.3762/bjnano.15.45

• with more than 90 atom % Fe were obtained [19], presumably related to electron beam heating effects. However, attempts to purify deposits with initial Fe contents of only 40 atom % by annealing up to 700 °C led to phase segregation into a highly pure and crystalline Fe phase and a carbonaceous material

• applied that enable beam-induced heating of the deposit and, thus, enhance additional thermal reactions [19]. Furthermore, the somewhat better performance of Fe2(CO)9 [19] is obtained at the cost of a significantly lower volatility as compared to Fe(CO)5 [48]. A strategy that has not been explored so far

Aero-ZnS prepared by physical vapor transport on three-dimensional networks of sacrificial ZnO microtetrapods

• Veaceslav Ursaki,
• Tudor Braniste,
• Victor Zalamai,
• Emil Rusu,
• Vladimir Ciobanu,
• Vadim Morari,
• Daniel Podgornii,
• Pier Carlo Ricci,
• Rainer Adelung and
• Ion Tiginyanu

Beilstein J. Nanotechnol. 2024, 15, 490–499, doi:10.3762/bjnano.15.44

• final ZnS aero-semiconductor material is produced in the second chamber by heating the ZnS/ZnO core–shell structures in a H2 atmosphere. Thus, the sacrificial ZnO template is dissolved from the ZnS/ZnO core–shell structures. In contrast, in this paper, all technological procedures occur in a single

Heat-induced morphological changes in silver nanowires deposited on a patterned silicon substrate

• Elyad Damerchi,
• Sven Oras,
• Edgars Butanovs,
• Allar Liivlaid,
• Mikk Antsov,
• Boris Polyakov,
• Annamarija Trausa,
• Veronika Zadin,
• Andreas Kyritsakis,
• Loïc Vidal,
• Karine Mougin,
• Siim Pikker and
• Sergei Vlassov

Beilstein J. Nanotechnol. 2024, 15, 435–446, doi:10.3762/bjnano.15.39

• NW networks is in highly flexible transparent film heaters [15]. In recent years, Ag NWs have garnered attention as a key element in neuromorphic computing devices [16]. In the context of the applications mentioned, Ag NWs are subjected to elevated temperatures caused by Joule heating [17]. Moreover

• were then heated to different temperatures in air, and the behavior of suspended as opposed to the adhered part under heating was compared. Experiments are supplemented with molecular dynamics (MD) and finite element method (FEM) simulations. Materials and Methods Preparation of samples Silver NWs with

• out in a muffle furnace (NABERTHERM, L-091H1RN-240). Samples were placed into the furnace that was already preheated to the target temperature, then they were removed after 10 min from the hot furnace, and were naturally cooled in air at room temperature. The heating time (10 min) was chosen for

Modulated critical currents of spin-transfer torque-induced resistance changes in NiCu/Cu multilayered nanowires

• Mengqi Fu,
• Roman Hartmann,
• Julian Braun,
• Sergej Andreev,
• Torsten Pietsch and
• Elke Scheer

Beilstein J. Nanotechnol. 2024, 15, 360–366, doi:10.3762/bjnano.15.32

• , Supporting Information File 1). It results from Joule heating due to the high current density rather than from spin-related effects. Therefore, in order to visualize the spin-related features, the reduced differential resistance (dV/dI)red was obtained by subtracting the background curve measured at µ0H

Determining by Raman spectroscopy the average thickness and N-layer-specific surface coverages of MoS₂ thin films with domains much smaller than the laser spot size

• Felipe Wasem Klein,
• Jean-Roch Huntzinger,
• Vincent Astié,
• Damien Voiry,
• Romain Parret,
• Houssine Makhlouf,
• Sandrine Juillaguet,
• Jean-Manuel Decams,
• Sylvie Contreras,
• Périne Landois,
• Ahmed-Azmi Zahab,
• Jean-Louis Sauvajol and
• Matthieu Paillet

Beilstein J. Nanotechnol. 2024, 15, 279–296, doi:10.3762/bjnano.15.26

• monotonically, reversibly, and quasi-linearly with Pλ (see inset of Figure 1). For MoS2, we found an increase rate of 25–30 °C/mW for monolayers (1L-MoS2) and 40–45 °C/mW for bilayers (2L-MoS2). Usual effects of sample heating are the frequency shift of the phonon modes and their concomitant broadening. In

Ultrasensitive and ultrastretchable metal crack strain sensor based on helical polydimethylsiloxane

• Shangbi Chen,
• Dewen Liu,
• Weiwei Chen,
• Huajiang Chen,
• Jiawei Li and
• Jinfang Wang

Beilstein J. Nanotechnol. 2024, 15, 270–278, doi:10.3762/bjnano.15.25

• responsiveness in quantifying the extent of flexion. Figure 4a illustrates the relationship between relative resistance change and temperature. A mandrel wrapped by the helical sensor undergoes expansion under external heating, resulting in alterations in helical diameter and resistance output. The findings

Vinorelbine-loaded multifunctional magnetic nanoparticles as anticancer drug delivery systems: synthesis, characterization, and in vitro release study

• Zeynep Özcan and
• Afife Binnaz Hazar Yoruç

Beilstein J. Nanotechnol. 2024, 15, 256–269, doi:10.3762/bjnano.15.24

• ]. Many well-designed agents have been developed for photothermal therapy, including carbon, metal, and organic nanocomposites [21]. Due to their superparamagnetic and heating potential, Fe3O4 nanoparticles have recently garnered attention, particularly in photothermal therapy research. Dopamine (DA) is a

• abovementioned paper. It was demonstrated through this study that as the amount of PDA polymer increased, both photothermal heating efficiency and drug release decreased, while the drug release rate increased when photothermal heating was applied. Fe3O4 nanoparticles with adjustable magnetic properties and

• min of laser irradiation. All drug-loaded nanostructures reached a heating temperature of 40 °C after 3 min and did not exceed a maximum temperature of 46 °C. These findings indicate a promising potential for applying these nanostructures in photothermal therapy. Figure 5c presents the results of the

Ion beam processing of DNA origami nanostructures

• Leo Sala,
• Agnes Zerolová,
• Violaine Vizcaino,
• Alain Mery,
• Alicja Domaracka,
• Hermann Rothard,
• Philippe Boduch,
• Dominik Pinkas and
• Jaroslav Kocišek

Beilstein J. Nanotechnol. 2024, 15, 207–214, doi:10.3762/bjnano.15.20

• irradiation of samples, a Faraday cup is inserted and the ratio between the Faraday cup and slit currents is determined and allows for calculating the reached projectile fluence. Fluxes were kept at or below 2 × 109 ions·cm−2·s−1 to prevent macroscopic sample heating. Projectile fluences ranged from 1012 to

• this decrease in height to localized sample heating, which can desorb residual H2O and loosely bound DNA radiolysis products especially in vacuum. We performed macroscopic sample heating experiments (Supporting Information File 1, Figure S1), and we detected an observable height loss starting from 150

• °C. This is consistent with what has been observed in heating experiments on dry DNA origami in Ar atmosphere [38]. At 250 °C, it has been observed that the nanostructures begin to be pyrolyzed [39], plausibly leaving inorganic residues such as Mg and P [38]. It is worth mentioning that neither 250

Graphene removal by water-assisted focused electron-beam-induced etching – unveiling the dose and dwell time impact on the etch profile and topographical changes in SiO₂ substrates

• Aleksandra Szkudlarek,
• Jan M. Michalik,
• Inés Serrano-Esparza,
• Zdeněk Nováček,
• Veronika Novotná,
• Piotr Ozga,
• Czesław Kapusta and
• José María De Teresa

Beilstein J. Nanotechnol. 2024, 15, 190–198, doi:10.3762/bjnano.15.18

• confocal Raman Alpha 300 M+ from WITec, which combines a Raman spectrograph with a confocal microscope. A laser with a 532 nm wavelength, spot size of 1 μm, and power fixed at 1 mW was used to avoid sample heating. The confocal microscope gives a higher lateral resolution than conventional optical

Modification of graphene oxide and its effect on properties of natural rubber/graphene oxide nanocomposites

• Nghiem Thi Thuong,
• Le Dinh Quang,
• Vu Quoc Cuong,
• Cao Hong Ha,
• Nguyen Ba Lam and
• Seiichi Kawahara

Beilstein J. Nanotechnol. 2024, 15, 168–179, doi:10.3762/bjnano.15.16

• g of NaNO3 and 3 g of KMnO4 were added to the mixture. The temperature was maintained between 0–5 °C, and the system was kept for 2 h before heating up to 35 °C and kept for 1 h. After that, water was added to increase the temperature to 90 °C for 30 min, and 10 mL of H2O2 was dropped into the flask

• after drying the solution in a heating oven. Vinyltriethoxysilane was used to modify GO [25][32] and it was bonded on the GO surface by the sol–gel method, as shown in Figure 1. Firstly, GO (0.4 g) was thoroughly dispersed in distilled water. After that, VTES (1.8 g) was added to the mixture, followed

• gravimetric analysis (TGA) of the samples was performed on a TA Q500 instrument. The temperature was increased at a heating rate of 10 °C /min from room temperature to 900 °C in air atmosphere. The morphology of the DPNR/GO-VTES was observed with field-emission scanning electron microscopy (FE-SEM) performed