Beilstein J. Nanotechnol.2014,5, 696–710, doi:10.3762/bjnano.5.82
photoexcited to generate hotelectrons, which are injected from the surface of the gold nanoparticles to the CB of TiO2. Meanwhile, the compensative electrons can be transferred from a certain type of donor in the solution to the gold nanoparticles [76]. The proposed charge transfer mechanism is shown in
hotelectrons can cross over or transfer through the potential barrier of the Schottky junction at the metal–semiconductor interface [68][88].
It is noteworthy that the plasmonic nanostructures can play different roles under UV and visible light. Under UV light, the plasmonic nanostructures play the
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Figure 1:
Schematic steps for the photocatalytic reactions occuring on the surface of a semiconductor. Adapte...
Beilstein J. Nanotechnol.2011,2, 665–673, doi:10.3762/bjnano.2.71
temperature the most important factor for the ion diffusion in the plasma [21]. In turn the transport coefficient of these particles determines the growth kinetics of the nanoparticles. The majority of ions and hotelectrons in our experiments were produced from the excited argon sheath gas.
By reacting the
TMS precursor in the vapour phase with plasma-induced hotelectrons, the rate-limited nucleation reaction step is accelerated and a significantly higher reaction rate is sustained at lower temperatures than is possible with thermal activation alone [9]. An important advantage of the plasma process for
decomposition of TMS has been shown. The reaction is initiated by collisions between electrons and neutral molecules of TMS. By reacting the TMS precursors in the vapour phase with plasma-induced hotelectrons, the nucleation reaction step is accelerated and a significantly higher reaction rate is sustained at
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Figure 1:
Calculated values for the smallest thermodynamically stable particle radius rcrit at different part...