Hierarchical coassembly of DNA–triptycene hybrid molecular building blocks and zinc protoporphyrin IX

• Rina Kumari,
• Sumit Singh,
• Mohan Monisha,
• Sourav Bhowmick,
• Anindya Roy,
• Neeladri Das and
• Prolay Das

Beilstein J. Nanotechnol. 2016, 7, 697–707, doi:10.3762/bjnano.7.62

• desorption/ionization time-of-flight (MALDI-TOF). The biologically relevant photosensitizer Zn PpIX was used to direct the hybridization-mediated self-assembly of DNA–TPA molecular building blocks as well as a model guest molecule within the DNA–TPA supramolecular self-assembly. The formation of fiber-like

Silica-coated upconversion lanthanide nanoparticles: The effect of crystal design on morphology, structure and optical properties

• Uliana Kostiv,
• Miroslav Šlouf,
• Hana Macková,
• Alexander Zhigunov,
• Hana Engstová,
• Katarína Smolková,
• Petr Ježek and
• Daniel Horák

Beilstein J. Nanotechnol. 2015, 6, 2290–2299, doi:10.3762/bjnano.6.235

• photosensitizer [43]. Upconversion OM–NaYF4:Yb3+/Er3+ nanoparticles were excited by near-infrared light at 980 nm, i.e., at the Yb3+ absorption maximum. Photons were emitted at 520, 545 and 660 nm in the fluorescence spectra of the OM–NaYF4:Yb3+/Er3+ nanoparticles. The NaYF4:Yb3+/Er3+ nanoparticles were

Novel ZnO:Ag nanocomposites induce significant oxidative stress in human fibroblast malignant melanoma (Ht144) cells

• Syeda Arooj,
• Samina Nazir,
• Akhtar Nadhman,
• Nafees Ahmad,
• Bakhtiar Muhammad,
• Ishaq Ahmad,
• Kehkashan Mazhar and
• Rashda Abbasi

Beilstein J. Nanotechnol. 2015, 6, 570–582, doi:10.3762/bjnano.6.59

• thus exciting the photosensitizer to produce reactive oxygen species (ROS) such as singlet oxygen (1O2) and hydroxyl radicals (HO•) [6][7]. Photo-oxidation holds promises for the targeted treatment and controlled elimination of cancer cells [8]. ZnO NPs have also shown photo-oxidative anticancer

Enhanced photocatalytic hydrogen evolution by combining water soluble graphene with cobalt salts

• Jing Wang,
• Ke Feng,
• Hui-Hui Zhang,
• Bin Chen,
• Zhi-Jun Li,
• Qing-Yuan Meng,
• Li-Ping Zhang,
• Chen-Ho Tung and
• Li-Zhu Wu

Beilstein J. Nanotechnol. 2014, 5, 1167–1174, doi:10.3762/bjnano.5.128

• graphene. The photocatalytic hydrogen evolution activity of the catalyst was tested by using triethanolamine (TEOA) as electron donor and eosin Y (EY) as the photosensitizer under LED irradiation at 525 nm. Hydrogen was produced constantly even after 20 h, and the turnover number (TON) reached 148 (H2/Co

• graphene in terms of the unique spectroscopic property of photosensitizer EY [51]. The result stimulated us to explore graphene-based hydrogen evolution systems with earth-abundant co-catalysts. In the present work, we report a new water-soluble graphene–cobalt-based hydrogen evolution system, showing a

• 5.6 times higher efficiency than that of the same system without graphene. Herein, sulfonated-graphene (G-SO3), being water-soluble and partially reduced [52][53], serves as a great platform [41][51] to support the catalysts. With TEOA (triethanolamine) as an electron donor, EY as a photosensitizer

Growth and characterization of CNT–TiO₂ heterostructures

• Yucheng Zhang,
• Ivo Utke,
• Johann Michler,
• Gabriele Ilari,
• Marta D. Rossell and
• Rolf Erni

Beilstein J. Nanotechnol. 2014, 5, 946–955, doi:10.3762/bjnano.5.108

• instrumentations. Efficiency enhancement mechanisms for photocatalysis using CNT–TiO2 nanocomposites. (a) CNT scavenges electrons generated in TiO2, resulting in excessive holes on the surface for redox actions. (b) CNT acts as a photosensitizer and injects electrons and holes into TiO2 for redox actions. (c) CNT

Nanostructure sensitization of transition metal oxides for visible-light photocatalysis

• Hongjun Chen and
• Lianzhou Wang

Beilstein J. Nanotechnol. 2014, 5, 696–710, doi:10.3762/bjnano.5.82

• oxides can realize visible-light photocatalysis by virtue of a narrow bandgap of photosensitizers, which is fundamentally different from the metal or non-metal doped ones. The photosensitizer can be an organic dye, an inorganic complex, and different nanostructures. Normally, photosensitizers have a

• bandgap, which is, narrower and has a higher CB minimum or lowest unoccupied molecular orbital (LUMO) in comparison with wide-bandgap transition metal oxides. Because a photosensitizer normally has a narrow bandgap, it can absorb the visible sunlight and even the infrared sunlight to generate electron

• –hole pairs. Then, if coupled with a transition metal oxide, the photogenerated electrons can be easily transferred from the CB minimum of the photosensitizer or LUMO to that of a transition metal oxide. Thus the efficient charge separation in the metal oxide-photosensitizer nanocomposites facilitates

Energy transfer in complexes of water-soluble quantum dots and chlorin e6 molecules in different environments

• Irina V. Martynenko,
• Anna O. Orlova,
• Vladimir G. Maslov,
• Alexander V. Baranov,
• Anatoly V. Fedorov and
• Mikhail Artemyev

Beilstein J. Nanotechnol. 2013, 4, 895–902, doi:10.3762/bjnano.4.101

• example, the photoinduced reversible electron transfer between QD and molecule, and the formation of QD photoluminescence deactivation centers at the place where the molecule is attached to the QD. Chlorin e6 (Ce6) is one of the tetrapyrrole compounds widely used as a photosensitizer. Photophysical

• (ethylene terephthalate) track membranes that can be utilized as an element of microfluidic devices [8]. Experimental Chemicals Bis-N-methyl-D-glucamine salt of chlorin e6 (photosensitizer “Photoditazin”) was purchased from VETA Grand Ltd. Photoditazin has a QY of 9% in aqueous solution. Trioctylphosphine

Self-assembled monolayers and titanium dioxide: From surface patterning to potential applications

• Yaron Paz

Beilstein J. Nanotechnol. 2011, 2, 845–861, doi:10.3762/bjnano.2.94