Beilstein J. Nanotechnol.2014,5, 1235–1244, doi:10.3762/bjnano.5.137
the charge transfer capabilities have been discussed as follows. Figure 4 shows photographs of the polymer P3HT and the polymernanocomposites of P3HT:CISe, P3HT:CIGSe and P3HT:CZTSe nanocrystals in toluene exposed to a UV lamp. A clear color gradation from left to right is visible. The first one
quenching and charge transfer capabilities of each of the synthesized nanocrystals CISe, CIGSe and CZTSe when forming polymernanocomposites with P3HT. Figure 5a–c shows the emission intensity (λmax = 580 nm) profiles of nanocomposites of CISe:P3HT, CIGSe:P3HT and CZTSe:P3HT dispersed in toluene. As evident
in Figure 5a, a more pronounced decrease of the emission intensity of the P3HT:CZTSe composite is observed with an increasing CZTSe concentration compared to P3HT:CISe and P3HT:CIGSe polymernanocomposites. This corroborates the suggestion that a more efficient electron transfer is taking place
PDF
Figure 1:
The crystal structures of (a) CISe, (b) CIGSe and (c) CZTSe.
Beilstein J. Nanotechnol.2010,1, 94–100, doi:10.3762/bjnano.1.11
. For an aspect ratio of 3, NRs polymernanocomposites with a maximum transmission of 93% in the region between 700–800 nm have been fabricated.
CTA nanocomposites
The 9–15 µm thin CTA nanocomposite layers containing NRs (aspect ratio 6) on glass exhibit bright orange luminescence (see Figure 9). The