Conjugated photothermal materials and structure design for solar steam generation

• Chia-Yang Lin and
• Tsuyoshi Michinobu

Beilstein J. Nanotechnol. 2023, 14, 454–466, doi:10.3762/bjnano.14.36

• from 300 to 2500 nm and reflectance, transmission, and radiative relaxation must not be significant in order to maximize the energy absorbed from the sun and convert it into thermal energy (Figure 2b). Photothermal conversion efficiency Solar energy can be converted into various forms of energy such as

• nonradiative relaxation of excited electrons to the ground state. Depending on the interaction mechanism, photothermal phenomena are classified into three categories, namely plasmonic local heating of metals, nonradiative relaxation of semiconductors, and thermal vibration relaxation of conjugated molecules

• either undergo radiative relaxation in the form of photons or nonradiative relaxation in the form of phonons (heat) to release and transfer energy to impurities/defects or dangling bonds on the material surface. When energy is released in the form of phonons, local heating of the lattice is induced

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• various material phenomena other than bandgap absorption for heat generation in nanoparticles (NPs), leading to a rapid proliferation of materials for the same. For example, organic materials undergo rapid internal relaxation by the PT effect and are often desired in cancer treatment research as they

• product of ωτ, where τ is the relaxation time of the free electron gas) is much higher than unity, thus leading to an approximation that there is no damping. Hence ignoring the damping term in Equation 5, we get It follows also that under plasmon resonance conditions ε1 < −εm, εm is the dielectric

• critical for predicting and understanding PT performance, for which a discussion on the same is presented next. 2.3 Relaxation mechanisms of plasmons – the conversion of photons to heat When photons strike a plasmonic nanoparticle, plasmon excitations result in changes to the electron cloud thermal

Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• encapsulated in these ethyl cellulose nanoparticles by dissolving it in the hydrophobic droplet phase of the starting nanoemulsions. The drug release from the nanoparticles appeared to follow a coupled diffusion/relaxation model. Nanoemulsions containing ethyl cellulose have also been prepared at room

Bismuth-based nanostructured photocatalysts for the remediation of antibiotics and organic dyes

• Akeem Adeyemi Oladipo and
• Faisal Suleiman Mustafa

Beilstein J. Nanotechnol. 2023, 14, 291–321, doi:10.3762/bjnano.14.26

• photocatalysis over the past few years due to their distinct optical and electronic characteristics [42][88][106]. Simple strain relaxation and short diffusion paths are benefits of 1-D nanostructured materials and are advantageous for the separation of photogenerated carriers [102]. 1-D spindle-like BiVO4

Recent progress in cancer cell membrane-based nanoparticles for biomedical applications

• Qixiong Lin,
• Yueyou Peng,
• Yanyan Wen,
• Xiaoqiong Li,
• Donglian Du,
• Weibin Dai,
• Wei Tian and
• Yanfeng Meng

Beilstein J. Nanotechnol. 2023, 14, 262–279, doi:10.3762/bjnano.14.24

• by enhancing proton relaxation in tissues [120]. Among them, superparamagnetic iron oxides (SPIONs) are widely used with numerous advantages, such as small size, colloidal stability, low toxicity, magnetic heating properties, and enhanced molecular MRI [121]. However, SPIONs cannot be effectively

Spin dynamics in superconductor/ferromagnetic insulator hybrid structures with precessing magnetization

• Yaroslav V. Turkin and
• Nataliya Pugach

Beilstein J. Nanotechnol. 2023, 14, 233–239, doi:10.3762/bjnano.14.22

• ; Introduction Creation and manipulation of spin flows in superconducting hybrid systems have become a very active research area during the last decade because of the possibility to create spin supercurrents with much larger relaxation lengths and spin lifetimes [1]. The creation of persistent spin currents in

• spin relaxation processes, but we do not take into account any spin relaxation mechanisms within our model for a superconductor. We should mention that both spin pumping mechanisms in superconductors and normal metals are determined by the penetration of nonequillibrium spin density from the interface

• . In metals, such a penetration is limited by the spin flip scattering, while inside the superconductor, the spin relaxation time is usually much longer. Thus, induced magnetization and spin current in our problem are determined mainly by the competition between spin singlet and spin triplet orders [34

Cyclodextrins as eminent constituents in nanoarchitectonics for drug delivery systems

• Makoto Komiyama

Beilstein J. Nanotechnol. 2023, 14, 218–232, doi:10.3762/bjnano.14.21

• smaller band overlap of the trans/cis isomers, and thus the photoisomerization proceeds almost completely in both directions. Moreover, thermal relaxation of the cis isomer is negligible [52]. Like azobenzenes, only the trans isomer forms inclusion complexes with CyDs. In Figure 3b, carboxymethyl

• the entry of the resultant nanoparticles to cells, the S-nitrosothiol reacts with glutathione to release NO, which relieves hypoxia at tumor sites through NO-mediated blood vessel relaxation. Furthermore, the NO reacts with ROSs, generated by light-activation of chlorin e6, to form ONOO− and other

Characterisation of a micrometer-scale active plasmonic element by means of complementary computational and experimental methods

• Ciarán Barron,
• Giulia Di Fazio,
• Samuel Kenny,
• Silas O’Toole,
• Robin O’Reilly and
• Dominic Zerulla

Beilstein J. Nanotechnol. 2023, 14, 110–122, doi:10.3762/bjnano.14.12

• information extracted in both cases does not depend on the drive frequency, given the thermal relaxation time of such a metallic element on a sapphire substrate is of the order of nanoseconds, and as such there is no need for matching drive frequencies. AFM scans were performed on a 30 × 30 μm2 window with a

Upper critical magnetic field in NbRe and NbReN micrometric strips

• Zahra Makhdoumi Kakhaki,
• Antonio Leo,
• Federico Chianese,
• Loredana Parlato,
• Giovanni Piero Pepe,
• Angela Nigro,
• Carla Cirillo and
• Carmine Attanasio

Beilstein J. Nanotechnol. 2023, 14, 45–51, doi:10.3762/bjnano.14.5

• candidates for the realization of fast superconducting nanowire single-photon detectors (SNSPDs) [1][2][3][4]. Apart from the reduced values of the superconducting gap and short quasi-particle relaxation times [5], the property that makes these materials appropriate to be used as SNSPDs is the high value of

• rotation and relaxation studies [13] and large values of the upper critical magnetic fields [11][14], which are above the Pauli paramagnetic limit [15][16]. In the case of thin films, the structure of NbRe is polycrystalline with grains of small dimensions, typically of the order of 2–3 nm [7][8][17

The influence of structure and local structural defects on the magnetic properties of cobalt nanofilms

• Alexander Vakhrushev,
• Aleksey Fedotov,
• Olesya Severyukhina and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2023, 14, 23–33, doi:10.3762/bjnano.14.3

• cobalt atom spins for ideal crystal hexagonal close-packed lattice (a), (b), (c) and nanofilm structure (d), (e), (f) formed in the numerical experiment at a deposition temperature of 300 K, spin relaxation time 100 ps, and external magnetic field value of 1.0 T. Changes in spin temperature under a

Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition

• Mykhailo Nahorniak,
• Pamela Pasetto,
• Jean-Marc Greneche,
• Volodymyr Samaryk,
• Sandy Auguste,
• Anthony Rousseau,
• Nataliya Nosova and
• Serhii Varvarenko

Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2

• typical for the presence of superparamagnetic relaxation phenomena suggested a very small size (about 10 nm compared to results from the literature) for the synthesized nanoparticles, which was consistent with electron and XRD diffraction results, as well as TEM results. Different fitting models can be

• sample. The shape of a single line at 300 K and a more pronounced ultrafine structure at 77 K indicate a decrease in superparamagnetic relaxation phenomena, probably caused by a larger size of the nanoparticles. Furthermore, the spectrum recorded at 77 K can be divided into four different components: (i

Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin

• Polina M. Kalachikova,
• Anastasia E. Goldt,
• Eldar M. Khabushev,
• Timofei V. Eremin,
• Timofei S. Zatsepin,
• Elena D. Obraztsova,
• Konstantin V. Larionov,
• Liubov Yu. Antipina,
• Pavel B. Sorokin and
• Albert G. Nasibulin

Beilstein J. Nanotechnol. 2022, 13, 1564–1571, doi:10.3762/bjnano.13.130

• –Martins pseudopotentials and double-zeta plus polarization basis set were used for structural relaxation as implemented in the SIESTA package [30][31][32][33][34][35]. The geometrically confined systems were treated in a supercell scheme allowing at least 20 Å empty space between them to make

Hydroxyapatite–bioglass nanocomposites: Structural, mechanical, and biological aspects

• Olga Shikimaka,
• Mihaela Bivol,
• Bogdan A. Sava,
• Marius Dumitru,
• Christu Tardei,
• Beatrice G. Sbarcea,
• Daria Grabco,
• Constantin Pyrtsac,
• Daria Topal,
• Andrian Prisacaru,
• Vitalie Cobzac and
• Viorel Nacu

Beilstein J. Nanotechnol. 2022, 13, 1490–1504, doi:10.3762/bjnano.13.123

• . For composites with plastic-fragile and fragile behavior, the ISE is caused by involving and developing delamination and cracking with increasing load (Figure 6), which leads to the relaxation of stress in the deformation zone and, as a result, to the decrease of hardness. SBF testing and bioactivity

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• flattening of the semicircle caused by the distribution of the relaxation time constants. Ideally, when only one time constant describes relaxation processes in the material (Debye-type response), the fit parameter α is close to 0 and there is no flattening of the semicircle. The distribution of the time

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• conversion efficiency by generating new cross-relaxation pathways between the ladder-like energy levels of Nd3+ ions and the continuous energy band of PB [10]. The strategy to generate new cross-relaxation pathways between different materials is applicable to design all kinds of enhanced photothermal agents

Influence of water contamination on the sputtering of silicon with low-energy argon ions investigated by molecular dynamics simulations

• Grégoire R. N. Defoort-Levkov,
• Alan Bahm and
• Patrick Philipp

Beilstein J. Nanotechnol. 2022, 13, 986–1003, doi:10.3762/bjnano.13.86

• region, or to relaxation of previous displacement cascades. Due to the strong interaction between silicon and oxygen particles, Si–O products tend to be sputtered as a cluster or the oxygen migrates into the amorphous region. The other relevant reaction products (e.g., Si–OH, Si–H2, and Si–O2) are

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• the O K-edge in nickel-doped zirconia with and without O vacancies are presented and discussed. A conclusion is given in the final section. Computational Methodology Structural relaxation First principles calculations have been performed with the Quantum-ESPRESSO code [38] using the plane waves basis

• -polarized structural relaxation calculations are then performed to determine the energetically most stable spin configuration of the Ni dopant atoms in zirconia. The relaxed configuration of ZrO2 with the Ni1 and Ni2 dopants containing no vacancies, that is, the S0 structure is cubic. This structure is

• relaxed structure of S0, ferromagnetic spin alignments are more stable compared to the antiferromagnetic configuration, and the local environment around Ni dopants assumes to a tetrahedral symmetry following the relaxation (Figure 2a,b). In the case of S1, the ferromagnetic configuration is still the most

Self-assembly of C₆₀ on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C₆₀ monolayer

• Guglielmo Albani,
• Michele Capra,
• Alessandro Lodesani,
• Alberto Calloni,
• Gianlorenzo Bussetti,
• Marco Finazzi,
• Franco Ciccacci,
• Alberto Brambilla,
• Lamberto Duò and
• Andrea Picone

Beilstein J. Nanotechnol. 2022, 13, 857–864, doi:10.3762/bjnano.13.76

• surfaces for the investigation of their intrinsic properties, the minimization of the molecule–substrate interaction is desirable [20]. Furthermore, a weak molecule/metal electronic coupling is required in organic solar cells, because metallic states promote the relaxation of photo-excitations, lowering

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• inhomogeneities. The low-temperature fraction of the residual paramagnetic phase can be deduced from the magnitude of the slow reflectivity relaxation component. It is estimated as ≈30% for x = 0.038 and ≈15% for x = 0.062 films. The minimal iron content ensuring the magnetic homogeneity of the ferromagnetic

• magnetic inhomogeneities in thin films. Individual constituents can be characterized by specific relaxation components that can be used to detect magnetic inhomogeneities and track their evolution. In addition, the peculiarities of the magnetization dynamics in magnetically inhomogeneous systems themselves

• angles were ≈2° and ≈18°. The relaxation of the electronic subsystem was monitored by the relative change in the reflection coefficient (∆R/R). Ultrafast dynamics of the magnetization was analyzed by the deviation of the angle of rotation of the polarization plane of the probing light from the

Tunable high-quality-factor absorption in a graphene monolayer based on quasi-bound states in the continuum

• Jun Wu,
• Yasong Sun,
• Feng Wu,
• Biyuan Wu and
• Xiaohu Wu

Beilstein J. Nanotechnol. 2022, 13, 675–681, doi:10.3762/bjnano.13.59

• Fermi level, ω is the angular frequency, e is the elementary charge, and τ is the carrier relaxation lifetime. In our simulation, the permittivity of the graphene monolayer is described by: where ε0 is the relative permittivity of vacuum, and hg is the thickness of the graphene, which is assumed to be

A superconducting adiabatic neuron in a quantum regime

• Marina V. Bastrakova,
• Dmitrii S. Pashin,
• Dmitriy A. Rybin,
• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Igor I. Soloviev,
• Anastasiya A. Gorchavkina and
• Arkady M. Satanin

Beilstein J. Nanotechnol. 2022, 13, 653–665, doi:10.3762/bjnano.13.57

• instantaneous eigenbasis. Numerical simulations are performed for the temperature of the bosonic thermostat at T = 50 mK. We investigated the relaxation of the excited states for both the single-well (l < l*, Figure 10a,c) and double-well (l > l*, Figure 10b,d) potential shapes. The key result is the

• suppression of the oscillations of the activation function for the neuron initialized in a superposition of two basic states. The dynamics of changes in the populations |ck(t)|2 of the energy levels for this case is shown in the insets of Figure 10 (see Figure 6 for comparison). This relaxation takes the full

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

• MoSe2 monolayer is indicated by the red arrow. The olive arrow denotes the non-radiative relaxation process. The photoluminescence emission in MoSe2 monolayer is represented by the wine red arrow. Supporting Information Supporting Information features Raman spectra of the MoSe2 flake, the absorption

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• in a less dense but more ordered structure over a large area with very few defects. During the self-assembly process, gold adatoms are ejected from the surface layer due to the relaxation of the herringbone reconstruction [68]. Several gold adatom islands, which would build up if the density of

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

• Ali Javed,
• Felix Steinke,
• Stephan Wöhlbrandt,
• Hana Bunzen,
• Norbert Stock and
• Michael Tiemann

Beilstein J. Nanotechnol. 2022, 13, 437–443, doi:10.3762/bjnano.13.36

• detail below. (We did not observe any semicircular behavior in the absence of humidity, neither before nor after thermal activation, from which we conclude that other phenomena, such as relaxation of electric dipoles, do not significantly contribute to the charge mobility.) Another way to depict the

Nanoscale friction and wear of a polymer coated with graphene

• Robin Vacher and
• Astrid S. de Wijn

Beilstein J. Nanotechnol. 2022, 13, 63–73, doi:10.3762/bjnano.13.4

• adhesion or covalent chemical bonds, would behave more like the flat graphene in our simulations and would provide additional protection. The temperature dependence of friction can potentially allow one to probe different relaxation mechanisms in the polymer [33][34]. In our previous work [23], we

• extensively investigated the temperature dependence of friction of bare PVA. However, it was not possible to extract information about specific relaxation mechanisms this way because of the dominant involvement of wear. While the graphene coating reduces wear, it does not eliminate it to a degree that we