Beilstein J. Nanotechnol.2014,5, 1553–1568, doi:10.3762/bjnano.5.167
species in the surrounding medium like O2 or water leads to singletoxygen radicals and superoxide radical anions. According to the authors, these may then act as nucleation sites. One unresolved question here is the fact that these results differ significantly from other work [16][18] where calcium
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Figure 1:
(A) ATR-FTIR spectra and (B) XRD patterns of calcium phosphates obtained from [Bmim][Cl]. The refle...
Beilstein J. Nanotechnol.2013,4, 895–902, doi:10.3762/bjnano.4.101
investigated [1][2][3][4]. The interest in complexes based on tetrapyrrole compounds has been sparked by their ability to generate singletoxygen [5]. The singletoxygen is used in different applications such as photodynamic therapy, blood plasma sterilization and wastewater treatment.
In QD/tetrapyrrole
complexes the efficiency of singletoxygen generation may be significantly increased, as compared with the free tetrapyrroles, due to an efficient photoexcitation energy transfer from the QD to the molecule. QDs have unique optical properties such as a broad absorption spectrum with extremely high
these complexes as singletoxygen generators, two conditions should be simultaneously fulfilled: 1) the ability of the tetrapyrrole molecules to generate singletoxygen upon complex formation should be maintained and 2) the effective intracomplex photoexcitation energy transfer should occur.
In QD
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Figure 1:
The absorption (solid line) and photoluminescence (dash line) spectra of QDs of different sizes and...