Beilstein J. Nanotechnol.2010,1, 75–93, doi:10.3762/bjnano.1.10
random direction and adherent rows tend to align with each other in areas of high concentration [10][60].
The arrangement of disks is not yet completely understood. The minimization and size dependence of the van der Waals contribution are supposed to be the main driving forces for the spatial
arrangement [15][51] and the size distribution along the chains [51]. Bao et al. explained the formation of disk rows by a hydrophobic interaction between the ligand tails, thus, minimizing exposure to air by maximizing the contact between the ligand tails [60]. Due to the magnetic nature of the Co disks, a
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Figure 1:
Schematic representation of the precursor concentration according to the LaMer model. The blue line...
Beilstein J. Nanotechnol.2010,1, 24–47, doi:10.3762/bjnano.1.5
the finally obtained spatialarrangement of the NPs. This basic idea of preparation and the different steps involved are summarized in the schematics shown in Scheme 1.
The first experimental realization of the above approach was demonstrated by the preparation of hexagonally ordered arrays of Au NPs
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Scheme 1:
Preparation of NPs by a reverse micelle technique. PS-b-P2VP or PS-b-P4VP is dispersed in anhydrous...