First-principles study of the structural, optoelectronic and thermophysical properties of the π-SnSe for thermoelectric applications

• Muhammad Atif Sattar,
• Najwa Al Bouzieh,
• Maamar Benkraouda and
• Noureddine Amrane

Beilstein J. Nanotechnol. 2021, 12, 1101–1114, doi:10.3762/bjnano.12.82

• is the Grüneisen parameter [9]. We used the values of θD = 240.86 and γ = 2.1875 at 300 K in the Slack’s equation to obtain the lattice thermal conductivity. The temperature dependence of the lattice thermal conductivity for the cubic π-SnSe alloy is presented in Figure 9c. From the plot, it can be

In situ transport characterization of magnetic states in Nb/Co superconductor/ferromagnet heterostructures

• Olena M. Kapran,
• Roman Morari,
• Taras Golod,
• Evgenii A. Borodianskyi,
• Vladimir Boian,
• Andrei Prepelita,
• Nikolay Klenov,
• Anatoli S. Sidorenko and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 913–923, doi:10.3762/bjnano.12.68

• ][21]. This could lead to a weakening of superconductivity in S′ layers and, thus, may explain the appearance of the third high-resistance state between P and AP states [6]. However, there should be yet another explanation for the reported strong temperature dependence of MR, seen in Figure 2a–c

• , since the magnetic state of F-layers should not exhibit strong temperature dependence in a very narrow temperature range, in which large variation of MR are observed, see Figure 2a–c, spin-triplet mechanism alone cannot explain our observation, and the domain-triggered FF mechanism should play an

9.1% efficient zinc oxide/silicon solar cells on a 50 μm thick Si absorber

• Rafal Pietruszka,
• Bartlomiej S. Witkowski,
• Monika Ozga,
• Katarzyna Gwozdz,
• Ewa Placzek-Popko and
• Marek Godlewski

Beilstein J. Nanotechnol. 2021, 12, 766–774, doi:10.3762/bjnano.12.60

• (a, c) textured and (b, d) planar solar cells studied by SEM (top row) and AFM (bottom row). (a) External quantum efficiency and (b) current voltage characteristics of ZnO/Si solar cells. Current–voltage–temperature characteristics of (a) textured and (b) planar ZnO/Si solar cells. Temperature

• dependence of basics solar cell parameters. Growth parameters of ALD films. Basic parameters of ZnO/Si solar cells extracted from a double exponential model. Funding This work was partially supported by the National Centre for Research and Development TECHMATSTRATEG1/347431/14/NCBR/2018 (PV-BLJ-SC) and the

Nickel nanoparticle-decorated reduced graphene oxide/WO₃ nanocomposite – a promising candidate for gas sensing

• Ilka Simon,
• Alexandr Savitsky,
• Rolf Mülhaupt,
• Vladimir Pankov and
• Christoph Janiak

Beilstein J. Nanotechnol. 2021, 12, 343–353, doi:10.3762/bjnano.12.28

• Ni@rGO composite without heat treatment. The temperature dependence of the magnetization was determined during several heating–cooling cycles. It was noted that with an increase in the number of cycles, the Сurie temperature of the sample increased from 345 to 357 °C. Most likely, the increase in the

• with a noncollinear spin configuration, which causes the formation of a surface spin canting due to thermal fluctuation of magnetic moments. Figure 7 shows the temperature dependence of the magnetization obtained in the course of the last measurement cycle at which, for nickel particles, ferromagnetic

A self-powered, flexible ultra-thin Si/ZnO nanowire photodetector as full-spectrum optical sensor and pyroelectric nanogenerator

• Liang Chen,
• Jianqi Dong,
• Miao He and
• Xingfu Wang

Beilstein J. Nanotechnol. 2020, 11, 1623–1630, doi:10.3762/bjnano.11.145

• energy. This is achieved by utilizing the temperature dependence of electric displacement of polar materials, which are already applied in solar cells, photodetectors, temperature sensors, and stretchable electronics [15][16][17][18]. It means that the PENGs could serve as a power source to power PDs by

Controlling the proximity effect in a Co/Nb multilayer: the properties of electronic transport

• Sergey Bakurskiy,
• Mikhail Kupriyanov,
• Nikolay V. Klenov,
• Igor Soloviev,
• Andrey Schegolev,
• Roman Morari,
• Yury Khaydukov and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1336–1345, doi:10.3762/bjnano.11.118

• effective critical temperature of the magnetic superconductor is significantly smaller than of the bulk semiconductor material. This property of the system is demonstrated in Figure 3. Figure 3a presents the temperature dependence of the pair potential in different superconducting layers for P (solid lines

• ) and AP (dashed) magnetization configurations in F-layers. In the large semiconductor electrode, the temperature dependence of the pair potential coincides with the prediction of the pure Bardeen–Cooper–Schrieffer (BCS) model. At the same time, the pair potential in thin s-layers rapidly increases near

Proximity effect in [Nb(1.5 nm)/Fe(x)]₁₀/Nb(50 nm) superconductor/ferromagnet heterostructures

• Yury Khaydukov,
• Sabine Pütter,
• Laura Guasco,
• Roman Morari,
• Gideok Kim,
• Thomas Keller,
• Anatolie Sidorenko and
• Bernhard Keimer

Beilstein J. Nanotechnol. 2020, 11, 1254–1263, doi:10.3762/bjnano.11.109

• Oe. At 13 K the saturation moment increases to msat = 40 μemu and a field above Hsat ≈ 2 kOe is needed to saturate the magnetic moment of the sample. The temperature dependence of the magnetic moment at H = 250 Oe (Figure 4b) shows that the moment is constant down to T ≈ 100 K, and grows upon further

• and (b) sample s6. Dashed tilted lines show the direction of specular reflection. The color bars show the logarithmic intensity scale. SQUID data of the s3 sample. (a) Hysteresis loop measured at T = 300 K (red) and T = 13 K (black). (b) Temperature dependence of the magnetic moment measured at H

Microwave photon detection by an Al Josephson junction

• Leonid S. Revin,
• Andrey L. Pankratov,
• Anna V. Gordeeva,
• Anton A. Yablokov,
• Igor V. Rakut,
• Victor O. Zbrozhek and
• Leonid S. Kuzmin

Beilstein J. Nanotechnol. 2020, 11, 960–965, doi:10.3762/bjnano.11.80

• anomalously large lifetime, not described by the Kramers’ theory for the escape time over a barrier under the influence of fluctuations. We explain it by the phase diffusion regime, which is evident from the temperature dependence of the switching current histograms. Therefore, phase diffusion allows for a

• then relax into one of the potential minima [24]. When barrier and noise are large, the exit from the well and the subsequent retrapping processes may occur many times at a given bias current. The most evident signature of the phase diffusion phenomenon is the temperature dependence of the switching

• range of 8–14 GHz. Experimentally measured histogram P(ISW) of switching the Josephson junction to the resistive state for the current ISW at the indicated temperatures. The inset shows the I–V curve of the junction at 20 mK. Temperature dependence of the mean switching current (left axis, red dots) and

Band tail state related photoluminescence and photoresponse of ZnMgO solid solution nanostructured films

• Vadim Morari,
• Aida Pantazi,
• Nicolai Curmei,
• Vitalie Postolache,
• Emil V. Rusu,
• Marius Enachescu,
• Ion M. Tiginyanu and
• Veaceslav V. Ursaki

Beilstein J. Nanotechnol. 2020, 11, 899–910, doi:10.3762/bjnano.11.75

• optical absorption (OA) spectroscopy investigations in w-ZnMgO films produced by RF-MBE in the composition range x = 0.00–0.37 [36] and x = 0.27–0.55 [10], respectively. The observed Stokes shifts were indicative of the presence of band tail states introduced by alloying, while the “S-shaped” temperature

• dependence of the maximum PL emissions was explained in terms of exciton localization in potential traps induced by Mg compositional fluctuations. The fluctuations in the local arrangement of Mg and Zn atoms have been also recently investigated by means of cathodoluminescence (CL) and OA spectroscopy in c

Transition from freestanding SnO₂ nanowires to laterally aligned nanowires with a simulation-based experimental design

• Jasmin-Clara Bürger,
• Sebastian Gutsch and
• Margit Zacharias

Beilstein J. Nanotechnol. 2020, 11, 843–853, doi:10.3762/bjnano.11.69

• presents the pressure and temperature dependence of the diffusion coefficient D, and Equation 2 describes the covered distance as a function of time, t, adapted from [28]: where T and p are the process temperature and the process pressure, respectively, and Dn is the tabular value of the diffusion

Epitaxial growth and superconducting properties of thin-film PdFe/VN and VN/PdFe bilayers on MgO(001) substrates

• Wael M. Mohammed,
• Igor V. Yanilkin,
• Amir I. Gumarov,
• Airat G. Kiiamov,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2020, 11, 807–813, doi:10.3762/bjnano.11.65

• epitaxially. Electric resistance measurements demonstrate a metallic-type temperature dependence for the VN film with a small residual resistivity of 9 μΩ·cm at 10 K, indicating high purity and structural quality of the film. The transition to the superconducting state was observed at 7.7 K for the VN film

• . Magnetic moment measurements shown in Figure 4 confirm the composition of Pd0.96Fe0.04 and Pd0.92Fe0.08 through the ferromagnetic transition temperature TC ≈ 125 K and TC ≈ 240 K, respectively [41]. Temperature dependence of resistance and superconducting transition A physical property measurement system

• (QUANTUM DESIGN PPMS-9, USA) was used for studying the temperature dependence of the electrical resistance of the VN thin films and Pd0.96Fe0.04/VN and VN/Pd0.92Fe0.08 heterostructures in the temperature range of 4.2–300 K. A four-probe resistance measurement scheme was used. Figure 5 shows the measurement

Light–matter interactions in two-dimensional layered WSe₂ for gauging evolution of phonon dynamics

• Avra S. Bandyopadhyay,
• Chandan Biswas and
• Anupama B. Kaul

Beilstein J. Nanotechnol. 2020, 11, 782–797, doi:10.3762/bjnano.11.63

• dynamics in WSe2, where τ and the change in phonon concentration deciphered from an energy parameter E0 were quantified as a function of external stimuli, specifically temperature, T, of the WSe2 and the Raman laser power, P, in 1L, ML and bulk WSe2 samples using Raman and PL spectroscopy. The temperature

• dependence of the Raman shifts in 2D TMDCs such as MoS2 [20][21][22][23][24], and WS2 [25][26] have been extensively studied over a wide temperature range from which properties such as thermal conductivity was deciphered [23][27]. On the contrary, the temperature-dependent Raman analysis of WSe2 is rather

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• , spectral instabilities common in solid-state emitters can hinder many applications. A strong temperature dependence of ZPLs was first observed, as shown in [44][106], in multilayer h-BN flakes. Specifically, Jungwirth et al. [44] investigated two different SPEs in h-BN flakes emitting at 575 nm and 682 nm

• and clarified their temperature dependence of the ZPL peak shift, line width, and PL intensity ranging from 4 to 300 K. The temperature-dependent line width, spectral energy shift, and intensity differing ZPLs are described by a lattice vibration model that considers piezoelectric coupling to in-plane

• phonons. The temperature dependence can result in spectral instability and diffusion. They found that the line width of ZPLs was wider than their natural linewidth, suggesting that the broadening of the line width is attributed to the phonon-mediated mechanism. Kianinia et al. [106] demonstrated stable

Soybean-derived blue photoluminescent carbon dots

• Shanshan Wang,
• Wei Sun,
• Dong-sheng Yang and
• Fuqian Yang

Beilstein J. Nanotechnol. 2020, 11, 606–619, doi:10.3762/bjnano.11.48

• irreversible change in the energy gap induced by the annealing. It is known that the temperature dependence of the energy gap for the fluoresence of CDs can be expressed as [42] where Eg(T) is the energy gap at temperature T, S is the Huang–Rhys factor representing the coupling strength between exciton and

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

• Varsha Sharma and
• Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

• screening effect on multilayer bonds [44]. Similar morphological changes were observed when the temperature dependence of electrostatically bound capsules was studied with various PEs that are thermo-responsive [45]. Additionally, the effect of the dissolution of the core on the permeability of capsules was

Anomalous current–voltage characteristics of SFIFS Josephson junctions with weak ferromagnetic interlayers

• Tairzhan Karabassov,
• Anastasia V. Guravova,
• Aleksei Yu. Kuzin,
• Elena A. Kazakova,
• Shiro Kawabata,
• Boris G. Lvov and
• Andrey S. Vasenko

Beilstein J. Nanotechnol. 2020, 11, 252–262, doi:10.3762/bjnano.11.19

• ferromagnetic metal. The existence of such phenomena enables the creation of so-called Josephson π junctions with a negative critical current [1][2]. Oscillations of the pair wave function in the F layer leads to several interesting phenomena in S/F/(S) systems, including nonmonotonic critical temperature

• dependence [8][9][10][11][12], Josephson critical current oscillations [13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39][40][41], and density of states (DOS) oscillations [42][43][44][45]. S/F hybrid structures have many promising applications in

Internalization mechanisms of cell-penetrating peptides

• Ivana Ruseska and
• Andreas Zimmer

Beilstein J. Nanotechnol. 2020, 11, 101–123, doi:10.3762/bjnano.11.10

Targeted therapeutic effect against the breast cancer cell line MCF-7 with a CuFe₂O₄/silica/cisplatin nanocomposite formulation

• B. Rabindran Jermy,
• Vijaya Ravinayagam,
• Widyan A. Alamoudi,
• Dana Almohazey,
• Hatim Dafalla,
• Lina Hussain Allehaibi,
• Abdulhadi Baykal,
• Muhammet S. Toprak and
• Thirunavukkarasu Somanathan

Beilstein J. Nanotechnol. 2019, 10, 2217–2228, doi:10.3762/bjnano.10.214

• inverse spinels occupying the A site, while Cu2+ prefers the B site. SQUID-vibrating sample magnetometry (VSM) analysis showed the formation of superparamagnetic behavior, while a temperature dependence study using field cooling and zero field cooling analysis (ZFC/FC) showed spin-glass-like surface

High-temperature resistive gas sensors based on ZnO/SiC nanocomposites

• Vadim B. Platonov,
• Marina N. Rumyantseva,
• Alexander S. Frolov,
• Alexey D. Yapryntsev and
• Alexander M. Gaskov

Beilstein J. Nanotechnol. 2019, 10, 1537–1547, doi:10.3762/bjnano.10.151

• material to the gas phase. The data obtained allowed us to calculate the value of the sensor response as where Rair is the resistance of the material in background air, and Rgas is the resistance of the material in the presence of the target gas (СО or NH3). The temperature dependence of the sensor

• = 30% (b,d). Insets: Sensor response dependence on SiC content in nanocomposites. Temperature dependence of the sensor response of ZnO nanofibers and ZnO/SiC nanocomposites towards 20 ppm NH3 (a,b) and 20 ppm CO (c,d) in dry air RH25 = 0% (a,c) and at relative humidity RH25 = 30% (b,d). Estimated band

Synthesis of P- and N-doped carbon catalysts for the oxygen reduction reaction via controlled phosphoric acid treatment of folic acid

• Rieko Kobayashi,
• Takafumi Ishii,
• Yasuo Imashiro and
• Jun-ichi Ozaki

Beilstein J. Nanotechnol. 2019, 10, 1497–1510, doi:10.3762/bjnano.10.148

• activity with the CPAT temperature. The temperature-dependence of ORR activity is remarkably large for P-series precursors. The highest ORR activity among the precursors was achieved by P-1000. Structure, chemical composition, and electronic properties of carbonized FA PH-series carbon materials were

Energy distribution in an ensemble of nanoparticles and its consequences

• Dieter Vollath

Beilstein J. Nanotechnol. 2019, 10, 1452–1457, doi:10.3762/bjnano.10.143

• particle size dependent, the determination of the particle size distribution is inherently possible from the experimentally found temperature dependence of a phase transformation. Results and Discussion Mathematical model Maxwell and Boltzmann assumed a normal distribution of the velocity for gas atoms

• experimental determination of particle sizes, the agreement between experimental and calculated data was found to be excellent. Therefore, one may conclude that this evaluation of the temperature dependence of experimental results gives reliable values for the particle size distribution. These successful

Luminescence of Tb₃Al₅O₁₂ phosphors co-doped with Ce³⁺/Gd³⁺ for white light-emitting diodes

• Yu-Guo Yang,
• Lei Wei,
• Jian-Hua Xu,
• Hua-Jian Yu,
• Yan-Yan Hu,
• Hua-Di Zhang,
• Xu-Ping Wang,
• Bing Liu,
• Cong Zhang and
• Qing-Gang Li

Beilstein J. Nanotechnol. 2019, 10, 1237–1242, doi:10.3762/bjnano.10.123

• experimental parameters of 40 kV, 30 mA and 2°/min. The measurements of excitation, emission, temperature-dependence of emission and decay curves were carried out in an Edinburgh Instrument FLS920 spectrophotometer equipped with a 450 W xenon lamp as the excitation source. The measurements were spectrally

Scavenging of reactive oxygen species by phenolic compound-modified maghemite nanoparticles

• Małgorzata Świętek,
• Yi-Chin Lu,
• Rafał Konefał,
• Liliana P. Ferreira,
• M. Margarida Cruz,
• Yunn-Hwa Ma and
• Daniel Horák

Beilstein J. Nanotechnol. 2019, 10, 1073–1088, doi:10.3762/bjnano.10.108

• (10–260 K) and magnetic field (up to 5.5 T) was obtained for colloids frozen in quartz tubes using an MPMS superconducting quantum interference device (SQUID; Quantum Design; San Diego, CA, USA). The temperature dependence was analyzed using zero-field-cooled (ZF-C) and field-cooled (F-C) measurements

• aqueous γ-Fe2O3 colloid (4.4 mg/mL) at 260 K. The inset shows the magnetization curves of all colloids normalized by the nanoparticle weight. (d) Temperature dependence of the magnetization of the γ-Fe2O3@Hep-CS-G colloid. H is the applied magnetic field, and μ0 is the magnetic permeability of vacuum

Direct observation of the CVD growth of monolayer MoS₂ using in situ optical spectroscopy

• Claudia Beatriz López-Posadas,
• Yaxu Wei,
• Wanfu Shen,
• Daniel Kahr,
• Michael Hohage and
• Lidong Sun

Beilstein J. Nanotechnol. 2019, 10, 557–564, doi:10.3762/bjnano.10.57

• features A and B observed at room temperature are hardly visible. We attribute this deviation from the optical spectrum measured at room temperature to the high substrate temperature (≈700 °C) during growth. Indeed, the study of the temperature dependence of the absorption of the MoS2 monolayer shows the

Mechanical and thermodynamic properties of Aβ₄₂, Aβ₄₀, and α-synuclein fibrils: a coarse-grained method to complement experimental studies

• Adolfo B. Poma,
• Horacio V. Guzman,
• Mai Suan Li and
• Panagiotis E. Theodorakis

Beilstein J. Nanotechnol. 2019, 10, 500–513, doi:10.3762/bjnano.10.51

• stable at higher temperatures than at room temperature, while the opposite is the case for α-syn fibrils. In this regard, our method can be used to explore systematically the temperature dependence of the mechanical properties (thermoelasticity) in biological fibrils at experimental length and time