Beilstein J. Nanotechnol.2014,5, 696–710, doi:10.3762/bjnano.5.82
photocatalytic mechanism for TiO2/carbon nanodots is schematically shown in Figure 9. When TiO2/carbon nanodots are illuminated by visible light, the carbon nanodots can absorb visible light (λ > 520 nm) and emit UV light (325 < λ < 425 nm) due to the PL upconversion of carbon nanodots. The UV light emitted by
due to the photosensitization of carbon nanodots. By virtue of PL upconversion properties, carbon nanodots can also be used as photosensitizer to harness near-infrared light to further enhance the photocatalytic activity of some visible-light active semiconductors. Kang et al. recently reported that
) and then emit shorter wavelength light (300 to 530 nm) for the excitation of m-BiVO4 to further generate electron–hole pairs for photocatalytic degradation. Due to the special upconversion property of carbon nanodots, the carbon nanodots–m-BiVO4 nanospheres can be used as photocatalysts under the
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Figure 1:
Schematic steps for the photocatalytic reactions occuring on the surface of a semiconductor. Adapte...
Beilstein J. Nanotechnol.2011,2, 516–524, doi:10.3762/bjnano.2.56
such as Förster resonance energy transfer (FRET) pairs, fluorescent proteins and upconversion particles.
Experimental
We realized an instrument capable of single molecule excitation spectroscopy by combining a high power supercontinuum white light source (Fianium SC-400pp) with a grating spectrometer
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Figure 1:
Single emitter characteristics observed by excitation spectroscopy of isolated quantum dots. a) Exc...