One-step chemical vapor deposition synthesis and supercapacitor performance of nitrogen-doped porous carbon–carbon nanotube hybrids

• Egor V. Lobiak,
• Lyubov G. Bulusheva,
• Ekaterina O. Fedorovskaya,
• Yury V. Shubin,
• Pavel E. Plyusnin,
• Pierre Lonchambon,
• Boris V. Senkovskiy,
• Zinfer R. Ismagilov,
• Emmanuel Flahaut and
• Alexander V. Okotrub

Beilstein J. Nanotechnol. 2017, 8, 2669–2679, doi:10.3762/bjnano.8.267

• reduces the resistance at the carbon surface/electrolyte interface and the nanotubes permeating the porous carbon provide fast charge transport in the cell. Keywords: bimetallic catalyst; electrochemical impedance spectroscopy; N-doped carbon; porous carbon–carbon nanotube hybrid; supercapacitor

• . The value is larger when the fraction of porous carbon in the sample is lower (Table S1 in Supporting Information File 1). This fact evidences the role played by the MWCNTs in the enhancement of the charge transport properties of the materials. The fast ion-transfer process in the cells results in

The role of ligands in coinage-metal nanoparticles for electronics

• Ioannis Kanelidis and
• Tobias Kraus

Beilstein J. Nanotechnol. 2017, 8, 2625–2639, doi:10.3762/bjnano.8.263

• substrates to create highly conductive patterns for an electroluminescent device [42]. Yu et al. successfully used silver nanoparticle (Ag NP) inks to prepare grids for polymer solar cells by inkjet or flexographic printing [51]. Charge transport in spaced metal nanoparticle layers is strongly affected by

• inks colloidally stable, but they may prevent electrical contacts in deposited films [32]. Charge transport can be improved after deposition by removing the surface-bound ligands [105], by linking nanoparticles chemically [106], or by ligand exchange in order to manipulate spacing in metal nanoparticle

• well dispersed and had a lower Tp than those with a dense shell, so that conductive films (2 × 105 S/cm) could be formed already at 145 °C. Charge transport also depended on the substituents in ligands, for example, in para-substituted thiophenol ligands on gold nanoparticles. Electron-donating

Inelastic electron tunneling spectroscopy of difurylethene-based photochromic single-molecule junctions

• Youngsang Kim,
• Safa G. Bahoosh,
• Dmytro Sysoiev,
• Thomas Huhn,
• Fabian Pauly and
• Elke Scheer

Beilstein J. Nanotechnol. 2017, 8, 2606–2614, doi:10.3762/bjnano.8.261

• theoretical analysis of charge transport through diarylethene-derived single-molecule devices, which are created using the mechanically controlled break-junction technique. Inelastic electron tunneling (IET) spectroscopy measurements performed at 4.2 K are compared with first-principles calculations in the

• properties of several species of photochromic molecules in single-molecule junctions with gold electrodes have been investigated extensively to understand the mechanisms of charge transport and optical switching [11][12][13][14][15][16]. Among the photochromic molecules, diarylethene derivatives are

• , including the energy of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) and their coupling to electrodes. This behavior results in a change of the charge transport properties of the corresponding molecular junctions, most prominently of the electrical

Electronic structure, transport, and collective effects in molecular layered systems

• Torsten Hahn,
• Tim Ludwig,
• Carsten Timm and
• Jens Kortus

Beilstein J. Nanotechnol. 2017, 8, 2094–2105, doi:10.3762/bjnano.8.209

• ; Introduction Implementing molecular spintronics requires the understanding and the ability to modify and control charge-transport characteristics of organic molecules. Thus a solid understanding of the basic effects that govern the transport characteristics in the desired material is required for the

Spin-dependent transport and functional design in organic ferromagnetic devices

• Guichao Hu,
• Shijie Xie,
• Chuankui Wang and
• Carsten Timm

Beilstein J. Nanotechnol. 2017, 8, 1919–1931, doi:10.3762/bjnano.8.192

• , namely an inversion of the rectification, may happen. This has been discussed in detail in [59]. Note that the concept of SC rectification reviewed here is based on spin-polarized charge transport. This phenomenon has also been reported in a molecular junction with one ferromagnetic and one nonmagnetic

• -electron and radical spins has so far been treated in a mean-field approximation, which neglects the dynamics of the radical spins. Spin and also charge transport is expected to be affected by the dynamics, which requires a quantum-mechanical description since the radicals typically carry spins S = 1/2

Parylene C as a versatile dielectric material for organic field-effect transistors

• Tomasz Marszalek,
• Maciej Gazicki-Lipman and
• Jacek Ulanski

Beilstein J. Nanotechnol. 2017, 8, 1532–1545, doi:10.3762/bjnano.8.155

• organic light-emitting diode (OLED) (10−6 g/m2 per day) [23]. Nevertheless, some of the organic semiconductors (mostly electron-transporting materials) require an encapsulation layer, in order to observe charge transport in the transistor architecture [24]. According to our knowledge, there is a limited

• traps but they cannot entirely eliminate surface SiOH groups [39]. When polyethylene was used as a buffer dielectric, unhindered charge transport was observed [40], suggesting that thin polymer layers could play the same role as SAMs do. For this reason, polymers are often used as a part of twin

• hole-type semiconductor. In this case, a more effective charge transport was observed when a Parylene C dielectric film was used instead of the Si/SiO2 combination. An application of parylene insulator also facilitated an evaluation of the influence that the crystalline structure of the semiconductor

Formation of ferromagnetic molecular thin films from blends by annealing

• Peter Robaschik,
• Ye Ma,
• Salahud Din and
• Sandrine Heutz

Beilstein J. Nanotechnol. 2017, 8, 1469–1475, doi:10.3762/bjnano.8.146

• crystallites in our MnPc films reach a size of up to 10 µm for their longer axis, which is attractive for high coercivity in magnetism and improved charge transport along the crystallites. Results from optical microscopy can be refined by X-ray diffraction (XRD). Figure 3a shows the XRD patterns of the as

Spin-chemistry concepts for spintronics scientists

• Konstantin L. Ivanov,
• Alexander Wagenpfahl,
• Carsten Deibel and
• Jörg Matysik

Beilstein J. Nanotechnol. 2017, 8, 1427–1445, doi:10.3762/bjnano.8.143

• , if the charge transport is limited by spin-selective electron–hole recombination [86]. In contrast to the unipolar OMAR (where bipolarons enhance the current flow) here two (oppositely charged) polaron pairs usually reduce the current: either by recombination or generation of a triplet exciton

Charge transport in organic nanocrystal diodes based on rolled-up robust nanomembrane contacts

• Vineeth Kumar Bandari,
• Lakshmi Varadharajan,
• Longqian Xu,
• Abdur Rehman Jalil,
• Mirunalini Devarajulu,
• Pablo F. Siles,
• Feng Zhu and
• Oliver G. Schmidt

Beilstein J. Nanotechnol. 2017, 8, 1277–1282, doi:10.3762/bjnano.8.129

• Str. 20, 01069 Dresden, Germany 10.3762/bjnano.8.129 Abstract The investigation of charge transport in organic nanocrystals is essential to understand nanoscale physical properties of organic systems and the development of novel organic nanodevices. In this work, we fabricate organic nanocrystal

• diodes contacted by rolled-up robust nanomembranes. The organic nanocrystals consist of vanadyl phthalocyanine and copper hexadecafluorophthalocyanine heterojunctions. The temperature dependent charge transport through organic nanocrystals was investigated to reveal the transport properties of ohmic and

• space-charge-limited current under different conditions, for instance, temperature and bias. Keywords: charge transport; nanomembrane; organic diode; organic nanocrystal; rolled-up nanotechnology; Introduction Organic semiconductors have been widely applied in developing optoelectronic devices

Growth, structure and stability of sputter-deposited MoS₂ thin films

• Reinhard Kaindl,
• Bernhard C. Bayer,
• Roland Resel,
• Thomas Müller,
• Viera Skakalova,
• Gerlinde Habler,
• Rainer Abart,
• Alexey S. Cherevan,
• Dominik Eder,
• Maxime Blatter,
• Fabian Fischer,
• Jannik C. Meyer,
• Dmitry K. Polyushkin and
• Wolfgang Waldhauser

Beilstein J. Nanotechnol. 2017, 8, 1115–1126, doi:10.3762/bjnano.8.113

• for HER, in order to allow efficient charge transport through the electro-catalyst layers [21]. Both electronic and electro-catalytic applications of MoS2 share the key pre-requisite of a scalable and controllable fabrication technique for MoS2. Starting from early attempts with mechanical exfoliation

• cm length scale. In contrast, in many optimized device geometries the catalytically active MoS2 films are deposited onto highly conductive substrates, such as glassy carbon [18][20], where charge transport is then facilitated by current flowing only across the thin MoS2 film on a nm length scale into

Ultrasmall magnetic field-effect and sign reversal in transistors based on donor/acceptor systems

• Thomas Reichert and
• Tobat P. I. Saragi

Beilstein J. Nanotechnol. 2017, 8, 1104–1114, doi:10.3762/bjnano.8.112

• films. This enhances the probability of bipolaron formation, which is the process responsible for magnetoresistance effects in our system. Thereby even ultrasmall magnetic fields as low as 0.7 mT can influence the resistance of the charge transport channel. Moreover, the magnetoresistance is drastically

• number of free charge carriers is available and the charge transport is hindered. In this scenario, the magnetic field induced reduction of the spin mixture and thus, the reduced bipolaron formation-probability leads to a release of charge carriers, resulting in an increase of the current. Finally

• Spiro-TTB (EHOMO = −4.9 eV) and the LUMO of HAT-CN (ELUMO = −5.1 eV), the intrinsically available number of holes and electrons is so large that the gate-induced charge carrier accumulation does not has a significant influence on the drain current Id [18]. Therefore, Vd does not only dominate the charge

Energy-level alignment at interfaces between manganese phthalocyanine and C₆₀

• Daniel Waas,
• Florian Rückerl,
• Martin Knupfer and
• Bernd Büchner

Beilstein J. Nanotechnol. 2017, 8, 927–932, doi:10.3762/bjnano.8.94

• (opto-)electronic devices [1][2][3][4][5][6][7][8][9][10]. A key issue in any device is the energetics at the device interfaces as it determines charge transport across or charge separation at the corresponding interface [11][12]. Thus, it is not surprising that the investigation of organic

Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields

• Arpita Jana,
• Elke Scheer and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2017, 8, 688–714, doi:10.3762/bjnano.8.74

• maintain unique 2D characteristics due to the functional separation of the layers at the nanoscale [93]. This hybrid system has potential for achieving the functional separation of charge transport and storage. A highly efficient, stable, sandwich-structured TiO2–Pt–graphene hybrid has been prepared by Xia

Analysis and modification of defective surface aggregates on PCDTBT:PCBM solar cell blends using combined Kelvin probe, conductive and bimodal atomic force microscopy

• Hanaul Noh,
• Alfredo J. Diaz and
• Santiago D. Solares

Beilstein J. Nanotechnol. 2017, 8, 579–589, doi:10.3762/bjnano.8.62

• modification of unidentified surface aggregates. The aggregates are characterized electrically by Kelvin probe force microscopy and conductive atomic force microscopy (C-AFM), whereby the correlation between local electrical potential and current confirms a defective charge transport. Bimodal AFM modification

• solvent used in the fabrication process (chlorobenzene or dichlorobenzene). We characterize the spatial and electrical properties of the aggregates, and show that the structures are clusters of thin molecular layers exhibiting hole-blocking properties, which can affect charge transport efficiency at the

• current image shows almost entirely no current for the surface aggregates (white = no current). Because the aggregation layer blocks most of the reverse bias current and some of the forward bias current, charge transport through the aggregates from the active layer to top electrode could hinder PSC

Solvent-mediated conductance increase of dodecanethiol-stabilized gold nanoparticle monolayers

• Patrick A. Reissner,
• Jean-Nicolas Tisserant,
• Antoni Sánchez-Ferrer,
• Raffaele Mezzenga and
• Andreas Stemmer

Beilstein J. Nanotechnol. 2016, 7, 2057–2064, doi:10.3762/bjnano.7.196

• .7.196 Abstract Gold nanoparticle monolayers provide convenient templates to study charge transport in organic molecules beyond single junction techniques. Conductance is reported to increase by several orders of magnitude following immersion of alkanethiol-stabilized gold nanoparticle monolayers in a

Nanostructured SnO₂–ZnO composite gas sensors for selective detection of carbon monoxide

• Paul Chesler,
• Cristian Hornoiu,
• Susana Mihaiu,
• Cristina Vladut,
• Jose Maria Calderon Moreno,
• Mihai Anastasescu,
• Carmen Moldovan,
• Bogdan Firtat,
• Costin Brasoveanu,
• George Muscalu,
• Ion Stan and
• Mariuca Gartner

Beilstein J. Nanotechnol. 2016, 7, 2045–2056, doi:10.3762/bjnano.7.195

• interconnected, and the charge transport mechanism through the oxide film remains unaffected. The films are highly transparent, noticeable as the gold interdigital electrodes are visible through the film. The film grains for the composite samples S2, S3 and S4 were identified with dimensions in the sub-μm range

Nanostructured TiO₂-based gas sensors with enhanced sensitivity to reducing gases

• Wojciech Maziarz,
• Anna Kusior and
• Anita Trenczek-Zajac

Beilstein J. Nanotechnol. 2016, 7, 1718–1726, doi:10.3762/bjnano.7.164

• surface area. Moreover, the sponge-like walls (or petals) induce fast charge transport. However, lower sensitivity to various gases can be attributed to phase composition. Anatase and rutile are the most common titanium dioxide polymorphs, which exhibit different properties [43]. Anatase is a more

Scanning probe microscopy studies on the adsorption of selected molecular dyes on titania

• Jakub S. Prauzner-Bechcicki,
• Lukasz Zajac,
• Piotr Olszowski,
• Res Jöhr,
• Antoine Hinaut,
• Thilo Glatzel,
• Bartosz Such,
• Ernst Meyer and
• Marek Szymonski

Beilstein J. Nanotechnol. 2016, 7, 1642–1653, doi:10.3762/bjnano.7.156

• judiciously introduced, the molecules tend to realign in an upright position as the coverage density increases. In such a case, molecules often form π-stacked structures, thus, the mutual π–π interactions between molecules moderate the intermolecular charge transport within the organic structure. The charge

• injection and charge transport both are very important when considering potential applications in photovoltaics, electronics and other fields. Additionally, inherent surface defects, such as oxygen vacancies on the TiO2(110) surface, cannot be ignored because they affect the level alignment of the molecule

• of dye molecules. The careful selection of buffer layer molecules may lead to systems with unaffected charge transport from the excited states of dye molecules to the oxide electrode, with significantly diminished dye–substrate recombination, and increased stability and quality of the active top-most

Fingerprints of a size-dependent crossover in the dimensionality of electronic conduction in Au-seeded Ge nanowires

• Maria Koleśnik-Gray,
• Gillian Collins,
• Justin D. Holmes and
• Vojislav Krstić

Beilstein J. Nanotechnol. 2016, 7, 1574–1578, doi:10.3762/bjnano.7.151

• ]. While the surface-to-volume ratio scales with NW radius and therefore can be controlled by adjusting synthesis conditions [11][12], the screening length depends on the density and dimensional character of the charge carriers in the NW [8]. Therefore it is crucial to investigate the charge transport

• -type charge transport. Inset: four-point current–voltage characteristic of the same NW. Radius-dependent charge transport properties in Ge NWs. (a) Electrical conductivity, (b) mobility and (c) charge carrier density as function of the NW radius R. Dotted lines in (a) and (b) are a guide to the eye

Filled and empty states of Zn-TPP films deposited on Fe(001)-p(1×1)O

• Gianlorenzo Bussetti,
• Alberto Calloni,
• Rossella Yivlialin,
• Andrea Picone,
• Federico Bottegoni and
• Marco Finazzi

Beilstein J. Nanotechnol. 2016, 7, 1527–1531, doi:10.3762/bjnano.7.146

• in organic devices, where the alignment of the HOMO and LUMO levels of the molecule with the substrate bands play a crucial role in charge transport. Experimental The experimental apparatus consists of a multichamber ultrahigh vacuum (UHV, base pressure in the 10−8 Pa range) system described

Role of solvents in the electronic transport properties of single-molecule junctions

• Katharina Luka-Guth,
• Sebastian Hambsch,
• Andreas Bloch,
• Philipp Ehrenreich,
• Bernd Michael Briechle,
• Filip Kilibarda,
• Torsten Sendler,
• Dmytro Sysoiev,
• Thomas Huhn,
• Artur Erbe and
• Elke Scheer

Beilstein J. Nanotechnol. 2016, 7, 1055–1067, doi:10.3762/bjnano.7.99

• , Helmholtz-Zentrum Dresden-Rossendorf, D-01328 Dresden, Germany Chemistry Department, University of Konstanz, D-78457 Konstanz, Germany 10.3762/bjnano.7.99 Abstract We report on an experimental study of the charge transport through tunnel gaps formed by adjustable gold electrodes immersed into different

• exposed to the solvent may also be considered. While the lifetime aspect is shortly addressed in our work, a comprehensive study of all these aspects is beyond the scope of this article. Conclusion We have investigated charge transport through tunnel contacts formed by the mechanically controllable break

Reorientation of single-wall carbon nanotubes in negative anisotropy liquid crystals by an electric field

• Amanda García-García,
• Ricardo Vergaz,
• José F. Algorri,
• Gianluigi Zito,
• Teresa Cacace,
• Antigone Marino,
• José M. Otón and
• Morten A. Geday

Beilstein J. Nanotechnol. 2016, 7, 825–833, doi:10.3762/bjnano.7.74

• conductivity, where the charge transport is favored along the longitudinal axis [2]. Liquid crystals (LCs) are self-organized anisotropic fluids, well-known for their use in flat panel mobile, PC, and TV displays. Besides consumer electronic products, LCs are employed in many photonic devices such as spatial

• longitudinal axis parallel to the electrodes) to perpendicular (i.e., the longitudinal axis is perpendicular to the electrodes) may be detected as a LC−SWCNT cell conductivity increase. This is attributed to the favored charge transport between the electrodes through the SWCNT longitudinal axis. The SWCNTs may

Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate

• Rainhard Machatschek,
• Patrick Ortmann,
• Renate Reiter,
• Stefan Mecking and
• Günter Reiter

Beilstein J. Nanotechnol. 2016, 7, 784–798, doi:10.3762/bjnano.7.70

• crystallization or dewetting may lead to films with a complex morphology that differs substantially from the homogeneous, closed and largely defect-free film, which is required for good charge transport. One has to take into account that differences in device morphology directly translate into differences in

• assembled at the crystal surface, probably exhibited a strong overlap of their π-orbitals, which is one of the main prerequisites for efficient charge transport [20]. Finally, we want to emphasize that the perylene derivative 1 used in this study can be replaced by many other semiconducting molecules, which

Thermo-voltage measurements of atomic contacts at low temperature

• Ayelet Ofarim,
• Bastian Kopp,
• Thomas Möller,
• León Martin,
• Johannes Boneberg,
• Paul Leiderer and
• Elke Scheer

Beilstein J. Nanotechnol. 2016, 7, 767–775, doi:10.3762/bjnano.7.68

• temperature gradients into electrical energy and for the local energy dissipation. More fundamentally, the study of thermoelectric effects in atomic-scale nanostructures and in molecular junctions gives important additional information of charge transport [2][3][4]. The thermopower is quantified by the

• from the behavior of bulk metals were found. The bulk values were retrieved for contacts larger than 10000 atoms in cross section only. Dell et al. [11] studied the charge transport characteristics of a series of organic molecules. Through thermo-voltage measurements, they showed that the transport

• combination allows the determination of the Seebeck coefficient of atomic-scale devices, which will lead to a better understanding of charge transport in these systems. The set-up is also suitable for measuring the thermopower of single-molecule contacts as well as to be operated at variable base temperature

Bacteriorhodopsin–ZnO hybrid as a potential sensing element for low-temperature detection of ethanol vapour

• Saurav Kumar,
• Sudeshna Bagchi,
• Senthil Prasad,
• Anupma Sharma,
• Ritesh Kumar,
• Rishemjit Kaur,
• Jagvir Singh and
• Amol P. Bhondekar

Beilstein J. Nanotechnol. 2016, 7, 501–510, doi:10.3762/bjnano.7.44

• . The morphological and spectroscopic analysis of the hybrid structures confirmed the ZnO thin film/nanorod growth and functional properties of bR. The photoactivity results of the bR protein further corroborated the sustainability of its charge transport property and biological activity. When exposed

• biological activity after immobilization on solid supports and exhibits charge transport in thin films [8][14][15]. These properties have attracted researchers for the development of novel bio-hybrid devices [5][7][16][17][18][19]. Hybrids of bR protein with various metal/metal oxides (e.g., Au, Ag, TiO2