Single-molecule magnet behavior in 2,2’-bipyrimidine-bridged dilanthanide complexes

• Wen Yu,
• Frank Schramm,
• Eufemio Moreno Pineda,
• Yanhua Lan,
• Olaf Fuhr,
• Jinjie Chen,
• Hironari Isshiki,
• Wolfgang Wernsdorfer,
• Wulf Wulfhekel and
• Mario Ruben

Beilstein J. Nanotechnol. 2016, 7, 126–137, doi:10.3762/bjnano.7.15

• along the lanthanide series, with a corresponding decrease in ionic radii referred to as the lanthanide contraction. The distances between the two lanthanide ions have the same trend and are also showed in Table 3. These values are often observed in other known bpm-bridged Ln(III) dimers [28][29

Current-induced runaway vibrations in dehydrogenated graphene nanoribbons

• Rasmus Bjerregaard Christensen,
• Jing-Tao Lü,
• Per Hedegård and
• Mads Brandbyge

Beilstein J. Nanotechnol. 2016, 7, 68–74, doi:10.3762/bjnano.7.8

• dehydrogenated armchair graphene nanoribbon. All parameters are obtained from density functional theory. The dehydrogenated carbon dimers behave as effective impurities, whose motion decouples from the rest of carbon atoms. The electrical current can couple the dimer motion in a coherent fashion. The coupling

• study suggests that the carbon dimers at the armchair edge vibrate locally and interact strongly with the electrical current [8]. They can be thought as atomic scale defects at the boundary. How the current-induced forces affect the dynamics of these dimers is an interesting question to ask since it

• motion of the dehydrogenated carbon dimer at the nanoribbon boundaries are relatively decoupled from other dimers and also from the rest carbon atoms. This results in several nearly degenerate atomic vibrations, where each of these involves mainly one dimer. However, a coupling of the dimer vibrations

Surface-enhanced Raman scattering by colloidal CdSe nanocrystal submonolayers fabricated by the Langmuir–Blodgett technique

• Alexander G. Milekhin,
• Larisa L. Sveshnikova,
• Tatyana A. Duda,
• Ekaterina E. Rodyakina,
• Volodymyr M. Dzhagan,
• Ovidiu D. Gordan,
• Sergey L. Veber,
• Cameliu Himcinschi,
• Alexander V. Latyshev and
• Dietrich R. T. Zahn

Beilstein J. Nanotechnol. 2015, 6, 2388–2395, doi:10.3762/bjnano.6.245

• 10.3762/bjnano.6.245 Abstract We present the results of an investigation of surface-enhanced Raman scattering (SERS) by optical phonons in colloidal CdSe nanocrystals (NCs) homogeneously deposited on both arrays of Au nanoclusters and Au dimers using the Langmuir–Blodgett technique. The coverage of the

• axis was 20. The SERS signal intensity was also investigated as a function of the distance between nanoclusters in a dimer. Here the maximal SERS enhancement was observed for the minimal distance studied (about 10 nm), confirming the formation of SERS “hot spots”. Keywords: CdSe nanocrystals; dimers

• ]. The fabrication details of regular arrays of Au nanoclusters and dimers on a Si substrate are presented in [29]. In addition to regular arrays of Au nanoclusters, arrays of paired Au nanoclusters or dimers were fabricated by electron beam lithography on a Si substrate covered with 75 nm of SiO2. The

Nanostructured surfaces by supramolecular self-assembly of linear oligosilsesquioxanes with biocompatible side groups

• Maria Nowacka,
• Anna Kowalewska and
• Tomasz Makowski

Beilstein J. Nanotechnol. 2015, 6, 2377–2387, doi:10.3762/bjnano.6.244

• hydrogen bonds (linear catemeric structures) it adheres to mica as clusters of polymeric chains cross-linked by –COOH···HOOC– dimers or amine salts (–COO−NH2+– and –COO−NH3+–). Species P2, P3 and P4, having donor/acceptor NH/NH2 units, can adsorb on mica-CA via formation of complementary hydrogen bonds

Magnetic properties of self-organized Co dimer nanolines on Si/Ag(110)

• Lisa Michez,
• Kai Chen,
• Fabien Cheynis,
• Frédéric Leroy,
• Alain Ranguis,
• Haik Jamgotchian,
• Margrit Hanbücken and
• Laurence Masson

Beilstein J. Nanotechnol. 2015, 6, 777–784, doi:10.3762/bjnano.6.80

• ][28][29]. The STM image of Figure 2c shows a typical 1D Co nanostructure formed after Co deposition at RT on isolated Si NRs, partially covering the Ag(110) surface. The grown 1D nanostructures correspond to Co nanolines composed of dimers oriented perpendicular to the axis of the Si NRs. A Co dimer

• of the second layer can also be observed. The Co–Co distance in a dimer, as measured by STM, is ≈0.4 nm (i.e., ≈) and the distance between two dimers along the nanoline is ≈0.43 nm (i.e., ≈1.5 ∙ ). The apparent height of both Co layers is ≈50 pm, suggesting single-atom-thick layers. Interestingly, it

A versatile strategy towards non-covalent functionalization of graphene by surface-confined supramolecular self-assembly of Janus tectons

• Ping Du,
• David Bléger,
• Fabrice Charra,
• Vincent Bouchiat,
• David Kreher,
• Fabrice Mathevet and
• André-Jean Attias

Beilstein J. Nanotechnol. 2015, 6, 632–639, doi:10.3762/bjnano.6.64

• -assembled on HOPG (Figure 2). The surface-confined molecular self-assemblies were characterized by scanning tunneling microscopy (STM) at the liquid–solid interface. As expected, they form non-covalent, surface self-assembled dimers, supramolecular linear polymers, and 2D networks. The versatility of the

Influence of size, shape and core–shell interface on surface plasmon resonance in Ag and Ag@MgO nanoparticle films deposited on Si/SiO_x

• Sergio D’Addato,
• Daniele Pinotti,
• Maria Chiara Spadaro,
• Guido Paolicelli,
• Vincenzo Grillo,
• Sergio Valeri,
• Luca Pasquali,
• Luca Bergamini and
• Stefano Corni

Beilstein J. Nanotechnol. 2015, 6, 404–413, doi:10.3762/bjnano.6.40

• dimers or other smaller aggregates. Indeed, for both thicknesses, the simulations provide a good match with the experiments when the quantity of nanospheroids is less than that of the nanospheres (compare Figure 3e with Figure 3c). For tAg = 0.8 nm, the best spectrum reproduction was found for a

X-ray photoelectron spectroscopy of graphitic carbon nanomaterials doped with heteroatoms

• Toma Susi,
• Thomas Pichler and
• Paola Ayala

Beilstein J. Nanotechnol. 2015, 6, 177–192, doi:10.3762/bjnano.6.17

• bonding of azafullerene dimers, or differences in the core hole screening compared to other nitrogen-doped systems may affect the measured value by at most a few hundred meV, the N 1s core level of C59N measured at 400.7 eV [132][152] should provide the first estimate for the energy of the N substitution

Functionalization of α-synuclein fibrils

• Simona Povilonienė,
• Vida Časaitė,
• Virginijus Bukauskas,
• Arūnas Šetkus,
• Juozas Staniulis and
• Rolandas Meškys

Beilstein J. Nanotechnol. 2015, 6, 124–133, doi:10.3762/bjnano.6.12

• dimers, which could be reduced to monomers by TCEP treatment (a gel-filtration analysis, data not shown), and the formation of fibrils was similar to that of the wild type α-Syn. After the reduction of α-SynC141 fibrils with TCEP and subsequent dialysis, the concentration of free sulfhydryl groups was

Exploring plasmonic coupling in hole-cap arrays

• Thomas M. Schmidt,
• Maj Frederiksen,
• Vladimir Bochenkov and
• Duncan S. Sutherland

Beilstein J. Nanotechnol. 2015, 6, 1–10, doi:10.3762/bjnano.6.1

• explained by the hybridization model which describes the complex plasmonic interactions as a combination of elementary plasmon modes [17]. Good examples of this are seen in the cases of nanorice [4], nanostars [18], semishells [8] and nanoparticle dimers [19][20]. Such hybridized systems have shown promise

Anticancer efficacy of a supramolecular complex of a 2-diethylaminoethyl–dextran–MMA graft copolymer and paclitaxel used as an artificial enzyme

• Yasuhiko Onishi,
• Yuki Eshita,
• Rui-Cheng Ji,
• Masayasu Onishi,
• Takashi Kobayashi,
• Masaaki Mizuno,
• Jun Yoshida and
• Naoji Kubota

Beilstein J. Nanotechnol. 2014, 5, 2293–2307, doi:10.3762/bjnano.5.238

• hydrophobic interactions between the cationic DDMC/PTX complex and its substrate, the α,β-tubulin dimer, orientate β-tubulin with the hydrophobic pocket of the DDMC/PTX complex, which promotes the polymerization of α,β-tubulin dimers through the activity of PTX by their entropy elasticity, which is consistent

• with allosteric Michaelis–Menten kinetics. The stability of the enzyme (DDMC/PTX complex) substrate (α,β-tubulin dimer) complex (Michaelis complex) can be represented as 1/Km, which is probably small [42] for an allosteric reaction; it does not cause dynamic instability in the tubulin dimers to stop

Influence of the supramolecular architecture on the magnetic properties of a Dy^III single-molecule magnet: an ab initio investigation

• Julie Jung,
• Olivier Cador,
• Kevin Bernot,
• Fabrice Pointillart,
• Javier Luzon and
• Boris Le Guennic

Beilstein J. Nanotechnol. 2014, 5, 2267–2274, doi:10.3762/bjnano.5.236

• distances are equal to 2.34(4) Å and 2.49(5) Å, respectively. The formation of “head to tail” dimers is observed in both compounds. Despite their identical coordination spheres the experimental magnetic properties of the two compounds differ significantly. Indeed, in the condensed phase the thermal

Spin annihilations of and spin sifters for transverse electric and transverse magnetic waves in co- and counter-rotations

• Hyoung-In Lee and
• Jinsik Mok

Beilstein J. Nanotechnol. 2014, 5, 1887–1898, doi:10.3762/bjnano.5.199

• correspond roughly to the two extreme cases of the coupled SRR dimers [10] for which the twist angle serves as something like q. It is more interesting that the Lagrangian energy for the electric mode changes its sign as ±|q|2 for the TE mode, whereas the Lagrangian energy for the magnetic mode stays the

Numerical investigation of the effect of substrate surface roughness on the performance of zigzag graphene nanoribbon field effect transistors symmetrically doped with BN

• Majid Sanaeepur,
• Arash Yazdanpanah Goharrizi and
• Mohammad Javad Sharifi

Beilstein J. Nanotechnol. 2014, 5, 1569–1574, doi:10.3762/bjnano.5.168

• doped with BN dimers, namely, a 5h-2BN-ZGNR structure. Figure 2a illustrates the average transmission of a 10 nm length 4h-2BN-ZGNR versus energy for various SR amplitudes. As shown by increasing the roughness amplitude, the transmission decreases due to an increased SR scattering rate [28]. The inset

Nano-rings with a handle – Synthesis of substituted cycloparaphenylenes

• Anne-Florence Tran-Van and
• Hermann A. Wegner

Beilstein J. Nanotechnol. 2014, 5, 1320–1333, doi:10.3762/bjnano.5.145

• macrocyclization using nickel-catalyzed homocoupling initially developed by Itami et al. The syn and anti trimers were isolated in 11% yield. Dimers were also isolated. The aromatization of 37 was performed by using DDQ yielding the corresponding [9]CPP with three 5,8-dimethoxynaphth-1,4-diyl units in 88% yield

• . However, the aromatization of the dimer precursor for the [6]CPP was not successful due to larger strain energy. The NMR study of 38 suggests that the phenyl units undergo fast rotation as only one set of signals was observed. CPP dimers and other architectures The structure of para-connected CPP

• -substituted benzene units are staggered by 12.5°, and the distance between these two connection units is 18.4 Å, which lies between the diameter of [13]CPP and [14]CPP. The strain energy was calculated through the homodesmotic reaction method to 67.2 kcal/mol. Dimers of CPPs were prepared in the Jasti group

Model systems for studying cell adhesion and biomimetic actin networks

• Dorothea Brüggemann,
• Johannes P. Frohnmayer and
• Joachim P. Spatz

Beilstein J. Nanotechnol. 2014, 5, 1193–1202, doi:10.3762/bjnano.5.131

• integrin molecules attach directly to their ligand molecules in the ECM; the intracellular tail of integrin binds to proteins like talin and FAK. On the intracellular side, active talin dimers also bind to filamentous actin. Other proteins like FAK form an indirect linkage to the actin cortex together with

Classical molecular dynamics investigations of biphenyl-based carbon nanomembranes

• Andreas Mrugalla and
• Jürgen Schnack

Beilstein J. Nanotechnol. 2014, 5, 865–871, doi:10.3762/bjnano.5.98

• by X-ray diffraction. In [4] quantum chemical calculations were performed for various dimers of biphenyls, which left open how the precursor molecules interlink laterally. A first small-scale quantum calculation (using ARGUS Lab) of a two-dimensional cutout of 6 by 5 biphenyls is reported in [5

Hole-mask colloidal nanolithography combined with tilted-angle-rotation evaporation: A versatile method for fabrication of low-cost and large-area complex plasmonic nanostructures and metamaterials

• Jun Zhao,
• Bettina Frank,
• Frank Neubrech,
• Chunjie Zhang,
• Paul V. Braun and
• Harald Giessen

Beilstein J. Nanotechnol. 2014, 5, 577–586, doi:10.3762/bjnano.5.68

• demonstrated the possibility to tune particle plasmon resonances by varying geometries, materials, and substrates. Recently, more complex geometries such as dimers, oligomers, stacked and chiral structures, and hybrid combinations with different materials were examined [1][2][3]. Mode coupling, plasmon

• sufficient oxygen plasma etching time has been reached. PS nanospheres of 119 nm diameter were used in all four examples. A variety of different nanostructures fabricated by hole-mask colloidal lithography: (a) ellipses, (b) split-rings, (c) asymmetric double split-rings, (d) dimers, (e) pentamers, (f) three

Structural development and energy dissipation in simulated silicon apices

• Samuel Paul Jarvis,
• Lev Kantorovich and
• Philip Moriarty

Beilstein J. Nanotechnol. 2013, 4, 941–948, doi:10.3762/bjnano.4.106

• variation in the simulated F(z) curves. A small deviation is calculated only when the tip is rotated to the position we define as 180° (see Figure 1b), in which both of the atoms within the tip and surface dimers are able to interact with each other at very close approach. More interesting behaviour arises

• , stable, configuration resulting in the F(z) curve that is shown in Figure 5c. For the D2b to D2c transition, extreme features are observed both in the approach and retraction sections of the calculated F(z) because of the complicated interaction between the tip and the surface Si(100) dimers. These

• features originate from the blunt structure of the tip interacting with two dimers on the surface during rearrangement. The D2c tip structure is shown in Figure 5d and Figure 5e displayed from two perpendicular perspectives. This final tip configuration is found to be stable upon continued spectroscopy

Adsorption of the ionic liquid [BMP][TFSA] on Au(111) and Ag(111): substrate effects on the structure formation investigated by STM

• Benedikt Uhl,
• Florian Buchner,
• Dorothea Alwast,
• Nadja Wagner and
• R. Jürgen Behm

Beilstein J. Nanotechnol. 2013, 4, 903–918, doi:10.3762/bjnano.4.102

• round shaped protrusions form a densely packed line of dimers, which are slightly rotated against the main direction of the line (in Figure 4a, the lines run roughly from the lower left to the upper right corner), which results in a zig-zag like appearance. Between two close-packed lines of round

Probing the plasmonic near-field by one- and two-photon excited surface enhanced Raman scattering

• Katrin Kneipp and
• Harald Kneipp

Beilstein J. Nanotechnol. 2013, 4, 834–842, doi:10.3762/bjnano.4.94

• aggregates of nanoparticle of various sizes and shapes reaching from dimers [4][5][6][7], and trimers [8] to selfsimilar structures formed by silver- or gold nanospheres [9]. High local fields can also exist in fractal films or cavities of these noble metals [10]. The recently reported super-resolution

Spin relaxation in antiferromagnetic Fe–Fe dimers slowed down by anisotropic Dy^III ions

• Valeriu Mereacre,
• Frederik Klöwer,
• Yanhua Lan,
• Rodolphe Clérac,
• Juliusz A. Wolny,
• Volker Schünemann,
• Christopher E. Anson and
• Annie K. Powell

Beilstein J. Nanotechnol. 2013, 4, 807–814, doi:10.3762/bjnano.4.92

• parameter P that corresponds to the half of the length of the shortest Fe–O–Fe-bridge in the complex. This is also supported by the value J ≈ −8.7 cm−1, which was determined by using another magnetostructural correlation originally developed for dimers that utilizes both the Fe–O distances and the Fe–O–Fe

Apertureless scanning near-field optical microscopy of sparsely labeled tobacco mosaic viruses and the intermediate filament desmin

• Alexander Harder,
• Mareike Dieding,
• Volker Walhorn,
• Sven Degenhard,
• Andreas Brodehl,
• Christina Wege,
• Hendrik Milting and
• Dario Anselmetti

Beilstein J. Nanotechnol. 2013, 4, 510–516, doi:10.3762/bjnano.4.60

• ) Assembly model of type II intermediate filaments [24]. Desmin monomers associate to parallel coiled coil dimers. Dimers form antiparallel tetramers which assemble to unit length filaments (ULF). Filaments elongate by longitudinal assembly of ULF. a) Scheme of the experimental setup. b) The sample

Magnetic anisotropy of graphene quantum dots decorated with a ruthenium adatom

• Igor Beljakov,
• Velimir Meded,
• Franz Symalla,
• Karin Fink,
• Sam Shallcross and
• Wolfgang Wenzel

Beilstein J. Nanotechnol. 2013, 4, 441–445, doi:10.3762/bjnano.4.51

• experimentally [4][5][6][7][8][9][10][11]. High magnetic anisotropies were predicted for graphene decorated with transition-metal (TM) adatoms and dimers [12][13]. Inspired by its application potential in the fields of spintronics and magnetic storage as well as fundamental science, a number of works were

Influence of the solvent on the stability of bis(terpyridine) structures on graphite

• Daniela Künzel and
• Axel Groß

Beilstein J. Nanotechnol. 2013, 4, 269–277, doi:10.3762/bjnano.4.29

• distance and interaction energy for water dimers, calculated with different force fields and with quantum chemical methods. Force field molecular dynamics result for the free energy of solvation Esolv for pyridine and benzene in water. Experimental values taken from [35]. Force-field molecular dynamics