Beilstein J. Nanotechnol.2011,2, 261–267, doi:10.3762/bjnano.2.30
aliphatic chains results in epitaxialgrowth on HOPG due to their well matched atomic distances. For example, Watel et al. [24] have shown for long chain alkanes that the carbon skeleton lies parallel to the HOPG surface. On the other hand, epitaxialgrowth of long chain alkanes on Au(111) resulted in a
vertical arrangement of the carbon skeleton [12] on the substrate. Similarly, Dorset et al. [25][26] have also demonstrated the unusual orientation of paraffin waxes by studying their epitaxialgrowth on organic crystals. It is important to note that epitaxialgrowth is limited to the first few layers
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Figure 1:
Consecutive AFM images showing nonacosan-10-ol wax tubule growth on a single crystal Au(111) surfac...