Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• sources of lead exposure [4]. Through contaminated food or drink or through mouth-to-mouth contact, lead can enter the body. Standard techniques for determining lead content involve the use of atomic absorption spectroscopy (AAS) [5] and inductively coupled plasma–mass spectrometry (ICP–MS) [6]. Although

• ZnO frequently causes a reduction in the bandgap, leading to a shift toward longer wavelengths in the absorption spectra. The smaller bandgaps of the samples in optoelectronic devices provide a significant advantage [21]. Zeta potential of Ag@ZnO nanorods Surface properties of the synthesized Ag@ZnO

Size control of nanoparticles synthesized by pulsed laser ablation in liquids using donut-shaped beams

• Abdel Rahman Altakroury,
• Oleksandr Gatsa,
• Farbod Riahi,
• Zongwen Fu,
• Miroslava Flimelová,
• Andrei Samokhvalov,
• Stephan Barcikowski,
• Carlos Doñate-Buendía,
• Alexander V. Bulgakov and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 407–417, doi:10.3762/bjnano.16.31

• increase in the radiation absorption efficiency inside transparent materials because of the implosion of the absorbed energy during propagation [39]. It is crucial to understand the early-stage mechanisms of PLAL to correlate them to NP size control. Plasma plume formation and expansion is a critical step

• that occurs after absorption of the laser radiation and localized heating of the target surface. The plume interacts with the surrounding liquid. This interaction defines the cooling rate of the species present in the plasma and significantly affects NP growth (i.e., plasma quenching forms small NPs

• the spatial distribution of the laser intensity and, thus, the radiation absorption by the target, influencing plasma plume and cavitation bubble formation, evolution, cooling, and the temperature and pressure conditions that determine nanoparticle formation. In the case of a donut-shaped beam, the

Engineered PEG–PCL nanoparticles enable sensitive and selective detection of sodium dodecyl sulfate: a qualitative and quantitative analysis

• Soni Prajapati and
• Ranjana Singh

Beilstein J. Nanotechnol. 2025, 16, 385–396, doi:10.3762/bjnano.16.29

• . Polystyrene latex absorption coefficient and refractive index were used to measure synthesized nanoparticles, prefilled in the software with values of 0.01 and 1.59, respectively. All measurements were performed at 25 °C. The surface morphology of PEG–PCL nanoparticles was analyzed using scanning electron

• PCL segments. The absorption band at 1628 cm−1 represents the characteristic C=O stretching vibration of the ester groups in PCL blocks. The peak at 1510 cm−1 can be assigned to the C–H bending vibrations of the methylene groups. The peaks at 1336 and 1273 cm−1 correspond to the C–O and C–C stretching

• presence of peaks at 2349 and 2073 cm−1 might be due to ambient CO2 absorption or other environmental factors during measurement. This spectral analysis confirms the successful incorporation of PEG and PCL into the nanoparticle structure, showing their characteristic functional groups and molecular

Development of a mucoadhesive drug delivery system and its interaction with gastric cells

• Ahmet Baki Sahin,
• Serdar Karakurt and
• Deniz Sezlev Bilecen

Beilstein J. Nanotechnol. 2025, 16, 371–384, doi:10.3762/bjnano.16.28

• both situations, the effectiveness of the drug formulation depends on several factors such as gastric residence time, gastric emptying, release rate of the drug from the dosage form, and the therapeutic agent reaching the site of action or absorption. Conventional drug delivery systems may not be

• surface area for adhesion. Also, mucus penetration would be hindered because of the mesh-like structure of mucin. For therapeutics that have gastric mucosa as target, this might limit the efficiency and decrease the drug absorption at the site. A smaller particle size, however, is advantageous because of

• the drugs within the mucus microenvironment of the stomach and, thus, may lead to elevated local activity or absorption of the therapeutic agents from the mucosa. Results and Discussion Morphology of nanoparticles After the synthesis of alginate (Alg) and Eudragit-coated alginate (EudAlg

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• nanosecond pulses, graphite has an effective absorption coefficient of 5 µm−1 [26], resulting in an ablation threshold fluence of 0.7 J·cm−2 [27]; thus, our chosen fluence was well below this ablation threshold. The critical melting fluence of graphite has been reported to be 0.13 J·cm−2 [28], suggesting

• absorption and volatilization [35][36]. However, surfaces return to their initial state fast and cannot be kept microscopically clean because the removal of ubiquitous surface contaminants leaves unterminated, highly reactive surfaces with dangling bonds and, as a result, high surface energy, which is

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• and ionized donor levels. The absorbance was also found to decrease with increasing substrate temperature. This is due to the increase in the transparency of films with increasing substrate temperature. A blue shift in the absorption edge was observed with increasing temperature. The absorption

• , 400 °C, 500 °C, and 600 °C, respectively. Figure 5C shows the absorption coefficient as a function of the wavelength for ZnTe/Qz films at different substrate temperatures. From Figure 5C, it is observed that α has very low values at higher wavelengths (≥600 nm). The absorption coefficient increases

• very slowly in this region. In contrast, a sharp increase in α is observed in the lower-wavelength (≤600 nm) region. This type of variation in absorption coefficient points toward the existence of both direct and indirect bandgaps in a material. ZnTe films exhibit both direct and indirect transitions

Fabrication and evaluation of BerNPs regarding the growth and development of Streptococcus mutans

• Tuyen Huu Nguyen,
• Hong Thanh Pham,
• Kieu Kim Thanh Nguyen,
• Loan Hong Ngo,
• Anh Ngoc Tuan Mai,
• Thu Hoang Anh Lam,
• Ngan Thi Kim Phan,
• Dung Tien Pham,
• Duong Thuy Hoang,
• Thuc Dong Nguyen and
• Lien Thi Xuan Truong

Beilstein J. Nanotechnol. 2025, 16, 308–315, doi:10.3762/bjnano.16.23

• analysis of BerNPs samples revealed four characteristic absorption peaks of berberine at 230, 266, 350, and 430 nm (Figure 2A). These peaks are consistent with previous studies on the characteristic absorption spectra of berberine [26][27]. According to the standard curve (Figure 2B), the pure berberine

• . Powder BerNPs were obtained by the freeze-drying for 48 h at −55 °C under vacuum. Physicochemical characterization of BerNPs The specific adsorption peak of BerNPs was determined by UV–vis absorption spectroscopy in a wavelength range from 200 to 600 nm after dilution in methanol. The berberine

• recorded by observing the stained cells attached to the walls of the test tubes. FE-SEM images of (a) berberine and (b) BerNPs. (c) Histogram of particle size distribution of BerNPs. (a) UV–vis absorption spectrum of BerNPs. (b) Standard curve of pure berberine. (c) XRD patterns of pure berberine and

Emerging strategies in the sustainable removal of antibiotics using semiconductor-based photocatalysts

• Yunus Ahmed,
• Keya Rani Dutta,
• Parul Akhtar,
• Md. Arif Hossen,
• Md. Jahangir Alam,
• Obaid A. Alharbi,
• Hamad AlMohamadi and
• Abdul Wahab Mohammad

Beilstein J. Nanotechnol. 2025, 16, 264–285, doi:10.3762/bjnano.16.21

• . General mechanisms of the photocatalysis process Three fundamental steps can be identified in semiconductor photocatalysis for the breakdown of antibiotics in contaminated water, that is, photon absorption, excitation, and reaction [54][55]. When a photocatalyst absorbs photons with energy higher than its

• CB of the material [58][59]. This action serves to reduce the bandgap, which in turn extends the absorption wavelength edge towards the region of visible light [60][61]. The idea of modifying semiconductor materials in the second generation involves the process of co-doping with both metal and

• nonmetal atoms. This method has attracted considerable interest because of its synergistic effect on improving the absorption of visible light and minimizing electron–hole recombination [62][63][64]. However, these synthesized materials not only remove antibiotic pollutants but also impact the formation of

Radiosensitizing properties of dual-functionalized carbon nanostructures loaded with temozolomide

• Radmila Milenkovska,
• Nikola Geskovski,
• Dushko Shalabalija,
• Ljubica Mihailova,
• Petre Makreski,
• Dushko Lukarski,
• Igor Stojkovski,
• Maja Simonoska Crcarevska and
• Kristina Mladenovska

Beilstein J. Nanotechnol. 2025, 16, 229–251, doi:10.3762/bjnano.16.18

• ] in which physicochemical properties of non-covalently PEGylated CNs loaded with TMZ were characterized. Ultraviolet-visible absorption spectroscopy UV–vis absorption spectroscopy turned out to be a useful tool for characterizing functionalization with FA and for confirming the TMZ loading through the

• characteristic absorption peaks of FA (at 280 nm) and TMZ (at 255 and 328 nm, corresponding to the active hydrolytic metabolite MTIC and the prodrug TMZ, respectively) in water solution and the concurrent absence of peaks in water solution of free PEG6000 and unloaded non-PEGylated and PEGylated CNs (Figure 3

Synthesis and the impact of hydroxyapatite nanoparticles on the viability and activity of rhizobacteria

• Bedah Rupaedah,
• Indrika Novella,
• Atiek Rostika Noviyanti,
• Diana Rakhmawaty Eddy,
• Anna Safarrida,
• Abdul Hapid,
• Zhafira Amila Haqqa,
• Suryana Suryana,
• Irwan Kurnia and
• Fathiyah Inayatirrahmi

Beilstein J. Nanotechnol. 2025, 16, 216–228, doi:10.3762/bjnano.16.17

• application and storage [7]. Nanomaterials have gained significant attention in the development of rhizobacterial carrier materials, as their effective utilization can provide protective benefits to plants, assist in nutrient absorption, and, when in gel form, significantly improve water management efficiency

Recent advances in photothermal nanomaterials for ophthalmic applications

• Jiayuan Zhuang,
• Linhui Jia,
• Chenghao Li,
• Rui Yang,
• Jiapeng Wang,
• Wen-an Wang,
• Heng Zhou and
• Xiangxia Luo

Beilstein J. Nanotechnol. 2025, 16, 195–215, doi:10.3762/bjnano.16.16

• photothermal conversion and tunability of light absorption of these materials simplify the therapeutic light source, broadening their applicability [17][18]. Furthermore, the customizable nature of these nanomaterials allows for the development of personalized treatment plans, tailored to individual patient

• , and inorganic semiconductor materials that absorb light through bandgap transitions [25]. The specific photothermal properties of these materials, encompassing aspects such as range and rate of light absorption, photothermal conversion efficiency, heat transfer capability, and photothermal stability

• endogenous chromophores (i.e., blood, water, and melanin) and biomolecules in the human body have a low absorption rate of NIR light. Hence, NIR has a high tissue penetration depth, which can avoid photothermal damage to healthy tissues [35][36][37]. Activation of photothermal nanomaterials with NIR light

A review of metal-organic frameworks and polymers in mixed matrix membranes for CO₂ capture

• Charlotte Skjold Qvist Christensen,
• Nicholas Hansen,
• Mahboubeh Motadayen,
• Nina Lock,
• Martin Lahn Henriksen and
• Jonathan Quinson

Beilstein J. Nanotechnol. 2025, 16, 155–186, doi:10.3762/bjnano.16.14

• , including regenerative solvent-based absorption [2][6], fixed-bed adsorption [7], cryogenic separation techniques [8], and membrane separation methods [9][10][11][12]. Of these, membrane technology offers advantages such as exceptional stability, high efficiency, low energy consumption, and ease of

Clays enhanced with niobium: potential in wastewater treatment and reuse as pigment with antibacterial activity

• Silvia Jaerger,
• Patricia Appelt,
• Mario Antônio Alves da Cunha,
• Fabián Ccahuana Ayma,
• Ricardo Schneider,
• Carla Bittencourt and
• Fauze Jacó Anaissi

Beilstein J. Nanotechnol. 2025, 16, 141–154, doi:10.3762/bjnano.16.13

• modified with niobium are presented in Figure 7. It can be observed that the NbOPO4 and Nb2O5 powder samples do not show an absorption band. However, the bentonite modified with these compounds exhibited a band with a maximum of 493 nm. The samples BEOx and BEPh obtained after adsorption/photocatalysis

• present profiles like BE clay, with intense absorption in the UV region with a sharp drop of around 550 nm [8]. This fact indicates the feasibility of activating the A-BEPh, A-BEPhP, A-BEOx, and A-BEOXPh samples under visible light (above 400 nm) [8]. The indirect bandgap energy values for the BE, NbOPO4

• shown in Supporting Information File 1, Figure S3. It is possible to observe that the BEOx and BEPh samples dispersed in clear paint, despite presenting a yellow coloration, did not show absorption bands. The samples collected after the adsorption/photocatalysis assays exhibited bands in the maximum

TiO₂ immobilized on 2D mordenite: effect of hydrolysis conditions on structural, textural, and optical characteristics of the nanocomposites

• Marina G. Shelyapina,
• Rosario Isidro Yocupicio-Gaxiola,
• Gleb A. Valkovsky and
• Vitalii Petranovskii

Beilstein J. Nanotechnol. 2025, 16, 128–140, doi:10.3762/bjnano.16.12

• . Nitrogen sorption and thermogravimetric studies Figure 5a,b shows the N2 adsorption/desorption isotherms of the studied nanocomposites. They demonstrate features characteristic of hierarchical porous structures possessing both micro- and mesoporosity. At low pressure, there is a sharp gas absorption

• (isotherm I or II according to IUPAC classification); at increasing pressure, the absorption continues and is accompanied by a hysteresis loop (isotherm IV according to IUPAC classification). For the series of Ti-WNh-C samples hydrolyzed in pure water, the inflection point on the desorption curves appears

• diffuse reflectance spectra. In this method, it is assumed that the energy-dependent absorption coefficient α can be written as where h is the Planck constant, hν is the photon energy, and B is a constant. The factor n depends on the nature of the electron transition, that is, n = 1/2 for direct and n = 2

Comparison of organic and inorganic hole transport layers in double perovskite material-based solar cell

• Deepika K and
• Arjun Singh

Beilstein J. Nanotechnol. 2025, 16, 119–127, doi:10.3762/bjnano.16.11

• deteriorate. Inorganic HTLs proved to perform better. Some examples of inorganic HTLs are CuI, Cu2O, and CuSCN. Organic HTLs consist of polymers or complex molecules, which affect the photovoltaic properties of the device in terms of light absorption and carrier mobility. Some examples of organic materials

• both HTL materials (Table 3 and Figure 3). The increase of the PCE with Cu2O signifies a better absorption of light with minimum reflection and, hence, increased carrier transportation across the interface. Cu2O is inorganic, and the high temperature leads to improved hole mobility and better charge

Nanocarriers and macrophage interaction: from a potential hurdle to an alternative therapeutic strategy

• Naths Grazia Sukubo,
• Paolo Bigini and
• Annalisa Morelli

Beilstein J. Nanotechnol. 2025, 16, 97–118, doi:10.3762/bjnano.16.10

Characterization of ZnO nanoparticles synthesized using probiotic Lactiplantibacillus plantarum GP258

• Prashantkumar Siddappa Chakra,
• Aishwarya Banakar,
• Shriram Narayan Puranik,
• Vishwas Kaveeshwar,
• C. R. Ravikumar and
• Devaraja Gayathri

Beilstein J. Nanotechnol. 2025, 16, 78–89, doi:10.3762/bjnano.16.8

• stretching vibrations, and at 1626 cm−1, indicating H–O–H bending vibrations. Additionally, we found a peak at 2924 cm−1, connected to C–H bonds, and peaks between 1400 and 1649 cm−1, associated with C=O stretching vibrations. A band around 2335 cm−1 could be attributed to CO2 absorption on metallic Zn2

• + cations. These findings offer information about the structure and chemical interactions within the ZnO NPs (Figure 2b). UV–vis absorption The UV–Vis absorption spectra of ZnO NPs, presented in Figure 2c, establish a distinct absorption peak at 3.16 eV, revealing the characteristic bandgap energy for ZnO

A nanocarrier containing carboxylic and histamine groups with dual action: acetylcholine hydrolysis and antidote atropine delivery

• Elina E. Mansurova,
• Andrey A. Maslennikov,
• Anna P. Lyubina,
• Alexandra D. Voloshina,
• Irek R. Nizameev,
• Marsil K. Kadirov,
• Anzhela A. Mikhailova,
• Polina V. Mikshina,
• Albina Y. Ziganshina and
• Igor S. Antipin

Beilstein J. Nanotechnol. 2025, 16, 11–24, doi:10.3762/bjnano.16.2

• ), a hypsochromic shift in absorption typical of Fl in organic solvents is observed, confirming the location of Fl in the organic core. The rise in baseline indicates dispersed media (Figure 6a). In the fluorescence spectra (PB, pH 7.4), the emission intensity of Fl@p(Hist-CA) is significantly lower

• ) solution, post-reaction and after 3.5 h of dialysis (C(RA) = 0.4 mM), was placed in a 12000 Da dialysis bag with ACh added at concentrations of 0.4, 4, and 40 mM. The dialysate volume was 50 mL. Yield and concentration of atropine were assessed through UV absorption at 224 nm, revealing that approximately

Orientation-dependent photonic bandgaps in gold-dust weevil scales and their titania bioreplicates

• Norma Salvadores Farran,
• Limin Wang,
• Primoz Pirih and
• Bodo D. Wilts

Beilstein J. Nanotechnol. 2025, 16, 1–10, doi:10.3762/bjnano.16.1

• customizable photonic bandgaps that might be used in novel optical materials. Keywords: animal coloration; photonic crystal; polarization conversion; sol–gel replication; weevil; Introduction Animal coloration is produced by means of absorption, scattering, luminescence, and interference. The latter is

Fabrication of hafnium-based nanoparticles and nanostructures using picosecond laser ablation

• Abhishek Das,
• Mangababu Akkanaboina,
• Jagannath Rathod,
• R. Sai Prasad Goud,
• Kanaka Ravi Kumar,
• Raghu C. Reddy,
• Ratheesh Ravendran,
• Katia Vutova,
• S. V. S. Nageswara Rao and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1639–1653, doi:10.3762/bjnano.15.129

• . All NPs exhibited novel optical reflectance properties. Reflectance measurements revealed that the fabricated NPs had a very high and broad optical absorption throughout the UV–vis–NIR range. The NPs synthesised in toluene exhibited the best absorption. The successful fabrication of Hf NSs with the

• optical properties [1][2][3][4]. Hf and its alloys are used in nuclear reactors because of their large neutron absorption cross sections and high melting points [5]. They are also used in submarines because of their corrosion resistance [6][7]. The high refractoriness of some Hf compounds [2][4] allows

• ) and the NIR (λ = 1200 nm) spectral regions of the NPs under different angles of incidence are summarised in Table 2. Based on the data, it can be concluded that Hf NPs show a very high and wide optical absorption from UV to NIR. HfNPs-T especially show exceptional performance compared to other NPs

Heterogeneous reactions in a HFCVD reactor: simulation using a 2D model

• Xochitl Aleyda Morán Martínez,
• José Alberto Luna López,
• Zaira Jocelyn Hernández Simón,
• Gabriel Omar Mendoza Conde,
• José Álvaro David Hernández de Luz and
• Godofredo García Salgado

Beilstein J. Nanotechnol. 2024, 15, 1627–1638, doi:10.3762/bjnano.15.128

• ratio x = [O]/[Si], which is determined by controlling key parameters in the deposition process [2]. This ratio determines optical and electrical properties such as bandgap energy, absorption coefficient, photoluminescence, refractive index, and electrical conductivity [3]. SiOx cannot only be obtained

Biomimetic nanocarriers: integrating natural functions for advanced therapeutic applications

• Hugo Felix Perini,
• Beatriz Sodré Matos,
• Carlo José Freire de Oliveira and
• Marcos Vinicius da Silva

Beilstein J. Nanotechnol. 2024, 15, 1619–1626, doi:10.3762/bjnano.15.127

• the production of nature-inspired synthetics as demonstrated in Figure 2B [22][23][24][25][26]. Indeed, the co-incubation of nanoparticles with cellular components creates an environment conducive to the absorption of proteins by the nanoparticles, thereby facilitating the connection of these

• drug absorption by the mononuclear phagocytic system due to its hydrophilic barrier [59]. Although PEG-coated nanostructures exhibit promising physicochemical properties, they have shown limitations; studies point to cases of hypersensitivity in PEGylated vaccines [60][61]. Potential adverse immune

• antiviral treatments. Tan et al. (2021) employed lopinavir (LPV), an antiviral drug, in polymeric nanoparticles coated with macrophage membranes (PLGA-LPV@M). This biomimetic nanocarrier demonstrated the ability to inherit the antigenic profile of macrophages, enabling the absorption of pro-inflammatory

Liver-targeting iron oxide nanoparticles and their complexes with plant extracts for biocompatibility

• Shushanik A. Kazaryan,
• Seda A. Oganian,
• Gayane S. Vardanyan,
• Anatolie S. Sidorenko and
• Ashkhen A. Hovhannisyan

Beilstein J. Nanotechnol. 2024, 15, 1593–1602, doi:10.3762/bjnano.15.125

• applications. Spectral analysis of the composite of Fe3O4 NPs with 70% ethanol extract of T. polium in our previous studies revealed the formation of a complex with leveling of peaks characteristic of the extract and a hypochromic shift in the Fe3O4 NPs absorption spectrum [50]. The results of the impact of

Facile synthesis of size-tunable L-carnosine-capped silver nanoparticles and their role in metal ion sensing and catalytic degradation of p-nitrophenol

• Akash Kumar,
• Ridhima Chadha,
• Abhishek Das,
• Nandita Maiti and
• Rayavarapu Raja Gopal

Beilstein J. Nanotechnol. 2024, 15, 1576–1592, doi:10.3762/bjnano.15.124

• ʟ-carnosine in synthesizing tunable plasmonic silver nanoparticles (ʟ-car-AgNPs). The formation of ʟ-car-AgNPs was confirmed via UV–vis optical absorption spectroscopy, showing single and double plasmonic peaks, depending on the synthesis conditions. Physicochemical characterization using TEM, FTIR

• heavy metal ion monitoring in environmental samples involve complex analytical instrumental techniques such as atomic absorption spectroscopy, inductively coupled plasma mass spectrometry, and high-performance liquid chromatography [8][9]. Environmental remediation of P-NP requires processes such as

• linear plot of the absorption as a function of the concentration of the detected metal ions. ʟ-carnosine-capped silver nanoparticles as the catalytic agent ʟ-car-AgNPs were evaluated regarding their catalytic performance in the degradation of P-NP as a model substrate. P-NP is reduced and forms p

Green synthesis of silver nanoparticles derived from algae and their larvicidal properties to control Aedes aegypti

• Matheus Alves Siqueira de Assunção,
• Douglas Dourado,
• Daiane Rodrigues dos Santos,
• Gabriel Bezerra Faierstein,
• Mara Elga Medeiros Braga,
• Severino Alves Junior,
• Rosângela Maria Rodrigues Barbosa,
• Herminio José Cipriano de Sousa and
• Fábio Rocha Formiga

Beilstein J. Nanotechnol. 2024, 15, 1566–1575, doi:10.3762/bjnano.15.123

• characteristics such as greater absorption capacity, greater bioavailability, controlled release of active ingredients, improved solubility of hydrophobic substances in water, and good kinetic stability [12][13][14]. Metallic nanoparticles have been investigated as a promising approach for vector control. The