Review of advanced sensor devices employing nanoarchitectonics concepts

• Katsuhiko Ariga,
• Tatsuyuki Makita,
• Masato Ito,
• Taizo Mori,
• Shun Watanabe and
• Jun Takeya

Beilstein J. Nanotechnol. 2019, 10, 2014–2030, doi:10.3762/bjnano.10.198

• sensing of general external environments such as pH, humidity, pressure, and magnetic field is undoubtedly important. Spanu et al. reported sensitive pH sensors based on organic charge-modulated field-effect transistor structures with 6,13-bis(triisopropylsilylethynyl)pentacene [95]. The fabricated

• -driven actuation material for a triboelectric nanogenerator device to realize a highly sensitive humidity sensor [99] (Figure 5). The reaction of the sensing materials to humidity results in electrical changes for sensing. The perfluorosulfonic acid ionomer membrane has perpendicularly extended

• nanochannels that can adsorb moisture. Under relatively high humidity conditions, the adsorption of water molecules expands the nanochannels resulting in internal stress generation. These changes can be sensitively detected by the triboelectric nanogenerator. At the same time, the collection of such electrical

Nanostructured and oriented metal–organic framework films enabling extreme surface wetting properties

• Andre Mähringer,
• Julian M. Rotter and
• Dana D. Medina

Beilstein J. Nanotechnol. 2019, 10, 1994–2003, doi:10.3762/bjnano.10.196

• antifog coating covering their eyes for clear vision in high humidity regions [8]. The fogstand beetles employ an antifog coating for enhancing water vapor harvesting abilities in dry climates [9]. In marine life, fish protect themselves from oil-polluted environments or avoid biofouling due to oil

Gold-coated plant virus as computed tomography imaging contrast agent

• Alaa A. A. Aljabali,
• Mazhar S. Al Zoubi,
• Khalid M. Al-Batanyeh,
• Ali Al-Radaideh,
• Mohammad A. Obeid,
• Abeer Al Sharabi,
• Walhan Alshaer,
• Bayan AbuFares,
• Tasnim Al-Zanati,
• Murtaza M. Tambuwala,
• Naveed Akbar and
• David J. Evans

Beilstein J. Nanotechnol. 2019, 10, 1983–1993, doi:10.3762/bjnano.10.195

• culture flasks at 6000 cells/cm2 in growth medium phenol red-free following the published protocol [50]. All cells were cultured in a humidified incubator at 95% humidity and 5% CO2 maintained at 37 °C. For experiments cells were seeded the day prior to the incubation with the NPs at 3.5 × 104 cells/cm3

Preservation of rutin nanosuspensions without the use of preservatives

• Pascal L. Stahr and
• Cornelia M. Keck

Beilstein J. Nanotechnol. 2019, 10, 1902–1913, doi:10.3762/bjnano.10.185

• cell spreader. For detection of existing bacteria, the agar plate containing the suspension or dilution was incubated for 24 h at 36 °C and 90% humidity. Fungal contamination was detected after 7 days at 25 °C storage by using undiluted nanosuspensions. For evaluation, the visible bacterial colonies

High-temperature resistive gas sensors based on ZnO/SiC nanocomposites

• Vadim B. Platonov,
• Marina N. Rumyantseva,
• Alexander S. Frolov,
• Alexey D. Yapryntsev and
• Alexander M. Gaskov

Beilstein J. Nanotechnol. 2019, 10, 1537–1547, doi:10.3762/bjnano.10.151

• (XPS). The electrophysical and gas sensing properties of the materials were investigated by in situ conductivity measurements in the presence of the reducing gases CO and NH3 (20 ppm), in dry conditions (relative humidity at 25 °C RH25 = 0) and in humid air (RH25 = 30%) in the temperature range 400–550

• monitoring the complete combustion of fuel and controlling medium-temperature chemical and metallurgical processes [3][4][5]. The development of high-temperature gas sensors requires the creation of new materials that are stable at 300–600 °C, high humidity, and lack of oxygen. Nanostructured semiconductor

• ,d) in dry air (Figure 8a,c) and at relative humidity RH25 = 30% (at 25 °C, Figure 8b,d). In all cases, in the presence of a reducing gas, CO or NH3, a decrease in the material resistance is observed due to reaction of the target gases with the oxygen chemisorbed on the surface of n-type

Development of a new hybrid approach combining AFM and SEM for the nanoparticle dimensional metrology

• Loïc Crouzier,
• Alexandra Delvallée,
• Sébastien Ducourtieux,
• Laurent Devoille,
• Guillaume Noircler,
• Christian Ulysse,
• Olivier Taché,
• Elodie Barruet,
• Christophe Tromas and
• Nicolas Feltin

Beilstein J. Nanotechnol. 2019, 10, 1523–1536, doi:10.3762/bjnano.10.150

• humidity and temperature are well controlled and stabilized (50 ± 5% relative humidity and 20 ± 0.15 °C for temperature). These precautions combined with the instrument performances make it possible to obtain low drifts and to carry out measurements with low noise. Basic measuring principle and data

Synthesis of P- and N-doped carbon catalysts for the oxygen reduction reaction via controlled phosphoric acid treatment of folic acid

• Rieko Kobayashi,
• Takafumi Ishii,
• Yasuo Imashiro and
• Jun-ichi Ozaki

Beilstein J. Nanotechnol. 2019, 10, 1497–1510, doi:10.3762/bjnano.10.148

• cm2 cell was used for fuel-cell testing. Polarization curves were obtained at a cell temperature of 80 °C, a back pressure of 200 kPa, and a reactant gas relative humidity of 100% using H2 (1 L·min−1) and O2 (1 L·min−1) as anode and cathode gases, respectively. Characterization techniques The Brunauer

Selective gas detection using Mn₃O₄/WO₃ composites as a sensing layer

• Yongjiao Sun,
• Zhichao Yu,
• Wenda Wang,
• Pengwei Li,
• Gang Li,
• Wendong Zhang,
• Lin Chen,
• Serge Zhuivkov and
• Jie Hu

Beilstein J. Nanotechnol. 2019, 10, 1423–1433, doi:10.3762/bjnano.10.140

• derived from temperature, the working temperature of a sensor is a key factor related to its sensing properties [21]. Therefore, it becomes necessary to optimize the working temperature. Unless otherwise stated, all gas sensing measurements were carried out at a humidity of ≈35 RH%. Figure 6 shows the

Gas sensing properties of individual SnO₂ nanowires and SnO₂ sol–gel nanocomposites

• Alexey V. Shaposhnik,
• Dmitry A. Shaposhnik,
• Sergey Yu. Turishchev,
• Olga A. Chuvenkova,
• Stanislav V. Ryabtsev,
• Alexey A. Vasiliev,
• Xavier Vilanova,
• Francisco Hernandez-Ramirez and
• Joan R. Morante

Beilstein J. Nanotechnol. 2019, 10, 1380–1390, doi:10.3762/bjnano.10.136

• considerably smaller amounts of hydroxy groups compared to the nanopowders. This leads to a decrease in the parasitic sensitivity of the sensing materials to humidity. In addition, we demonstrated that the nanowires are characterized by a nearly single-crystalline structure, ensuring higher stability of the

• maximal or minimal values of current transfer. As shown in Figure 11, a maximum response in both nanowire and sol–gel sensors is observed at a temperature of around 250 °C. The effect of superficial hydroxy groups on the sensor cross-sensitivity to humidity was investigated in detail in [52]. It was shown

• that the application of tin dioxide materials synthesized by spark discharge and characterized as having a reduced concentration of superficial hydroxy groups resulted in a significantly decreased parasitic humidity response of the sensing material. The same effect is observed for the tin dioxide

Multicomponent bionanocomposites based on clay nanoarchitectures for electrochemical devices

• Giulia Lo Dico,
• Bernd Wicklein,
• Lorenzo Lisuzzo,
• Giuseppe Lazzara,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2019, 10, 1303–1315, doi:10.3762/bjnano.10.129

• -casting from the 0.2% w/v dispersion on polyester Petri dishes and dried at 30 °C and 60% relative humidity (RH) in a CLIMACELL EVO Stability Chamber (Incubator model 111L). The bionanocomposite foams were prepared by freeze-drying (Cryodos-80, Telstar) of the 8% w/v dispersion, which was cast in

Alloyed Pt₃M (M = Co, Ni) nanoparticles supported on S- and N-doped carbon nanotubes for the oxygen reduction reaction

• Stéphane Louisia,
• Yohann R. J. Thomas,
• Pierre Lecante,
• Marie Heitzmann,
• M. Rosa Axet,
• Pierre-André Jacques and
• Philippe Serp

Beilstein J. Nanotechnol. 2019, 10, 1251–1269, doi:10.3762/bjnano.10.125

Serum type and concentration both affect the protein-corona composition of PLGA nanoparticles

• Katrin Partikel,
• Robin Korte,
• Dennis Mulac,
• Hans-Ulrich Humpf and
• Klaus Langer

Beilstein J. Nanotechnol. 2019, 10, 1002–1015, doi:10.3762/bjnano.10.101

• cm2 flasks with DMEM supplemented with 10% (v/v) FBS, 1% (v/v) non-essential amino acids (NEA), 1% (v/v) L-alanyl-L-glutamine (200 mM), 1% (v/v) penicillin/streptomycin (100 U/mL) at 37 °C, 100% humidity in a 10% CO2 atmosphere. Cells were subcultivated twice a week at a ratio of approximately 1:5

On the transformation of “zincone”-like into porous ZnO thin films from sub-saturated plasma enhanced atomic layer deposition

• Alberto Perrotta,
• Julian Pilz,
• Stefan Pachmajer,
• Antonella Milella and
• Anna Maria Coclite

Beilstein J. Nanotechnol. 2019, 10, 746–759, doi:10.3762/bjnano.10.74

• layers, the THMS600 temperature stage was equipped with a custom-made humidity pump, and the principles of ellipsometric porosimetry (EP) were used. The relative humidity was monitored via a sensor in the measurement chamber (Sparkfun SHT-15) and tuned in the range of 0–95% [44]. In this way, pores with

• a diameter ≥0.33 nm were probed. Dry atmosphere (i.e., 0% relative humidity) was reached using a flow of N2, ensuring the removal of water from the measurement chamber. In order to tune the relative humidity, the flow of humid air is mixed with N2 and adjusted in equilibrium steps. The temperature

• of the stage was kept at room temperature, assuring that the measured relative humidity in the chamber was the same as on top of the samples. During EP with water, the variation of both refractive index (n) and water multilayer thickness/swollen thin films is reported as a function of the relative

Topochemical engineering of composite hybrid fibers using layered double hydroxides and abietic acid

• Liji Sobhana,
• Lokesh Kesavan,
• Jan Gustafsson and
• Pedro Fardim

Beilstein J. Nanotechnol. 2019, 10, 589–605, doi:10.3762/bjnano.10.60

• solution. The newly formed wet hybrid fiber handsheets were pressed twice at a force of 400 ± 10 kPa between couch blotters for increased drying. Further, these handsheets were conditioned at 23 °C temperature in a room with 50% of relative humidity for 2 days. Functionalization of LDH grafted cellulose

Hydrophilicity and carbon chain length effects on the gas sensing properties of chemoresistive, self-assembled monolayer carbon nanotube sensors

• Juan Casanova-Cháfer,
• Carla Bittencourt and
• Eduard Llobet

Beilstein J. Nanotechnol. 2019, 10, 565–577, doi:10.3762/bjnano.10.58

• were most responsive to nitrogen dioxide and ethanol vapors, even in the presence of ambient humidity. In particular, this nanomaterial was about eight times more sensitive to nitrogen dioxide than bare Au-decorated carbon nanotubes when operated at room temperature. This response enhancement is

• such as lack of selectivity, environmental variations (e.g., changes in humidity level) affecting sensor response, or the difficulty to detect gases characterized by low adsorption energies are often encountered [11]. In order to enhance their selectivity and/or their sensitivity, CNTs have been

• humidified to 50% relative humidity (at 20 °C) and the same nitrogen dioxide concentrations that had been studied previously under dry conditions were measured again. These results are shown in Figure 7. As it could be expected, the presence of ambient moisture increases the sensitivity to a polar gas like

Temperature-dependent Raman spectroscopy and sensor applications of PtSe₂ nanosheets synthesized by wet chemistry

• Mahendra S. Pawar and
• Dattatray J. Late

Beilstein J. Nanotechnol. 2019, 10, 467–474, doi:10.3762/bjnano.10.46

• well with the reported 2D transition metal dichalcogenides. A PtSe2 nanosheet-based sensor device was tested for its applicability as a humidity sensor and photodetector. The humidity sensor based on PtSe2 nanosheets showed an excellent recovery time of ≈5 s, indicating the great potential of PtSe2 for

• annealed in a vacuum furnace at 170 °C to improve the contact resistance and adhesion of the nanosheets with the substrate. The humidity sensing performance was investigated by exposing the sensor device to various relative humidity (RH) levels ranging from 11.3–97.3% as described in detail previously [26

• comparison of the temperature coefficient values corresponding to various 2D materials are shown in Table 2. The value of Δω for both Eg and A1g modes was found to be 6.11 cm−1 and 3.14 cm−1, respectively. Humidity sensor and photodetector based on few-layer PtSe2 nanosheets Figure 7a shows the typical

Uniform Sb₂S₃ optical coatings by chemical spray method

• Jako S. Eensalu,
• Atanas Katerski,
• Erki Kärber,
• Ilona Oja Acik,
• Arvo Mere and
• Malle Krunks

Beilstein J. Nanotechnol. 2019, 10, 198–210, doi:10.3762/bjnano.10.18

• inside a glovebox with controlled humidity (<14 ppm). The solutions were ultrasonically nebulized and guided by compressed air at a flow rate of 5 L·min−1 onto glass/ITO/TiO2 substrates at deposition temperatures of 200, 210, and 220 °C for 20 min (Sb/S 1:3) or 40 min (Sb/S 1:6). After deposition, some

Wet chemistry route for the decoration of carbon nanotubes with iron oxide nanoparticles for gas sensing

• Hussam M. Elnabawy,
• Juan Casanova-Chafer,
• Badawi Anis,
• Mostafa Fedawy,
• Mattia Scardamaglia,
• Carla Bittencourt,
• Ahmed S. G. Khalil,
• Eduard Llobet and
• Xavier Vilanova

Beilstein J. Nanotechnol. 2019, 10, 105–118, doi:10.3762/bjnano.10.10

• as well as the effect of ambient humidity. Experimental Materials All materials and reagents used (listed below) were of analytical grade and were used as received. COOH functionalized multiwalled carbon nanotube (MWCNTs), Nanocyl (C purity higher than 95%) Nitric acid, Scharlau (HNO3 68–70

• recovery in dry air. To determine the selectivity of the sensor for carbon monoxide (CO) and benzene (C6H6), gas cylinders with a 100 ppm CO and 10 ppm C6H6 concentrations respectively, balanced in dry air, were used with the previously described set-up. To create the desired humidity in order to check the

• check the effect of humidity in the performance of the sensor, a new set of measurements for NO2 were performed. In this case, the relative humidity was set to 50%. Comparing these results with the ones performed with dry air (relative humidity was around 3%), one can realize that the sensor, when

Pull-off and friction forces of micropatterned elastomers on soft substrates: the effects of pattern length scale and stiffness

• Peter van Assenbergh,
• Marike Fokker,
• Julian Langowski,
• Jan van Esch,
• Marleen Kamperman and
• Dimitra Dodou

Beilstein J. Nanotechnol. 2019, 10, 79–94, doi:10.3762/bjnano.10.8

A comparison of tarsal morphology and traction force in the two burying beetles Nicrophorus nepalensis and Nicrophorus vespilloides (Coleoptera, Silphidae)

• Liesa Schnee,
• Benjamin Sampalla,
• Josef K. Müller and
• Oliver Betz

Beilstein J. Nanotechnol. 2019, 10, 47–61, doi:10.3762/bjnano.10.5

• experiments were carried out at room temperature (ca. 22 °C) and a relative humidity of ca. 50%. Friction was determined on the fore tarsus for five males and five females (n = 10). The measuring head was dragged over the surface with a load of 2 mN and a velocity of 100 µm/s. For each measurement, the

Contact splitting in dry adhesion and friction: reducing the influence of roughness

• Jae-Kang Kim and
• Michael Varenberg

Beilstein J. Nanotechnol. 2019, 10, 1–8, doi:10.3762/bjnano.10.1

• ) operated for 180 seconds at 18 mA current and about 5 × 10−2 Pa Ar pressure. All tests were repeated at least four times. The temperature and relative humidity in the laboratory were 23–25 °C and 45–55%, respectively. Characteristic images of tested polyvinylsiloxane (PVS) adhesive microstructures in (a

Electrostatic force microscopy for the accurate characterization of interphases in nanocomposites

• Diana El Khoury,
• Richard Arinero,
• Jean-Charles Laurentie,
• Mikhaël Bechelany,
• Michel Ramonda and
• Jérôme Castellon

Beilstein J. Nanotechnol. 2018, 9, 2999–3012, doi:10.3762/bjnano.9.279

• readily than Al2O3, as observed in Figure 8, and as confirmed by measurements performed in a highly humid environment [38]. Indeed, in the presence of high humidity, only scanning over alumina-covered samples was possible. All used probes were fixed to the surface and were consequently crushed or became

Graphene-enhanced metal oxide gas sensors at room temperature: a review

• Dongjin Sun,
• Yifan Luo,
• Marc Debliquy and
• Chao Zhang

Beilstein J. Nanotechnol. 2018, 9, 2832–2844, doi:10.3762/bjnano.9.264

• concentrations of NH3 and responded dramatically, which could be ascribed to the p–n heterojunctions formed between ZnO and rGO. However, the influence of humidity on the sensor response was not negligible due to the residual oxygen (high hydrophilicity) on rGO and the active sites (oxygen vacancies) on ZnO

• affected the sensor at low humidity levels. However, the response of the composite sensor increased with increasing humidity at high humidity levels. At low humidity levels, ammonia and water molecules competed for adsorption, which reduces the sensing performance of NH3. As humidity levels increased

• , ammonia adsorbed on the surface of sensor by dissolving into water, leading to the higher response. This is quite different from the usual opinion that sensitivity will decrease at high humidity levels. Zhang et al. [47] synthesized CuO nanoflowers via hydrothermal method, then CuO and rGO were deposited

Biomimetic surface structures in steel fabricated with femtosecond laser pulses: influence of laser rescanning on morphology and wettability

• Camilo Florian Baron,
• Alexandros Mimidis,
• Daniel Puerto,
• Evangelos Skoulas,
• Emmanuel Stratakis,
• Javier Solis and
• Jan Siegel

Beilstein J. Nanotechnol. 2018, 9, 2802–2812, doi:10.3762/bjnano.9.262

• related to water transport, although in this case not for camouflage but hydration purposes, which is vital considering the natural habitat of this lizard is the desert. The humidity in the air or moisture at the surface of rocks on which the lizard is standing can condense at the skin tiles, flowing

• surfaces were polished obtaining mirror-like quality with an average roughness Ra < 2 nm measured by an atomic force microscope (AFM, Agilent 5100 AFM/SPM in tapping mode). In order to avoid environmental oxidation by humidity, the samples were stored in a desiccator at 30% relative humidity. Before and

Characterization of the microscopic tribological properties of sandfish (Scincus scincus) scales by atomic force microscopy

• Weibin Wu,
• Christian Lutz,
• Simon Mersch,
• Richard Thelen,
• Christian Greiner,
• Guillaume Gomard and
• Hendrik Hölscher

Beilstein J. Nanotechnol. 2018, 9, 2618–2627, doi:10.3762/bjnano.9.243

• controlled temperature (21–23 °C) and humidity (50–70%). All AFM experiments were conducted with a Dimension Icon AFM (Veeco Inc., USA). The topography of the samples was measured in tapping mode while adhesion force, friction, and wear analysis were conducted in contact mode. No extra treatment was applied

• (National Instruments, Austin, USA) code. The tests were conducted at room temperature and in air with 50% relative humidity. Sample preparation for the non-biological samples relied on grinding with SiC papers of #800 down to #4000 grid. Mechanical polishing was carried out with a 3 µm diamond suspension