Controlling the electronic and physical coupling on dielectric thin films

• Philipp Hurdax,
• Michael Hollerer,
• Larissa Egger,
• Georg Koller,
• Xiaosheng Yang,
• Anja Haags,
• Serguei Soubatch,
• Frank Stefan Tautz,
• Mathias Richter,
• Alexander Gottwald,
• Peter Puschnig,
• Martin Sterrer and
• Michael G. Ramsey

Beilstein J. Nanotechnol. 2020, 11, 1492–1503, doi:10.3762/bjnano.11.132

• . The azimuthal orientations of the molecules can be derived by comparing the orientations of the molecular emission patterns to the orientation of the emission pattern from the Ag(100) substrate or from the crystal surface unit cell inferred from low energy electron diffraction (LEED) experiments. This

Self-assembly and spectroscopic fingerprints of photoactive pyrenyl tectons on hBN/Cu(111)

• Domenik M. Zimmermann,
• Knud Seufert,
• Luka Ðorđević,
• Tobias Hoh,
• Sushobhan Joshi,
• Tomas Marangoni,
• Davide Bonifazi and
• Willi Auwärter

Beilstein J. Nanotechnol. 2020, 11, 1470–1483, doi:10.3762/bjnano.11.130

• excitation of the low-energy absorption peak lead to a strong emission at 433 and 458 nm (2.86 and 2.71 eV), with a quantum yield of 96% (determined using coumarin 153 in an EtOH solution as a reference). As expected, the tetrasubstituted pyrene 1 showed electronic transitions that were bathochromically

Superconductor–insulator transition in capacitively coupled superconducting nanowires

• Alex Latyshev,
• Andrew G. Semenov and
• Andrei D. Zaikin

Beilstein J. Nanotechnol. 2020, 11, 1402–1408, doi:10.3762/bjnano.11.124

• proportional to that of the total charge that has passed through the point x of the ith wire up to the time moment t, i.e., Provided that the wires are thick enough, the low energy Hamiltonian in Equation 1 is sufficient. However, for thinner wires, one should also account for the effect of quantum phase

Analysis of catalyst surface wetting: the early stage of epitaxial germanium nanowire growth

• Owen C. Ernst,
• Felix Lange,
• David Uebel,
• Thomas Teubner and
• Torsten Boeck

Beilstein J. Nanotechnol. 2020, 11, 1371–1380, doi:10.3762/bjnano.11.121

• these clusters or if it just becomes thinner or perforated. However, the TEM data do not show any evidence of a wetting layer at room temperature, since at this temperature only very small gold clusters are seen. This is in agreement with low-energy electron microscopy (LEEM) calculations, which predict

Impact of fluorination on interface energetics and growth of pentacene on Ag(111)

• Qi Wang,
• Meng-Ting Chen,
• Antoni Franco-Cañellas,
• Bin Shen,
• Thomas Geiger,
• Holger F. Bettinger,
• Frank Schreiber,
• Ingo Salzmann,
• Alexander Gerlach and
• Steffen Duhm

Beilstein J. Nanotechnol. 2020, 11, 1361–1370, doi:10.3762/bjnano.11.120

• ) on Ag(111) via X-ray standing waves (XSW), low-energy electron diffraction (LEED) as well as ultraviolet and X-ray photoelectron spectroscopy (UPS and XPS). XSW revealed that the adsorption distances of F4PEN in (sub)monolayers on Ag(111) were 3.00 Å for carbon atoms and 3.05 Å for fluorine atoms

Hybridization vs decoupling: influence of an h-BN interlayer on the physical properties of a lander-type molecule on Ni(111)

• Maximilian Schaal,
• Takumi Aihara,
• Marco Gruenewald,
• Felix Otto,
• Jari Domke,
• Roman Forker,
• Hiroyuki Yoshida and
• Torsten Fritz

Beilstein J. Nanotechnol. 2020, 11, 1168–1177, doi:10.3762/bjnano.11.101

• the DBP molecules are well decoupled from the Ni(111) surface. Furthermore, a highly ordered DBP monolayer is obtained on h-BN/Ni(111) by depositing the molecules at a substrate temperature of 170 °C. The structural results are obtained by quantitative low-energy electron diffraction and low

• comprehensive study we utilized differential reflectance spectroscopy (DRS), low-energy electron diffraction (LEED), low-temperature scanning tunneling microscopy (LT-STM), as well as photoelectron spectroscopy (PES). Our results reveal that DBP on h-BN/Ni(111) is well decoupled from the metal substrate Ni(111

Scanning tunneling microscopy and spectroscopy of rubrene on clean and graphene-covered metal surfaces

• Karl Rothe,
• Alexander Mehler,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2020, 11, 1157–1167, doi:10.3762/bjnano.11.100

• may tentatively be explained by a molecular superstructure that is formed owing to the optimization of the intermolecular coupling. This might be facilitated by very low energy barriers, which are even lower than those observed for C42H28 on Au(111), for translational and rotational degrees of freedom

• preparation parameters for C42H28 deposition on Au(111) as on Pt(111) leads to island growth with a regular superstructure. The crystalline adsorption phase unravels that low energy barriers for translation and rotation of the molecule exist because the individual C42H28 molecules can optimize the coupling to

Monolayers of MoS₂ on Ag(111) as decoupling layers for organic molecules: resolution of electronic and vibronic states of TCNQ

• Asieh Yousofnejad,
• Gaël Reecht,
• Nils Krane,
• Christian Lotze and
• Katharina J. Franke

Beilstein J. Nanotechnol. 2020, 11, 1062–1071, doi:10.3762/bjnano.11.91

• charging. Additionally, a mode at 40 meV has a large Huang–Rhys factor. The excitation of this mode is not energetically well separated from the elastic onset of the LUMO in experiment. However, this mode contributes to an asymmetric line shape, which can be realized by comparing the low-energy flank to

• the high-energy fall-off of the first resonance. The low-energy side can be fitted by a Voigt profile and suggests a lifetime broadening of 55 ± 15 meV. This is, however, insufficient for a peak separation from the mode at 40 meV. We further note that the experimental spectrum was taken on a cyano

Band tail state related photoluminescence and photoresponse of ZnMgO solid solution nanostructured films

• Vadim Morari,
• Aida Pantazi,
• Nicolai Curmei,
• Vitalie Postolache,
• Emil V. Rusu,
• Marius Enachescu,
• Ion M. Tiginyanu and
• Veaceslav V. Ursaki

Beilstein J. Nanotechnol. 2020, 11, 899–910, doi:10.3762/bjnano.11.75

• embedded into the ZnMgO alloy matrix, which is responsible for the high energy broad PL band. To demonstrate that the low energy PL band is related to ZnO crystallites, it is compared to the spectrum of a high quality ZnO crystal measured at low temperature (curve 4 in Figure 5b). One can see that the

Epitaxial growth and superconducting properties of thin-film PdFe/VN and VN/PdFe bilayers on MgO(001) substrates

• Wael M. Mohammed,
• Igor V. Yanilkin,
• Amir I. Gumarov,
• Airat G. Kiiamov,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2020, 11, 807–813, doi:10.3762/bjnano.11.65

• composition were controlled by X-ray photoelectron spectroscopy. In situ low-energy electron diffraction and ex situ X-ray diffraction show that the 30 nm thick single-layer VN as well as the double-layer VN(30 nm)/Pd0.92Fe0.08(12 nm) and Pd0.96Fe0.04(20 nm)/VN(30 nm) structures have grown cube-on-cube

• −xFex were taken at each deposition step using low-energy electron diffraction (LEED) and X-ray photoelectron spectroscopy (XPS). Finally, all structures were capped with 10 nm layer of undoped Si by magnetron sputtering to prevent sample deterioration. Thus, a VN film and stacks of Pd0.96Fe0.04/VN and

Light–matter interactions in two-dimensional layered WSe₂ for gauging evolution of phonon dynamics

• Avra S. Bandyopadhyay,
• Chandan Biswas and
• Anupama B. Kaul

Beilstein J. Nanotechnol. 2020, 11, 782–797, doi:10.3762/bjnano.11.63

• , calculated from the slope of the low-energy edge of the excitonic mode of the PL spectra. The theory of spectral line shape in the Raman spectrum predicts a Lorentzian distribution of a collected signal in a dispersive medium, where the full-width-half-maximum (FWHM) scales as 1/τ, and not surprisingly, τ is

• for the so-called Urbach formulism. Ramos and Luzzi [49] used this Urbach formulism to explain the behavior displayed in the radiation emission band of semiconductors at high-excitation levels, and the slope of the low-energy edge of the spectrum was characterized with an empirical parameter E0 on a

• , from this low-energy edge due to excitons [51] and using Urbach formulism, the slope of the low-energy edge of the excitonic A-peak (Figure 2e) is calculated by the following Equation 5 [49], where I(ω) is the intensity, and E0 is in units of meV and is the so-called characteristic energy parameter [50

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• complexes, it is shown they are low-energy formation defects in h-BN. This suggests that the assignment is presently controversial also considering the successive verification of SPEs as discussed in the following. In [45] h-BN exfoliated flakes, monolayer chemical vapor deposition (CVD) and in-house h-BN

Atomic-resolution imaging of rutile TiO₂(110)-(1 × 2) reconstructed surface by non-contact atomic force microscopy

• Daiki Katsube,
• Shoki Ojima,
• Eiichi Inami and
• Masayuki Abe

Beilstein J. Nanotechnol. 2020, 11, 443–449, doi:10.3762/bjnano.11.35

• , because it cannot be clarified whether the (1 × 2) structure is formed over a wide area or only locally using macroscopic analysis methods such as diffraction. We used non-contact atomic force microscopy, scanning tunneling microscopy, and low-energy electron diffraction at room temperature to

• clean surface is relatively easy. A well-known rutile TiO2(110) surface is the (1 × 1) structure [2]. The (1 × 1) surface has been studied using low-energy electron diffraction (LEED) [3][4], surface X-ray diffraction [5], non-contact atomic force microscopy (NC-AFM) [6][7][8][9], scanning tunneling

Formation of nanoripples on ZnO flat substrates and nanorods by gas cluster ion bombardment

• Xiaomei Zeng,
• Vasiliy Pelenovich,
• Bin Xing,
• Rakhim Rakhimov,
• Wenbin Zuo,
• Alexander Tolstogouzov,
• Chuansheng Liu,
• Dejun Fu and
• Xiangheng Xiao

Beilstein J. Nanotechnol. 2020, 11, 383–390, doi:10.3762/bjnano.11.29

• and ion fluence are qualitatively the same as those of the flat targets. The obtained result can be compared with a study by Ghoniem et al. on the sputtering of Re and W nanorods with low-energy argon ions in which the authors have found the formation of rather weak ripple structures on the stem side

• direction of the wave vector k of the ripples is not parallel to the nanorod axis. Hence, it can be concluded that in the case of low energy and fluence the ripple formation is controlled by the orientation of the ion incidence projection on the facet surface under irradiation, analogously to the flat

• becomes impossible from this point of view. In our experiment we also use binary materials and a defect-free ripple formation is observed, but only for nanorods. However, here, the scenario described in [10] seems unlikely due to a very low energy per atom in the cluster (a few electronvolts) and a

Nonequilibrium Kondo effect in a graphene-coupled quantum dot in the presence of a magnetic field

• Levente Máthé and
• Ioan Grosu

Beilstein J. Nanotechnol. 2020, 11, 225–239, doi:10.3762/bjnano.11.17

• [52]. The points where the conduction and valence bands touch each other in momentum space are the Dirac points. The Dirac points play an important role in the electronic properties of graphene because around these points low-energy excitations can be achieved. Furthermore, the motion of the charge

Phase inversion-based nanoemulsions of medium chain triglyceride as potential drug delivery system for parenteral applications

• Eike Folker Busmann,
• Dailén García Martínez,
• Henrike Lucas and
• Karsten Mäder

Beilstein J. Nanotechnol. 2020, 11, 213–224, doi:10.3762/bjnano.11.16

• as the flexibility of the nanoparticles [6][7][8][9]. Shock dilution with ice-cold water during phase inversion of the emulsion gives the opportunity to produce nanocapsules without the use of any potentially toxic organic solvent at low energy cost [10][11]. The choice and the amount of the

Nanosecond resistive switching in Ag/AgI/PtIr nanojunctions

• Botond Sánta,
• Dániel Molnár,
• Patrick Haiber,
• Agnes Gubicza,
• Edit Szilágyi,
• Zsolt Zolnai,
• András Halbritter and
• Miklós Csontos

Beilstein J. Nanotechnol. 2020, 11, 92–100, doi:10.3762/bjnano.11.9

• distances granting metallic conductance also in this ultimate scaling limit. (iii) The device conductance is largely determined by the rearrangement of only a few atoms in this narrowest cross section, which can take place at a very large bandwidth and unprecedentedly low energy cost [5][6][7][8][9

Synthesis of amorphous and graphitized porous nitrogen-doped carbon spheres as oxygen reduction reaction catalysts

• Maximilian Wassner,
• Markus Eckardt,
• Andreas Reyer,
• Thomas Diemant,
• Michael S. Elsaesser,
• R. Jürgen Behm and
• Nicola Hüsing

Beilstein J. Nanotechnol. 2020, 11, 1–15, doi:10.3762/bjnano.11.1

• support to the C 1s signal of the carbon-containing catalyst film. The spectra showed minor charging effects, which were compensated by a neutralizer (low-energy electron flood gun). The C 1s peak was set to 284.8 eV for binding energy calibration [50]. Evaluation and deconvolution of the measured signals

Ultrathin Ni_1−xCo_xS₂ nanoflakes as high energy density electrode materials for asymmetric supercapacitors

• Xiaoxiang Wang,
• Teng Wang,
• Rusen Zhou,
• Lijuan Fan,
• Shengli Zhang,
• Feng Yu,
• Tuquabo Tesfamichael,
• Liwei Su and
• Hongxia Wang

Beilstein J. Nanotechnol. 2019, 10, 2207–2216, doi:10.3762/bjnano.10.213

• ]. Currently, carbon-based electrical double-layer capacitors (EDLCs) are commercially available, but they exhibit only a low energy density because of physical charge storage processes due to the adsorption/desorption of ions at the electrode–electrolyte interfaces [3]. These drawbacks have hindered further

Improvement of the thermoelectric properties of a MoO₃ monolayer through oxygen vacancies

• Wenwen Zheng,
• Wei Cao,
• Ziyu Wang,
• Huixiong Deng,
• Jing Shi and
• Rui Xiong

Beilstein J. Nanotechnol. 2019, 10, 2031–2038, doi:10.3762/bjnano.10.199

• of utilizing waste heat without generating any greenhouse gas, thermoelectric technology has attracted increasing attention [1]. Nevertheless, the application of thermoelectric materials is limited by the low energy conversion efficiency. The performance of thermoelectric materials is usually

Facile synthesis of carbon nanotube-supported NiO//Fe₂O₃ for all-solid-state supercapacitors

• Shengming Zhang,
• Xuhui Wang,
• Yan Li,
• Xuemei Mu,
• Yaxiong Zhang,
• Jingwei Du,
• Guo Liu,
• Xiaohui Hua,
• Yingzhuo Sheng,
• Erqing Xie and
• Zhenxing Zhang

Beilstein J. Nanotechnol. 2019, 10, 1923–1932, doi:10.3762/bjnano.10.188

• supercapacitors. Keywords: aqueous reduction; carbon nanotubes; iron oxide; nickel oxide; supercapacitors; Introduction Supercapacitors offer long cycling life, superior charge–recharge ability, high power density, and wide operating temperature [1][2][3]. However, the low energy density limits their

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

• Manuel Souto,
• Joaquín Calbo,
• Samuel Mañas-Valero,
• Aron Walsh and
• Guillermo Mínguez Espallargas

Beilstein J. Nanotechnol. 2019, 10, 1883–1893, doi:10.3762/bjnano.10.183

• ) nicely agrees with the low-energy broad band that appears in the experimental absorption spectrum of C60@MUV-2, centred at 550 nm and expanding up to 800 nm. In fact, theoretical calculations indicate that the intensity and energy of the S1 CT transition in C60@TTFTB is significantly affected by the

Tuning the performance of vanadium redox flow batteries by modifying the structural defects of the carbon felt electrode

• Ditty Dixon,
• Deepu Joseph Babu,
• Aiswarya Bhaskar,
• Hans-Michael Bruns,
• Joerg J. Schneider,
• Frieder Scheiba and
• Helmut Ehrenberg

Beilstein J. Nanotechnol. 2019, 10, 1698–1706, doi:10.3762/bjnano.10.165

• samples were analyzed using a focused (30–400 µm spot size), monochromatic Al Kα X-ray source. The Kα charge compensation system was employed during the experiment, using electrons of 8 eV energy and low-energy argon ions to prevent any localized charge build-up. The spectra were fitted with one or more

Kelvin probe force microscopy work function characterization of transition metal oxide crystals under ongoing reduction and oxidation

• Dominik Wrana,
• Karol Cieślik,
• Wojciech Belza,
• Christian Rodenbücher,
• Krzysztof Szot and
• Franciszek Krok

Beilstein J. Nanotechnol. 2019, 10, 1596–1607, doi:10.3762/bjnano.10.155

• the present case of thermally reduced SrTiO3(100), the dominant reconstruction is (√5×√5)R26.6°, which forms on the TiO2 termination, as proved by the scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) investigations (see Figure 5g,h). The surface is composed of two

Kelvin probe force microscopy of the nanoscale electrical surface potential barrier of metal/semiconductor interfaces in ambient atmosphere

• Petr Knotek,
• Tomáš Plecháček,
• Jan Smolík,
• Petr Kutálek,
• Filip Dvořák,
• Milan Vlček,
• Jiří Navrátil and
• Čestmír Drašar

Beilstein J. Nanotechnol. 2019, 10, 1401–1411, doi:10.3762/bjnano.10.138

• filtering effect [15][16][17]. The potential energy barrier connected with a metallic NP (Schottky barrier) or a multi-phase interface could scatter low-energy electrons more effectively than high-energy electrons [18]. This, in turn, results in an enhancement of the Seebeck coefficient with virtually no