ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• used, for example, in water purification, as electrochemical actuators, as transparent conductive electrodes, and as biosensors [21][22][28]. To enhance the performance of MXene supercapacitors, a variety of materials, such as graphene and carbon nanotubes (CNTs), tin(IV) oxide (SnO2), and iron(III

Free and partially encapsulated manganese ferrite nanoparticles in multiwall carbon nanotubes

• Saja Al-Khabouri,
• Salim Al-Harthi,
• Toru Maekawa,
• Mohamed E. Elzain,
• Ashraf Al-Hinai,
• Ahmed D. Al-Rawas,
• Abbsher M. Gismelseed,
• Ali A. Yousif and
• Myo Tay Zar Myint

Beilstein J. Nanotechnol. 2020, 11, 1891–1904, doi:10.3762/bjnano.11.170

• manganese ferrite nanoparticles inside the tubes is observed as a shift in the X-ray diffraction peaks and as an increase in stress, hyperfine field, and coercivity when compared to free manganese ferrite nanoparticles. On the other hand, a strong charge transfer from the multiwall carbon nanotubes is

• ferrite nanoparticles in comparison to free manganese ferrite nanoparticles, which leads to an enhancement of the metallic properties. Keywords: carbon nanotubes; charge transfer; manganese ferrite; metallic nanoparticles; partial encapsulation; stress; surface; Introduction Since the discovery of

• carbon nanotubes (CNTs), researchers have been interested in functionalizing, inserting, and encapsulating materials inside their inner cavities. Processes related to functionalizing and inserting nanomaterials (i.e., directly implanting as-synthesized nanomaterials into CNTs) have been widely reported

Kondo effects in small-bandgap carbon nanotube quantum dots

• Patryk Florków,
• Damian Krychowski and
• Stanisław Lipiński

Beilstein J. Nanotechnol. 2020, 11, 1873–1890, doi:10.3762/bjnano.11.169

• close to perpendicular. When the field approaches a transverse orientation a crossover from SU(2) or SU(3) symmetry into SU(4) is observed. Keywords: carbon nanotubes; Kondo effect; mesoscopic transport; quantum dots; valleytronics; Introduction Due to their remarkable electronic, transport

• , mechanical, and magnetic properties carbon nanotubes (CNTs) are of great interest in molecular electronics and spintronics with potential applications, for example, as field-effect transistors, nanoelectromechanical devices, logic gates, spin valves, spin diodes, and spin batteries [1][2][3][4][5][6][7][8][9

• ][10][11]. CNTs are also interesting for fundamental science. Their study allows for the examination of many basic properties in ranges often not reachable in other systems. Many of the fundamental transport properties were observed in nanotubes, including Coulomb blockade [12][13], Fabry–Perot

Towards 3D self-assembled rolled multiwall carbon nanotube structures by spontaneous peel off

• Jonathan Quinson

Beilstein J. Nanotechnol. 2020, 11, 1865–1872, doi:10.3762/bjnano.11.168

• ; multiwall carbon nanotubes; nitrogen doping; peel off; rolled carbon nanotubes; Introduction Carbon nanotubes (CNTs) are popular materials used in various applications [1]. These tubular hollow carbon nanomaterials have proven to be useful in multiple scientific fields [2][3][4][5][6]. Complex structures

Nanomechanics of few-layer materials: do individual layers slide upon folding?

• Ronaldo J. C. Batista,
• Rafael F. Dias,
• Ana P. M. Barboza,
• Alan B. de Oliveira,
• Taise M. Manhabosco,
• Thiago R. Gomes-Silva,
• Matheus J. S. Matos,
• Andreij C. Gadelha,
• Cassiano Rabelo,
• Luiz G. L. Cançado,
• Ado Jorio,
• Hélio Chacham and
• Bernardo R. A. Neves

Beilstein J. Nanotechnol. 2020, 11, 1801–1808, doi:10.3762/bjnano.11.162

• carbon nanotubes [13][14]. The interlayer slip is also intimately related to the dependence of κ on the thickness or the number of layers of a 2D material, which, in the case of very thin 2D materials, may be very different from that obtained from classical theories [12]. The quantification and

PEG/PEI-functionalized single-walled carbon nanotubes as delivery carriers for doxorubicin: synthesis, characterization, and in vitro evaluation

• Shuoye Yang,
• Zhenwei Wang,
• Yahong Ping,
• Yuying Miao,
• Yongmei Xiao,
• Lingbo Qu,
• Lu Zhang,
• Yuansen Hu and
• Jinshui Wang

Beilstein J. Nanotechnol. 2020, 11, 1728–1741, doi:10.3762/bjnano.11.155

• of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China 10.3762/bjnano.11.155 Abstract Single-walled carbon nanotubes (SWCNTs) have attracted great interest regarding drug-delivery applications. However, their application has been limited by some inherent disadvantages

• drugs. Keywords: antitumor activity; cellular uptake; PEG functionalization; PEI functionalization; poly(ethylene glycol) (PEG); polyethylenimine (PEI); single-walled carbon nanotubes; Introduction To date, chemotherapy is the most common therapy for cancer treatment. However, the inability of

• the distribution in normal tissues, and to improve the biological half-lives [3][4][5][6]. Carbon nanotubes (CNTs) have attracted great interest for biomedical applications, including the delivery of bioactive molecules such as drugs, the targeted cancer therapy, and biological imaging, because of

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• , Lopez de Dicastillo et al. (2018, 2019) have recently developed hollow titanium dioxide nanotubes and nanospheres through the deposition of tetrakis(dimethylamide) titanium and water, as precursors, on polymeric structures obtained via electrospinning. The resulting hollow nanotubes and nanospheres had

• thickness values of approximately 20 and 17 nm, respectively [38][39]. ALD has been recognized as a key technique used to deposit thin films on structures with complex geometries, allowing for the synthesis of nanostructures without shadowing effects and with a high aspect ratio, such as nanotubes with

• NPs has been directed towards water disinfection, food packaging in addition to their known use as a UV filter to prevent skin cancer [114]. Lopez de Dicastillo et al. (2019) developed hollow TiO2 nanotubes and nanospheres with high antimicrobial activity through the combination of electrospinning and

Structure and electrochemical performance of electrospun-ordered porous carbon/graphene composite nanofibers

• Yi Wang,
• Yanhua Song,
• Chengwei Ye and
• Lan Xu

Beilstein J. Nanotechnol. 2020, 11, 1280–1290, doi:10.3762/bjnano.11.112

• devices [1][2], are one of the most needed energy storage devices. Their main characteristics include high energy density, high power density, and fast charging speed [3][4][5]. These instruments have electrodes that are composed of either carbonaceous materials (carbon nanotubes, graphene, carbon

Ultrasensitive detection of cadmium ions using a microcantilever-based piezoresistive sensor for groundwater

• Dinesh Rotake,
• Anand Darji and
• Nitin Kale

Beilstein J. Nanotechnol. 2020, 11, 1242–1253, doi:10.3762/bjnano.11.108

• based on nanotubes, nanorods, nanoneedles, or nanoplates are also used to detect HMIs selectively down to the nanomolar range [8][9][10][11]. Many authors used adsorption methods to extract heavy metal ions from groundwater [12][13][14][15][16]. However, this is only useful when a pollution source has

3D superconducting hollow nanowires with tailored diameters grown by focused He⁺ beam direct writing

• Rosa Córdoba,
• Alfonso Ibarra,
• Dominique Mailly,
• Isabel Guillamón,
• Hermann Suderow and
• José María De Teresa

Beilstein J. Nanotechnol. 2020, 11, 1198–1206, doi:10.3762/bjnano.11.104

• nanotubes as small as 32 nm in diameter [17] and nanohelices with controllable geometries, including the smallest and most densely packed nanohelix to date with a diameter of 100 nm [19]. In this work, we present the direct writing of 3D WC crystalline superconducting hollow NWs with tailored diameters

• penetration depth, λ, [38][39] ranges from 720 to 874 nm. Additionally, Jc (0.6 K, 0 T) is approx. 0.15 MA/cm2. Summarizing, the estimated superconducting parameters (Tc, µ0Hc2, Jc, ξ, λ) for these NWs (Table 2) are mostly compatible with those reported for He+ FIBID out-of-plane WC nanotubes [17

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

• Mykola Borzenkov,
• Piersandro Pallavicini,
• Angelo Taglietti,
• Laura D’Alfonso,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

• photothermal effect under NIR laser irradiation. Carbon nanotubes are another valuable class of nanomaterials. They have high photothermal efficiency under NIR irradiation which excites the longitudinal phonon resonance along the nanotube. The resonance peaks can be tuned by changing the tube length [86

• ]. Therefore, carbon nanotubes also have potential to be used in the NIR-triggered photothermal bacterial treatment. It was shown that multiwall carbon nanotubes functionalized with antibodies against the group A Streptococcus bacteria were capable of photothermally ablating the planktonic and biofilm-residing

• bacteria upon 800 nm laser exposure (1.3 W/cm2) for 10–120 s [87]. The authors also found that, upon NIR irradiation, the antibody-labelled nanotubes displayed an enhanced antibacterial action on both planktonic cells and biofilms when compared to carboxylated multiwall carbon nanotubes. The use of carbon

Vibration analysis and pull-in instability behavior in a multiwalled piezoelectric nanosensor with fluid flow conveyance

• Sayyid H. Hashemi Kachapi

Beilstein J. Nanotechnol. 2020, 11, 1072–1081, doi:10.3762/bjnano.11.92

• result, MWNS materials are preferred in many applications such as nanoresonators. Many studies have been carried out on the vibration and stability analysis of nanostructures with some reviews given as follows. Strozzi and Pellicano investigated the vibration analysis of triple-walled carbon nanotubes

• (TWNTs) subjected to the interlayer van der Waals (vdW) force in the framework of the Sanders–Koiter shell theory [12]. Also, based on nonlocal cylindrical shell theory, Ghorbanpour Arani et al. studied nonlinear vibration and instability of double-walled boron nitride nanotubes [13]. Malihi et al

• stress theory to investigate the effects of various fluid parameters on the pull-in voltage of carbon nanotubes conveying viscous fluid [15]. Also, the vibration analysis of viscoelastic double-walled carbon nanotubes (DWCNTs) combined with ZnO layers and subjected to magnetic and electric fields were

Microwave-induced electric discharges on metal particles for the synthesis of inorganic nanomaterials under solvent-free conditions

• Vijay Tripathi,
• Harit Kumar,
• Anubhav Agarwal and
• Leela S. Panchakarla

Beilstein J. Nanotechnol. 2020, 11, 1019–1025, doi:10.3762/bjnano.11.86

• . The average diameter of the nanorods is 100 nm and the length ranges from 2 to 3 µm. The formation of external amorphous fluorinated carbon nanotubes helps as a template in the formation of ZnF2 nanorods. It is well established that sulfur acts as a growth promoter for carbon nanotubes and carbon

• mixture along with g-C3N4, sulfur helps to produce carbon nanotubes instead of carbon nanospheres. The reactivity of sulfur with the end caps of nanotubes does not allow the carbon nanotubes to close. These amorphous carbon nanotubes help as a template to intercalate metal fluorides/metal sulfides. As the

• local temperatures are very high, metal fluorides and sulfides melt and fill the nanotubes via capillary forces. The liquids solidify as one-dimensional nanorods inside the nanotubes. The usage of g-C3N4, instead of graphite, was found to be beneficial, especially for obtaining high yields of nanorods

Gas-sensing features of nanostructured tellurium thin films

• Dumitru Tsiulyanu

Beilstein J. Nanotechnol. 2020, 11, 1010–1018, doi:10.3762/bjnano.11.85

• grow Te nanoflakes. In order to synthesize Te nanowires, Liang and collaborators [13] performed chemical reactions of Na2TeO3, in aqueous solution, via hydrothermal treatment, whereas Ma and colleagues [14] used a solvothermal approach on glass substrates. To synthesize Te nanotubes, techniques such as

• sensing parameters did not differ much from the similar parameters obtained earlier for microcrystalline Te films. Further investigations have been extended to Te nanotubes grown on quartz or Si(111) substrates through a catalyst-free growing process in a furnace filled with argon [21]. Another study used

• the high-vacuum deposition technique in order to grow Te nanotubes on silicon substrates containing previously deposited nanoparticles of silver or gold [22]. In both cases, 50 nm diameter Te nanotubes were obtained. When exposed to low concentrations of different toxic gases, including NO2, the Te

Wet-spinning of magneto-responsive helical chitosan microfibers

• Dorothea Brüggemann,
• Johanna Michel,
• Naiana Suter,
• Matheus Grande de Aguiar and
• Michael Maas

Beilstein J. Nanotechnol. 2020, 11, 991–999, doi:10.3762/bjnano.11.83

• organic templates are examples of alternative ways to synthesize helical nano- or microfibers from various materials like carbon nanotubes (CNTs), ZnO or different polymers [8][48][49]. Here, we present a simple method for synthesizing helical chitosan microfibers with embedded magnetic nanoparticles

Electrochemical nanostructuring of (111) oriented GaAs crystals: from porous structures to nanowires

• Elena I. Monaico,
• Eduard V. Monaico,
• Veaceslav V. Ursaki,
• Shashank Honnali,
• Vitalie Postolache,
• Karin Leistner,
• Kornelius Nielsch and
• Ion M. Tiginyanu

Beilstein J. Nanotechnol. 2020, 11, 966–975, doi:10.3762/bjnano.11.81

• electrochemically filling the pores with metallic nanostructures such as nanowires or nanotubes, resulting in the production of 2D metallo-semiconductor interpenetrating networks, which are promising for various nanoelectronic, optoelectronic, plasmonic, and nanophotonic applications [4][5][6]. While the growth of

Nickel nanoparticles supported on a covalent triazine framework as electrocatalyst for oxygen evolution reaction and oxygen reduction reactions

• Secil Öztürk,
• Yu-Xuan Xiao,
• Dennis Dietrich,
• Beatriz Giesen,
• Juri Barthel,
• Jie Ying,
• Xiao-Yu Yang and
• Christoph Janiak

Beilstein J. Nanotechnol. 2020, 11, 770–781, doi:10.3762/bjnano.11.62

• ][11][12][13]. The performance of the nickel catalysts could be further enhanced via modifications, such as the usage of carbon supports including N-doped graphene [14], active carbon [15], graphene oxide [16][17], carbon nanotubes [12][18] and covalent triazine frameworks (CTFs) [19][20]. CTFs are

• layers (25.2 wt %), Ni encapsulated within single-layer graphene (32.8 wt %), but higher than that of nickel nanoparticles encapsulated in N-doped carbon nanotubes (14.5 wt %), and much lower than those of with N-doped carbon shells coated face-centered cubic (fcc) or hexagonal closed packed (hcp) nickel

• formation of pyridinic N and graphitic or quaternary N have been demonstrated to improve the activity of N-modified carbon-based materials such as N-doped ordered porous carbon and N-doped carbon nanotubes [49][50]. According to our evaluation of the XPS data, 8 atom % N is involved in bonding to Ni for Ni

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

• in h-BN [115]. Nanotubes and nanococoons Another class of 1D and 0D h-BN nanomaterials, such as nanotubes (BNNTs) and nanococoons, were found to exhibit SPE. BNNT can be associated with 2D h-BN hexagonal sheets rolled into a closed nanotube structure, making them a type of 1D material up to 200 µm

Effect of Ag loading position on the photocatalytic performance of TiO₂ nanocolumn arrays

• Jinghan Xu,
• Yanqi Liu and
• Yan Zhao

Beilstein J. Nanotechnol. 2020, 11, 717–728, doi:10.3762/bjnano.11.59

• , and Ag particles were loaded on the inside and the outside of the nanotubes by chemical deposition. The catalysis of this composite was carried out at a concentration of 1100 mM in AgNO3 solution. It was found that the loading position of precious metal particles in the TiO2 structure could not be

A novel dry-blending method to reduce the coefficient of thermal expansion of polymer templates for OTFT electrodes

• Xiangdong Ye,
• Bo Tian,
• Yuxuan Guo,
• Fan Fan and
• Anjiang Cai

Beilstein J. Nanotechnol. 2020, 11, 671–677, doi:10.3762/bjnano.11.53

• in a polymer to obtain a composite. Shokrieh et al. [10] carried out a systematic theoretical study to investigate the influence of carbon nanotubes (CNTs) on the CTE of CNT/epoxy, and the results indicate that the addition of 1 wt % CNT causes a significant decrease of the CTE of the matrix

Adsorptive removal of bulky dye molecules from water with mesoporous polyaniline-derived carbon

• Hyung Jun An,
• Jong Min Park,
• Nazmul Abedin Khan and
• Sung Hwa Jhung

Beilstein J. Nanotechnol. 2020, 11, 597–605, doi:10.3762/bjnano.11.47

• regarded to be very effective and attractive because of its operation under mild conditions and no need of oxidant, active catalyst, and irradiation [8][9]. Therefore, adsorption with carbon nanotubes, activated carbon (AC), biomass, and metallic–organic frameworks (MOFs) has been actively studied for the

• because of functional carbon materials (graphene [16] or porous carbon [17]), mesoporous materials [18] and MOFs [19][20][21][22]. For example, MOFs [23][24][25], carbonaceous materials (such as carbon nanotubes, graphene, biochar and activated carbon) [26] and clay [27] have been applied in adsorptive

Identification of physicochemical properties that modulate nanoparticle aggregation in blood

• Ludovica Soddu,
• Duong N. Trinh,
• Eimear Dunne,
• Dermot Kenny,
• Giorgia Bernardini,
• Ida Kokalari,
• Arianna Marucco,
• Marco P. Monopoli and
• Ivana Fenoglio

Beilstein J. Nanotechnol. 2020, 11, 550–567, doi:10.3762/bjnano.11.44

• (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) can induce platelet activation by inducing depletion of intracellular Ca2+ [10][11], an effect that was hypothesised to be caused by the interaction of CNTs with plasma and dense tubular system membranes likely related to the fibrous shape [12]. On the

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

• Varsha Sharma and
• Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

• in the shell are also used to carry out the release of the encapsulated payload in a controlled manner. The incorporation of functionalities such as organic molecules, NPs, fluorescent dyes, polymers, nanotubes and other biomolecules into the PE multilayers during the fabrication makes it easy to

• mechanical properties, carbon-based materials were also reported for the functionalization of hollow capsules. When the microcapsules were embedded with carbon nanotubes (CNTs) in the shell, the rigidity of the shell was improved upon drying and resulted in freestanding structures. The capsules modified with

Evolution of Ag nanostructures created from thin films: UV–vis absorption and its theoretical predictions

• Robert Kozioł,
• Marcin Łapiński,
• Paweł Syty,
• Damian Koszelow,
• Wojciech Sadowski,
• Józef E. Sienkiewicz and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2020, 11, 494–507, doi:10.3762/bjnano.11.40

• be observed, corresponding to the illumination in a direction parallel or perpendicular to its major axis [23]. In recent years, many scientific papers have also been devoted to triangular or tetrahedral nanoparticles, or nanorods/nanotubes with complex cross sections [23][24][25]. Plasmon resonance

Nanoarchitectonics: bottom-up creation of functional materials and systems

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2020, 11, 450–452, doi:10.3762/bjnano.11.36

• spectroscopy [37], bio-nanocomposites with clay nanoarchitectures for electrochemical devices [38], a biomimetic nanofluidic diode with polymeric carbon nitride nanotubes [39], and a unique Janus-micromotor applied as a luminescence sensor for sensitive TNT detection [40]. The variety of nanoarchitectonics