Beilstein J. Nanotechnol.2010,1, 14–20, doi:10.3762/bjnano.1.3
crystallization temperatures, homogenous nucleation and fast supersaturation by rapid dissolution [22][23][24][25][26][27]. In this work a study is conducted on the improvement of visible light photocatalyticdegradation of a model organic dye, methylene blue, with ZnO nanorods grown by a rapid growth process
(3 cm2). The photocatalyticdegradation of MB could be fitted using Equation 2 and the apparent rate constants (k = ab) were calculated from the linear curves using Equation 3:
The nanoparticle film demonstrated minimum photocatalytic activity as expected owing to lower surface (SA ≈ 6 cm2) exposed
. Comparative results of photocatalyticdegradation studies on methylene blue with visible light irradiation demonstrated that ZnO nanorods are 12–24% more active than nanoparticulate films. An enhancement of 8% in the photocatalytic activity of ZnO nanorods was achieved through engineered creation of oxygen
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Figure 1:
(a) Low-resolution TEM micrograph of ZnO nanoparticles, (b) electron diffraction pattern of the ZnO...