The influence of an interfacial hBN layer on the fluorescence of an organic molecule

• Christine Brülke,
• Oliver Bauer and
• Moritz M. Sokolowski

Beilstein J. Nanotechnol. 2020, 11, 1663–1684, doi:10.3762/bjnano.11.149

• additional enhancement [46]. According to the electromagnetic mechanism, on a rough surface, surface plasmon polaritons (SPPs) can also be excited by the incident light. The surface plasmons are located in the vicinity of surface defects, such as protrusions. The field enhancement at these defects leads to

Optically and electrically driven nanoantennas

• Monika Fleischer,
• Dai Zhang and
• Alfred J. Meixner

Beilstein J. Nanotechnol. 2020, 11, 1542–1545, doi:10.3762/bjnano.11.136

• integration, device-to-device communication, and bilateral transduction between electrons and photons [26]. An optical gap antenna typically consists of two nanostructures with a nanometer gap in between. Optical excitation induces a coupled plasmon oscillation along the two antenna parts, which can lead to

• low-background medical imaging or nanolasers [33]. Electrically driven optical antennas emit light when a bias voltage is applied to the contacted antenna arms that are forming a tunnel junction. Inelastic electron tunneling through the gap excites gap–plasmon oscillations leading to the emission of

• photons as a consequence of radiative plasmon relaxation [34][35][36]. The relaxation depends on how the gap modes couple and can hence be controlled by the design of the antenna. The combination of an electrically driven antenna with optical excitation is a very promising but not yet well explored

Superconductor–insulator transition in capacitively coupled superconducting nanowires

• Alex Latyshev,
• Andrew G. Semenov and
• Andrei D. Zaikin

Beilstein J. Nanotechnol. 2020, 11, 1402–1408, doi:10.3762/bjnano.11.124

• function at coincident points which reads where and is the velocity matrix for plasmon modes propagating along the wires. The matrix has the form where is the velocity of the Mooij–Schön modes in the ith wire in the absence of capacitive coupling between the wires, i.e. for Cm → 0. Following the

• fluctuations in one of these wires effectively decrease the superconducting properties of the other one. It follows from Equation 17 that the magnitude of such mutual influence depends on the ratio of the plasmon velocities in the two wires v1/v2 and on the strength of the capacitive coupling controlled by Cm

• . Provided the wire cross sections s1 and s2 differ strongly the plasmon velocities also differ considerably. Assume, for instance, that the first wire is much thinner than the second one. In this limit we have v1 ≪ v2 and, hence, the QPT condition (Equation 17) in the first wire remains almost unaffected

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

• Mykola Borzenkov,
• Piersandro Pallavicini,
• Angelo Taglietti,
• Laura D’Alfonso,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

• gold nanoparticle aggregation was implemented [54]. According to this strategy, the spherical nanoparticles, with a typical localized surface plasmon resonance (LSPR) absorption at 520 nm, aggregated in situ at the surface of the bacterial membrane. The gold nanoparticle aggregation induced a change in

Straightforward synthesis of gold nanoparticles by adding water to an engineered small dendrimer

• Sébastien Gottis,
• Régis Laurent,
• Vincent Collière and
• Anne-Marie Caminade

Beilstein J. Nanotechnol. 2020, 11, 1110–1118, doi:10.3762/bjnano.11.95

• gold nanoparticles since this color corresponds to the surface plasmon resonance wavelength. This is a well-known phenomenon observed in gold nanoparticles [56]. Considering that the gold nanoparticles are spherical, the maximum intensity of the visible spectrum at 545 nm should correspond to a mean

• size of ≈50 nm for the gold nanoparticles [57][58]. The shoulder detected at ≈630 nm corresponds to the longitudinal surface plasmon resonance, and it is characteristic of the presence of non-spherical gold NPs, in particular rod-like or triangular NPs [59][60]. The presence of this shoulder shifted

Highly sensitive detection of estradiol by a SERS sensor based on TiO₂ covered with gold nanoparticles

• Andrea Brognara,
• Ili F. Mohamad Ali Nasri,
• Beatrice R. Bricchi,
• Andrea Li Bassi,
• Caroline Gauchotte-Lindsay,
• Matteo Ghidelli and
• Nathalie Lidgi-Guigui

Beilstein J. Nanotechnol. 2020, 11, 1026–1035, doi:10.3762/bjnano.11.87

• water. SERS is mainly based on an electromagnetic effect that originates from the excitation of plasmon resonances, in particular of localized surface plasmons (LSPs) in metallic nanoparticles (NPs). Other effects may contribute to the enhancement such as the formation of hot spots or lightning rod

• µM, 100 µM, and 1 mM. Samples were left in the E2 solutions for 1 h before being rinsed with RO water and blown dry. Figure 1 gives a schematic of the final system. Optical and SERS measurements Plasmon resonance was evaluated via optical spectroscopy. For this purpose, transmission spectra were

• nm) and the Raman wavelength of the peak in consideration [5][39]. As shown in Figure 4 the plasmon resonances for all the samples were outside of this interval. The plasmonic properties of the NPs probably contribute to the enhancement of the Raman scattering. However, it also originates from the

Key for crossing the BBB with nanoparticles: the rational design

• Sonia M. Lombardo,
• Marc Schneider,
• Akif E. Türeli and
• Nazende Günday Türeli

Beilstein J. Nanotechnol. 2020, 11, 866–883, doi:10.3762/bjnano.11.72

• targeting ligands, such as angiopep-2, TAT or EGF, allows their accumulation to be increased in these specific areas [70][78][107][176]. Although to a lower extent, gold nanorods (AuNRs) have also been used for brain delivery. AuNRs, like AuNPs, exhibit an optical feature called surface plasmon resonance

• optical window. Light in this wavelength range can penetrate more deeply into the human body thanks to the low absorption by tissue and blood, making these nanoparticles interesting for theranostic treatments [177][179][180]. By excitation of surface plasmon oscillations, local heating can be generated

Hexagonal boron nitride: a review of the emerging material platform for single-photon sources and the spin–photon interface

• Stefania Castelletto,
• Faraz A. Inam,
• Shin-ichiro Sato and
• Alberto Boretti

Beilstein J. Nanotechnol. 2020, 11, 740–769, doi:10.3762/bjnano.11.61

Effect of Ag loading position on the photocatalytic performance of TiO₂ nanocolumn arrays

• Jinghan Xu,
• Yanqi Liu and
• Yan Zhao

Beilstein J. Nanotechnol. 2020, 11, 717–728, doi:10.3762/bjnano.11.59

• efficiency of methylene blue (MB) compared with Ag-coated TiO2 (ACT) nanocolumn arrays and pure TiO2 nanocolumns arrays. Both experimental and theoretical simulation results demonstrated that the enhanced photocatalytic performance of AFT nanocolumn arrays was attributed to the surface plasmon resonance (SPR

• ) of Ag and the absorption of light by TiO2. These results represent a promising step forward to the development of high-performance photocatalysts for energy conversion and storage. Keywords: anodic aluminum oxide template; nanocolumn arrays; photocatalysis; surface plasmon resonance; Introduction

• surface active sites [11][12]. In addition, TiO2 combined with noble metal (e.g., Au, Ag, Pt), nanostructured to form a metal–oxide structure, has been shown to greatly improve the catalytic efficiency of the material [13]. When excited by light, noble metal nanoparticles can exhibit surface plasmon

Silver-decorated gel-shell nanobeads: physicochemical characterization and evaluation of antibacterial properties

• Marta Bartel,
• Katarzyna Markowska,
• Marcin Strawski,
• Krystyna Wolska and
• Maciej Mazur

Beilstein J. Nanotechnol. 2020, 11, 620–630, doi:10.3762/bjnano.11.49

• -resolution spectra for these elements. The direct evidence for metallic silver embedded in the polymer matrix is the spin–orbit doublet recorded at 368.3 and 374.3 eV for Ag 3d5/2 and 3d3/2, respectively (Figure 5A), followed by plasmon loss peaks at 372 and 378 eV [30][31]. However, the asymmetric shape of

Luminescent gold nanoclusters for bioimaging applications

• Nonappa

Beilstein J. Nanotechnol. 2020, 11, 533–546, doi:10.3762/bjnano.11.42

• single atom. Additionally, due to covalently bound ligands, the NCs show extraordinary stability under ambient conditions. While plasmonic AuNPs display size-dependent surface plasmon resonance (SPR), NCs display characteristic molecule-like electronic spectra. This is attributed to the small size and

• quantum confinement, and the evolution of continuous or quasicontinuous bands (of bulk gold) into discrete electronic states [40]. Another attractive property of AuNCs is photoluminescence (PL), a phenomenon that is much less understood than the surface plasmon resonance of plasmonic gold nanoparticles

Multilayer capsules made of weak polyelectrolytes: a review on the preparation, functionalization and applications in drug delivery

• Varsha Sharma and
• Anandhakumar Sundaramurthy

Beilstein J. Nanotechnol. 2020, 11, 508–532, doi:10.3762/bjnano.11.41

• charged silica NPs as well as the disulfide linkages between cysteine blocks and gold NPs resulted in two types of functionalities in the capsule. In a similar way, the capsules incorporated with noble metal NPs (e.g., gold and silver) respond to external light illumination by increased surface plasmon

Evolution of Ag nanostructures created from thin films: UV–vis absorption and its theoretical predictions

• Robert Kozioł,
• Marcin Łapiński,
• Paweł Syty,
• Damian Koszelow,
• Wojciech Sadowski,
• Józef E. Sienkiewicz and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2020, 11, 494–507, doi:10.3762/bjnano.11.40

• quality of the nanostructures, in terms of their use as plasmonic platforms, is reflected in the UV–vis absorption spectra. The absorption spectrum is dominated by a maximum in the range of 450–500 nm associated with the plasmon resonance. As the initial layer thickness increases, an additional peak

• : dewetting; finite-difference time-domain (FDTD) method; plasmon resonance; silver (Ag) nanostructures; thin films; UV–vis absorption; Introduction In the last decade there has been significant development in sensor-related research regarding the application in optical, medical or biological areas [1][2][3

• ][4][5]. The principle of some of these sensors is the resonant enhancement of a local electromagnetic field as well as a sharp spectral absorption, which can be achieved by exploiting localized surface plasmon resonance (LSPR). This phenomenon is based on collective oscillations of free electrons

Preparation and in vivo evaluation of glyco-gold nanoparticles carrying synthetic mycobacterial hexaarabinofuranoside

• Gennady L. Burygin,
• Polina I. Abronina,
• Nikita M. Podvalnyy,
• Sergey A. Staroverov,
• Leonid O. Kononov and
• Lev A. Dykman

Beilstein J. Nanotechnol. 2020, 11, 480–493, doi:10.3762/bjnano.11.39

• . Another advantage of using these GNPs is their strong light absorption due to localized surface plasmon resonance (LSPR) around 520 nm while colloids of GNPs smaller than 3 nm do not exhibit an LSPR and are barely colored. It is known that the color of GNP colloids dramatically depends on size and shape

Synthesis and enhanced photocatalytic performance of 0D/2D CuO/tourmaline composite photocatalysts

• Changqiang Yu,
• Min Wen,
• Zhen Tong,
• Shuhua Li,
• Yanhong Yin,
• Xianbin Liu,
• Yesheng Li,
• Tongxiang Liang,
• Ziping Wu and
• Dionysios D. Dionysiou

Beilstein J. Nanotechnol. 2020, 11, 407–416, doi:10.3762/bjnano.11.31

• spectra were collected to study the optical properties of the samples. As shown in Figure 5a, the CuO/tourmaline composite exhibited higher optical adsorption than that of pure CuO, due to the plasmon resonance of the tourmaline units [24]. The band gap of CuO and CuO/tourmaline composite was calculated

Using gold nanoparticles to detect single-nucleotide polymorphisms: toward liquid biopsy

• María Sanromán Iglesias and
• Marek Grzelczak

Beilstein J. Nanotechnol. 2020, 11, 263–284, doi:10.3762/bjnano.11.20

• giving rise to the so-called localized surface plasmon resonance (LSPR). The position and the bandwidth of the LSPR can be modulated by the shape of the nanocrystals and can vary between 400 and 2000 nm. The high absorption cross section (plasmonic nanoparticles absorb photons over a region about ten

• times larger than their physical diameters) [59], and the lack of photobleaching (unlike organic fluorescent dyes and semiconductor nanocrystals) are additional parameters making plasmonic nanocrystals attractive materials for biosensing. Importantly, the position of the plasmon band and its bandwidth

• are also strictly related to the local environment. The collation of a nanoparticle at a nanometric distance from the surface of another nanoparticle induces a redshift of the maximum of the surface plasmon band because of plasmon coupling, causing a color change of the solution. Thus, the control

Fabrication of Ag-modified hollow titania spheres via controlled silver diffusion in Ag–TiO₂ core–shell nanostructures

• Bartosz Bartosewicz,
• Malwina Liszewska,
• Bogusław Budner,
• Marta Michalska-Domańska,
• Krzysztof Kopczyński and
• Bartłomiej J. Jankiewicz

Beilstein J. Nanotechnol. 2020, 11, 141–146, doi:10.3762/bjnano.11.12

• silver diffusion in Ag–TiO2 core–shell nanostructures (CSNs). Our approach comprises three simple steps starting from the synthesis of the metallic core, through its coating with titania and finally annealing leading to plasmonic hollow nanostructures with plasmon resonance in a broad spectral range. SEM

• result, to a red-shift of the plasmon resonance [20]. As can be seen from curve A in Figure 4, Ag@TiO2 CSNs have a broad absorption in the UV–vis range. This is the characteristic absorption of these composites, which does not change remarkably with a change of the shell thickness. The annealing of Ag

• @TiO2 CSNs leads to nanostructures with significantly changed optical properties as can be seen from curves B–E in Figure 4. In all cases, a red-shift of the maximum of absorption and a strengthening and widening of the plasmon resonance bands were observed. It is significant that the Ag-modified TiO2

Plasmonic nanosensor based on multiple independently tunable Fano resonances

• Lin Cheng,
• Zelong Wang,
• Xiaodong He and
• Pengfei Cao

Beilstein J. Nanotechnol. 2019, 10, 2527–2537, doi:10.3762/bjnano.10.243

• nanosensors, optical splitters, filters, optical switches, nonlinear photonic and slow-light devices. Keywords: Fano resonance; metal–dielectric–metal (MDM) waveguide; nanosensor; on-chip plasmonic structures; surface plasmon polaritons (SPPs); Introduction Surface plasmon polariton (SPP) is a unique

Formation of metal/semiconductor Cu–Si composite nanostructures

• Natalya V. Yumozhapova,
• Andrey V. Nomoev,
• Vyacheslav V. Syzrantsev and
• Erzhena C. Khartaeva

Beilstein J. Nanotechnol. 2019, 10, 2497–2504, doi:10.3762/bjnano.10.240

• [10], or can even consist of three layers [11][12]. These variations can be useful for practical applications, e.g., for enhancing the absorption capacity of particles or for plasmon–exciton interaction [13]. The presence of an inorganic shell on a metal particle often leads to a significant

Label-free highly sensitive probe detection with novel hierarchical SERS substrates fabricated by nanoindentation and chemical reaction methods

• Jingran Zhang,
• Tianqi Jia,
• Yongda Yan,
• Li Wang,
• Peng Miao,
• Yimin Han,
• Xinming Zhang,
• Guangfeng Shi,
• Yanquan Geng,
• Zhankun Weng,
• Daniel Laipple and
• Zuobin Wang

Beilstein J. Nanotechnol. 2019, 10, 2483–2496, doi:10.3762/bjnano.10.239

• chemical (CM) [5] and electromagnetic enhancement (EM) [6][7]. The CM enhancement is the main factor for charge transfer between the SERS substrate and probe molecule. The EM field enhancement is the main factor for localized surface plasmon resonance (LSPR) and significantly depends on the induced near

Abrupt elastic-to-plastic transition in pentagonal nanowires under bending

• Sergei Vlassov,
• Magnus Mets,
• Boris Polyakov,
• Jianjun Bian,
• Leonid Dorogin and
• Vahur Zadin

Beilstein J. Nanotechnol. 2019, 10, 2468–2476, doi:10.3762/bjnano.10.237

• conductive network [14][15][16]. Ag NWs are a promising material for flexible transparent electrodes [17]. Plasmon propagation and the optical properties of Ag and Au NWs make them attractive for nanophotonics as waveguides for visible light [18][19][20][21][22][23]. In all these applications, NWs may

• curved pathways for electromagnetic radiation. Any crack or other discontinuities that are introduced by bending can prevent plasmon propagation in the NW [19]. Pure bending conditions are realized in the cantilever beam bending configuration where the NW is fixed at one end and the free end is pushed by

Multiple Fano resonances with flexible tunablity based on symmetry-breaking resonators

• Xiao bin Ren,
• Kun Ren,
• Ying Zhang,
• Cheng guo Ming and
• Qun Han

Beilstein J. Nanotechnol. 2019, 10, 2459–2467, doi:10.3762/bjnano.10.236

• new opportunities to design on-chip optical devices with great tuning performance. Keywords: multiple Fano resonance; off-centered ring resonators; plasmonic waveguide; surface plasmon polaritons; symmetry-breaking; tunable resonance; Introduction Fano resonances originate from the interference of a

• reflectance). In addition to PhC waveguides, metal–dielectric–metal (MDM) waveguides are very attractive for researchers because they can support surface plasmon polaritons (SPPs) and allow for the control of light at the subwavelength scale. MDM waveguides provide an effective approach to chip-scale photonic

The role of Ag⁺, Ca²⁺, Pb²⁺ and Al³⁺ adions in the SERS turn-on effect of anionic analytes

• Stefania D. Iancu,
• Andrei Stefancu,
• Vlad Moisoiu,
• Loredana F. Leopold and
• Nicolae Leopold

Beilstein J. Nanotechnol. 2019, 10, 2338–2345, doi:10.3762/bjnano.10.224

• surface of the AgNPs. Therefore, the observed blue shift and damping of the surface plasmon resonance (SPR) peak, which is observed only after the formation of Ag+ adions, indicates an electronic contact between the AgNPs and citrate (Figure 1B) [28][29][30]. No SERS spectra of citrate were obtained at pH

Nonlinear absorption and scattering of a single plasmonic nanostructure characterized by x-scan technique

• Tushar C. Jagadale,
• Dhanya S. Murali and
• Shi-Wei Chu

Beilstein J. Nanotechnol. 2019, 10, 2182–2191, doi:10.3762/bjnano.10.211

• properties of plasmonic nanostructures differ significantly from those of the corresponding bulk materials, mainly because of two reasons, i.e., the enhancement in the surface-to-volume ratio and the appearance of resonance effects such as surface plasmon resonance (SPR). For example, the color, or more

• plasmonic nanostructures [4][5][6]. The potential applications of nonlinear nanoplasmonics include nanolasers [7], nanoantennas [8], surface plasmon polariton (SPP)-based waveguides [9], nanostructure-based optical limiters [10], nanoscopy instruments [11][12], and nanoelectronics as integrated optical

Gold-coated plant virus as computed tomography imaging contrast agent

• Alaa A. A. Aljabali,
• Mazhar S. Al Zoubi,
• Khalid M. Al-Batanyeh,
• Ali Al-Radaideh,
• Mohammad A. Obeid,
• Abeer Al Sharabi,
• Walhan Alshaer,
• Bayan AbuFares,
• Tasnim Al-Zanati,
• Murtaza M. Tambuwala,
• Naveed Akbar and
• David J. Evans

Beilstein J. Nanotechnol. 2019, 10, 1983–1993, doi:10.3762/bjnano.10.195

• confirms the formation of spherical particles for all three sizes. The surface plasmon resonance depends on the shape and the size of the NPs. For instance, ellipsoid shapes with three different axes have three different dipole modes. When the size of the spherical AuNPs increases, their SPR does not red

• functionalization of Au-CPMV. The localized surface plasmon resonance (LSPR) spectrum shifted by almost 4 nm (Figure 3A). This shift of the extinction maximum from 534 nm to 538 nm is a result of an increase in the local refractive index at the Au-CPMV surface as reported in the literature following surface