Charge and heat transport in soft nanosystems in the presence of time-dependent perturbations

• Alberto Nocera,
• Carmine Antonio Perroni,
• Vincenzo Marigliano Ramaglia and
• Vittorio Cataudella

Beilstein J. Nanotechnol. 2016, 7, 439–464, doi:10.3762/bjnano.7.39

• always gets larger with increasing the electron–vibration coupling EP. Actually, the electron–oscillator coupling gives rise to an additional damping rate on the vibrational dynamics whose effect is to enhance the thermal conductivity . In a certain sense, due to the electron–vibration coupling, the

Synthesis and applications of carbon nanomaterials for energy generation and storage

• Marco Notarianni,
• Jinzhang Liu,
• Kristy Vernon and
• Nunzio Motta

Beilstein J. Nanotechnol. 2016, 7, 149–196, doi:10.3762/bjnano.7.17

• hexagons around the equatorial plane and exhibits a more oval shape (Figure 4) [26]. The main properties of C60 are [25]: Young’s modulus, ≈14 GPa Electrical resistivity, ≈1014 Ω m Thermal conductivity, ≈0.4 W/mK Band gap, 1.7 eV The other fullerene species show similar properties to C60. Depending on the

• , ≈0.62–1.25 TPa [40] Electrical resistivity, ≈1 μΩ cm [41] Thermal conductivity, ≈3000 W/mK [42] In addition to their extraordinary properties, the density of CNTs is around 1.33–1.4 g/cm3 [40], which is half of the density of aluminium (2.7 g/cm3), making them very attractive for lightweight

• ][63], high Young’s modulus (≈1 TPa) with an intrinsic strength of 130 GPa [64][65], high thermal conductivity (over 3000 W m−1 K−1) [66] and excellent optical transmittance (≈97.7%) [67]. Additional graphene characteristics include: high theoretical specific surface area (2630 m2 g−1) [68

Current-induced runaway vibrations in dehydrogenated graphene nanoribbons

• Rasmus Bjerregaard Christensen,
• Jing-Tao Lü,
• Per Hedegård and
• Mads Brandbyge

Beilstein J. Nanotechnol. 2016, 7, 68–74, doi:10.3762/bjnano.7.8

• study since its discovery in 2004 [1]. Due to the strong σ-bonding between carbon atoms, graphene has a very high thermal conductivity, and can potentially sustain much higher current intensities than other materials. Graphene nanoribbons (GNR) exhibit a bandgap opening due to quantum confinement in the

Calculations of helium separation via uniform pores of stanene-based membranes

• Guoping Gao,
• Yan Jiao,
• Yalong Jiao,
• Fengxian Ma,
• Liangzhi Kou and
• Aijun Du

Beilstein J. Nanotechnol. 2015, 6, 2470–2476, doi:10.3762/bjnano.6.256

• lattice; Introduction With many outstanding properties such as low density, low boiling point, low solubility, and high thermal conductivity and inertness, helium finds extensive application in cryogenic science [1], arc welding processes [2], and leak detection [3]. Although it is the second most

High I_on/I_off current ratio graphene field effect transistor: the role of line defect

• Mohammad Hadi Tajarrod and
• Hassan Rasooli Saghai

Beilstein J. Nanotechnol. 2015, 6, 2062–2068, doi:10.3762/bjnano.6.210

• of its unique electronic transport properties. The properties of graphene such ultra-thin body properties for optimum electrostatic scaling and excellent thermal conductivity has made it a potential alternative to silicon and facilitated the manufacture of devices [1][2]. Furthermore, the high

• the best candidates for changing the hexagon structure of graphene with acceptable C–C distances and angles for sp2 hybridization [7]. These defects play a remarkable role in graphene and nano-structured devices. One controlled defect in graphene are grain boundaries. The electrical and thermal

• conductivity decrease with grain boundaries in materials [8][9]. By studying the grain boundaries in graphite, extended line defects become visible in the STM analysis [10]. The first experimental report of the extended line defect (ELD), which was studied through alternating Stone–Thrower–Wales defects, was

Simulation of thermal stress and buckling instability in Si/Ge and Ge/Si core/shell nanowires

• Suvankar Das,
• Amitava Moitra,
• Mishreyee Bhattacharya and
• Amlan Dutta

Beilstein J. Nanotechnol. 2015, 6, 1970–1977, doi:10.3762/bjnano.6.201

• for next generation transistor devices. The radial heterostructure offers the advantage of control of the band gap and charge carrier mobility by tuning their size [5] and selecting suitable impurity doping scheme [3][6]. In addition, they exhibit significantly suppressed phonon thermal conductivity

• been widely adopted for incorporating the quantum effects in classical MD simulations dealing with the measurement of thermal properties such as thermal conductivity [31] and the coefficient of thermal expansion [32][33]. In this method, a system with N atoms produces the 3N × 3N dynamical matrix, as

Temperature-dependent breakdown of hydrogen peroxide-treated ZnO and TiO₂ nanoparticle agglomerates

• Sinan Sabuncu and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2015, 6, 1897–1903, doi:10.3762/bjnano.6.193

• nm) was examined [16]. The thermal conductivity and surface potential of the nanofluids were also studied [17][18][19]. The toxicity of NPs is another concern that is strongly related to their size, shape, and surface chemistry. Since the synthesis of NPs of a certain size and shape in large

Metal hydrides: an innovative and challenging conversion reaction anode for lithium-ion batteries

• Luc Aymard,
• Yassine Oumellal and
• Jean-Pierre Bonnet

Beilstein J. Nanotechnol. 2015, 6, 1821–1839, doi:10.3762/bjnano.6.186

• particle size of the hydride but also enhances its reactivity vs Li-ions. In the case of the system Mg/MgH2, 5% of Super P carbon was mixed with the Mg powder in order to increase the thermal conductivity of the powder and to prevent the necking of particles during sorption cycles. Figure 13a and Figure

• commercial hydride, as expected (Figure 16). The dispersion of the hydride particles into carbon increases the thermal conductivity of the powder and helps the hydrogen release. With regard to the electrochemical properties, the potential–capacity curves of an electrode composite of MgH2–10% Ct,z obtained

Possibilities and limitations of advanced transmission electron microscopy for carbon-based nanomaterials

• Xiaoxing Ke,
• Carla Bittencourt and
• Gustaaf Van Tendeloo

Beilstein J. Nanotechnol. 2015, 6, 1541–1557, doi:10.3762/bjnano.6.158

• excellent electric and thermal conductivity [47][48] and suffer only slightly from damage related to inelastic scattering. Although the previous discussion has pointed out that low operating voltages increase the damage of large holes possibly due to etching, imaging conditions of 60 keV and 80 keV are

Thermal energy storage – overview and specific insight into nitrate salts for sensible and latent heat storage

• Nicole Pfleger,
• Thomas Bauer,
• Claudia Martin,
• Markus Eck and
• Antje Wörner

Beilstein J. Nanotechnol. 2015, 6, 1487–1497, doi:10.3762/bjnano.6.154

• the storage capacity is directly proportional to the heat capacity which therefore is an essential parameter. Several data exist which are summarized in the following. The data show that the heat capacity is slightly increasing with temperature (see Figure 2). Concerning the thermal conductivity

• several data exist which are not consistent and therefore rather give a rough idea, as shown in Figure 3. Even though the data differ in the different publications the measurements show that the thermal conductivity increases with temperature. More precise data require additional experiments. As to the

• properties (porosity, density, compressive strength, heat capacity) and the thermal stability up to 400 °C in an air atmosphere have been determined. Quartzite was chosen as the most suitable filler material because of its high thermal conductivity (caused by the high percentage of the mineral quartz) and

Improved optical limiting performance of laser-ablation-generated metal nanoparticles due to silica-microsphere-induced local field enhancement

• Zheren Du,
• Lianwei Chen,
• Tsung-Sheng Kao,
• Mengxue Wu and
• Minghui Hong

Beilstein J. Nanotechnol. 2015, 6, 1199–1204, doi:10.3762/bjnano.6.122

• absorbed laser energy. Hence, the size of the laser-generated Ag nanoparticles is larger. Au and Ag have different physical properties, such as the absorption spectrum of the laser light, melting point, boiling point and thermal conductivity, which all can contribute to the size difference. The laser

Enhancing the thermoelectric figure of merit in engineered graphene nanoribbons

• Hatef Sadeghi,
• Sara Sangtarash and
• Colin J. Lambert

Beilstein J. Nanotechnol. 2015, 6, 1176–1182, doi:10.3762/bjnano.6.119

• thermoelectricity requires a strongly suppressed thermal conductivity (κ) since the performance of thermoelectric devices is inversely proportional to the thermal conductivity. On the other hand, the cooling of local hot spots requires a high thermal conductivity [3]. Thermal conductance in a solid is defined by

• graphene [20]. This means that 2D graphene and its multilayer counterparts are useful for thermal management applications [21]. The high thermal conductivity of the graphene is mainly due to the high phonon contribution to heat transport. Therefore, for thermoelectricity applications, one needs to engineer

• phonon transport to achieve a low thermal conductivity. Moreover, graphene is a zero-gap material and not suitable to use as thermoelectric material because of its very small Seebeck coefficient. However, theoretical studies revealed that phonon transport is sensitive to defects, strain, sample size and

Graphene quantum interference photodetector

• Mahbub Alam and
• Paul L. Voss

Beilstein J. Nanotechnol. 2015, 6, 726–735, doi:10.3762/bjnano.6.74

• as high electrical mobility, high thermal conductivity, high mechanical strength, linear energy dispersion around the Dirac point and strong light absorption from near-infrared to visible wavelengths [1][2][3]. Graphene also exhibits ballistic electron transport over unusually long lengths [4][5][6

Structural, optical, opto-thermal and thermal properties of ZnS–PVA nanofluids synthesized through a radiolytic approach

• Alireza Kharazmi,
• Nastaran Faraji,
• Roslina Mat Hussin,
• Elias Saion,
• W. Mahmood Mat Yunus and
• Kasra Behzad

Beilstein J. Nanotechnol. 2015, 6, 529–536, doi:10.3762/bjnano.6.55

• , powder X-ray diffraction (XRD) for confirming the formation and crystalline structure of ZnS nanoparticles, UV–visible spectroscopy for measuring the electronic absorption characteristics, transient hot wire (THW) and photoacoustic measurements for measuring the thermal conductivity and thermal

• effusivity of the samples, from which, for the first time, the values of specific heat and thermal diffusivity of the samples were then calculated. Keywords: Fourier transform infrared spectroscopy (FTIR); specific heat; thermal conductivity; thermal effusivity; ZnS nanoparticles; Introduction Over the

• originating from chemical initiators [6]. The interest in measuring the thermal conductivity (k) and the thermal effusivity (e) of nanofluids containing semiconductors has increased [15] because of their increasing use in devices [16]. The photoacoustic (PA) effect has been demonstrated to be a valid

Synthesis of boron nitride nanotubes and their applications

• Saban Kalay,
• Zehra Yilmaz,
• Ozlem Sen,
• Melis Emanet,
• Emine Kazanc and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2015, 6, 84–102, doi:10.3762/bjnano.6.9

• radiation absorption. Their electrical insulation is indeed very high, despite a high thermal conductivity [6]. Due to these properties, they can be used in a wide range of applications. BNNTs can resist oxidation in air up to 1000 °C while CNTs are resistant only up to 500 °C under the same conditions [7

SERS and DFT study of copper surfaces coated with corrosion inhibitor

• Maurizio Muniz-Miranda,
• Francesco Muniz-Miranda and
• Stefano Caporali

Beilstein J. Nanotechnol. 2014, 5, 2489–2497, doi:10.3762/bjnano.5.258

• large electrical and thermal conductivity, mechanical workability and durability (due to its endurance to weathering). These properties, however, can be compromised by the occurrence of corrosion. In fact, copper undergoes severe corrosion in the presence of ions such as chlorides, which can be present

Synthesis of Pt nanoparticles and their burrowing into Si due to synergistic effects of ion beam energy losses

• Pravin Kumar,
• Udai Bhan Singh,
• Kedar Mal,
• Sunil Ojha,
• Indra Sulania,
• Dinakar Kanjilal,
• Dinesh Singh and
• Vidya Nand Singh

Beilstein J. Nanotechnol. 2014, 5, 1864–1872, doi:10.3762/bjnano.5.197

• combination is 846/ion (TRIM calculations). Using the thermal properties of silicon (a specific heat of 710 J/kg∙K and a thermal conductivity of 150 W/m∙K) and electronic energy deposited by the ions in silicon, we expect a spike temperature of about ≈2540 K (within 1 ps and 1 nm away from the ion track) [44

Carbon-based smart nanomaterials in biomedicine and neuroengineering

• Antonina M. Monaco and
• Michele Giugliano

Beilstein J. Nanotechnol. 2014, 5, 1849–1863, doi:10.3762/bjnano.5.196

• mobility of electrical charge carriers and high thermal conductivity [8][9]. Diamond exhibits these properties both in bulk as well as at the nanoscale and combines them with typical features of nanomaterials, such as a large surface area and small overall size. NDs, mainly obtained by detonation of TNT

A study on the consequence of swift heavy ion irradiation of Zn–silica nanocomposite thin films: electronic sputtering

• Compesh Pannu,
• Udai B. Singh,
• Dinesh. C. Agarwal,
• Saif A. Khan,
• Sunil Ojha,
• Ramesh Chandra,
• Hiro Amekura,
• Debdulal Kabiraj and
• Devesh. K. Avasthi

Beilstein J. Nanotechnol. 2014, 5, 1691–1698, doi:10.3762/bjnano.5.179

• , the incoming ion transfers its energy to electrons of the target. Due to the high thermal conductivity, the deposited energy is quickly transferred to other electrons and the heat transferred to the metal lattice through electron–phonon coupling is not sufficient to cause the melting of the metal

• . Whereas in the case of silica, a smaller deposited energy is enough to cause melting due to the low thermal conductivity and the high value of g. If we consider the case of metal nanoparticles embedded in silica (nanocomposite system), the scenario becomes quite different. The temperature of the metal

• through interaction with electrons of silica as well as of the metal nanoparticle. When the incident ion interacts with the electrons of the metal nanoparticle, the deposited energy rapidly diffuses to other electrons within the nanoparticle due to high thermal conductivity (ca. 318 W/(m·K) at 25 °C

Liquid fuel cells

• Grigorii L. Soloveichik

Beilstein J. Nanotechnol. 2014, 5, 1399–1418, doi:10.3762/bjnano.5.153

• separating the individual cells in the stack should have a high corrosion resistance, good electronic and thermal conductivity, and be designed to evenly distribute reactants and products. It is worth noting that the bipolar plates have an impact on the cost structure comparable with the impact of catalytic

• requires substantial thermal energy, which is technically challenging due to their low thermal conductivity. The dehydrogenation of methylcyclohexane to toluene for both transportation and seasonal hydrogen storage was proposed 20 years ago [18]. Later the less volatile decalin/naphtalene couple with 7.3

Review of nanostructured devices for thermoelectric applications

• Giovanni Pennelli

Beilstein J. Nanotechnol. 2014, 5, 1268–1284, doi:10.3762/bjnano.5.141

• TEG for thermal conduction: Most of the heat passes through the generator and it is wasted on the cold side without being converted in useful electrical power. Thus, one of the main target of research efforts in thermoelectricity is to develop materials with a very low thermal conductivity, while

• known materials both from the physical and the technological point of views, and it is at the center of a worldwide manufacturing infrastructure. Thermoelectric applications of silicon are currently limited by its high thermal conductivity (148 W/mK). However, several studies have observed a strong

• reduction of thermal conductivity in rough silicon nanowires [8][9][10]. For this reason, section IV is dedicated to the review of the main techniques currently investigated for the fabrication of silicon nanostructures that can be integrated in devices for thermoelectric generation. Review Principles of

Organic and inorganic–organic thin film structures by molecular layer deposition: A review

• Pia Sundberg and
• Maarit Karppinen

Beilstein J. Nanotechnol. 2014, 5, 1104–1136, doi:10.3762/bjnano.5.123

• reactions occurring during the growth. Also the GPC is far below the length of a Zn–EG unit, which was estimated to be around 6.9 Å. Thermal conductivity of the DEZ+EG hybrid was measured to be around 0.22–0.23 W/(m·K), with little variation in the values when thicker samples were analyzed. The volumetric

• 150 °C was obtained. Although considerably higher than when comparing to GPC obtained earlier, it is still far from the ideal growth, which was estimated to be around 8.4 Å per cycle. Thermal conductivity of the DEZ+HQ films was considerable higher than those of the DEZ+EG films, i.e., about 0.32–0.38

Integration of ZnO and CuO nanowires into a thermoelectric module

• Dario Zappa,
• Simone Dalola,
• Guido Faglia,
• Elisabetta Comini,
• Matteo Ferroni,
• Caterina Soldano,
• Vittorio Ferrari and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2014, 5, 927–936, doi:10.3762/bjnano.5.106

• ) performance of a material, including the thermal conductivity κ, the electrical conductivity σ and the Seebeck coefficient S. Further, the efficiency of a thermoelectric device depends on the thermoelectric power factor (TPF) and the figure of merit (ZT) of the material, which are defined as S2σ and S2Tσ/κ

• and the figure of merit ZT. In particular, in order to evaluate ZT is necessary to measure the thermal conductivity of the materials. Thermal conductivity measurements are still ongoing, because we need the reengineering of the test device to get rid of the thermal influence of the substrate. We

An analytical approach to evaluate the performance of graphene and carbon nanotubes for NH₃ gas sensor applications

• Elnaz Akbari,
• Vijay K. Arora,
• Aria Enzevaee,
• Mohamad. T. Ahmadi,
• Mehdi Saeidmanesh,
• Mohsen Khaledian,
• Hediyeh Karimi and
• Rubiyah Yusof

Beilstein J. Nanotechnol. 2014, 5, 726–734, doi:10.3762/bjnano.5.85

• . A CNT is known to have a very high electrical and thermal conductivity as well as a high Young's modulus giving it the mechanical strength. The applications of CNTs are broad due to their compact structure and include transistors, sensors, solar cells, fuel cells, etc. [17]. Andre Geim and

Resonance of graphene nanoribbons doped with nitrogen and boron: a molecular dynamics study

• Ye Wei,
• Haifei Zhan,
• Kang Xia,
• Wendong Zhang,
• Shengbo Sang and
• Yuantong Gu

Beilstein J. Nanotechnol. 2014, 5, 717–725, doi:10.3762/bjnano.5.84

• been reported to have supreme stiffness (Young’s modulus ≈ 1 TPa), very high electron mobility, electrical and thermal conductivity, optical absorption as well as many other excellent properties [2][3]. These properties of graphene open up huge potential applications in the area of electronics