Self-assembly of amino acids toward functional biomaterials

• Huan Ren,
• Lifang Wu,
• Lina Tan,
• Yanni Bao,
• Yuchen Ma,
• Yong Jin and
• Qianli Zou

Beilstein J. Nanotechnol. 2021, 12, 1140–1150, doi:10.3762/bjnano.12.85

• promising natural antitumor drug, which can inhibit the transformation, proliferation, and migration of tumor cells through various ways, and has anti-angiogenic activity and good biocompatibility [72]. However, the poor water solubility and low bioavailability of curcumin hinder its direct application [73

First-principles study of the structural, optoelectronic and thermophysical properties of the π-SnSe for thermoelectric applications

• Muhammad Atif Sattar,
• Najwa Al Bouzieh,
• Maamar Benkraouda and
• Noureddine Amrane

Beilstein J. Nanotechnol. 2021, 12, 1101–1114, doi:10.3762/bjnano.12.82

• conduction bands, respectively. The relation ħωcv = Eck – Evk shows the transition energy from valence to conduction bands. This absorptive imaginary ε2(ω) part of the dielectric function leads to the real part ε1(ω) through the Kramers–Kronig transformation and can be obtained from the following relation

Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries

• Marina Tabuyo-Martínez,
• Bernd Wicklein and
• Pilar Aranda

Beilstein J. Nanotechnol. 2021, 12, 995–1020, doi:10.3762/bjnano.12.75

• intermediate reactions [15], that is, (1) the transformation of sulfur into long-chain polysulfides: 4Na + S8 ⇌ 2Na2Sn (4 < n ≤ 8), (2) the transformation of long-chain into short-chain polysulfides: 2Na + Na2S4 ⇌ 2Na2Sm (2 ≤ m < 4), and (3) the transformation of short-chain polysulfides into sodium sulfide

• undergo a sodiation process to form Na2S2. Then, the Na2S2 intermediate is converted to Na2S. Another remarkable electrocatalyst are gold nanodots, as reported by Wang et al. [49]. The in situ synchrotron XRD results show that gold can effectively catalyze the transformation of Na2S4 into Na2S in the

Is the Ne operation of the helium ion microscope suitable for electron backscatter diffraction sample preparation?

• Annalena Wolff

Beilstein J. Nanotechnol. 2021, 12, 965–983, doi:10.3762/bjnano.12.73

• alterations and, in some instances, phase transformation of Cu to Cu3Ga occurred when polishing with Ga ions. Polishing with high-energy Ne ions at a glancing angle maintains the crystal structure and significantly improves indexing in EBSD measurements. By milling down to a depth equaling the depth of the

• grains is 25% when using this lower ion dose and would be sufficiently large to allow the formation of the Cu3Ga phase. To evaluate if a significant phase transformation and sample alteration occur at a lower ion dose than previously reported, the two different ion doses (2247 ions/nm2 and 3371 ions/nm2

• . Faster milling grains, however, do not reach this critical concentration and phase transformations. In addition, significant crystal structure changes could not be observed in the EBSD measurements for those grains. The measurements suggest that the damage and occurring phase transformation are linked to

In situ transport characterization of magnetic states in Nb/Co superconductor/ferromagnet heterostructures

• Olena M. Kapran,
• Roman Morari,
• Taras Golod,
• Evgenii A. Borodianskyi,
• Vladimir Boian,
• Andrei Prepelita,
• Nikolay Klenov,
• Anatoli S. Sidorenko and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2021, 12, 913–923, doi:10.3762/bjnano.12.68

• . Therefore, variation of MR reflects the transformation of magnetic states in the multilayer. In Figure 2e we replot low-field parts of the downward curves from Figure 2a and Figure 2c. It is seen that they coincide after proper scaling, that is, they represent a temperature-independent part of MR, which

• middle of the Rxx maximum. The reversal curve is clearly different from curve-5, revealing yet another initial state. With a further increase of Hr towards the negative saturation field, the hysteresis changes gradually until reaching the saturated state, shown in Figure 3a. Such a gradual transformation

Modification of a SERS-active Ag surface to promote adsorption of charged analytes: effect of Cu²⁺ ions

• Bahdan V. Ranishenka,
• Andrei Yu. Panarin,
• Irina A. Chelnokova,
• Sergei N. Terekhov,
• Peter Mojzes and
• Vadim V. Shmanai

Beilstein J. Nanotechnol. 2021, 12, 902–912, doi:10.3762/bjnano.12.67

• ]. For this purpose, copper cations were selected since they are already present in the structure of both analyte molecules and, thus, their chemical transformation can be excluded. Treatment of the NP surfaces with Cu2+ ions resulted in an about twofold increase of the CuTMpyP4 SERS intensity. Under the

Electromigration-induced formation of percolating adsorbate islands during condensation from the gaseous phase: a computational study

• Alina V. Dvornichenko,
• Vasyl O. Kharchenko and
• Dmitrii O. Kharchenko

Beilstein J. Nanotechnol. 2021, 12, 694–703, doi:10.3762/bjnano.12.55

• morphological transformation from separated adsorbate islands on the substrate towards separated holes inside the adsorbate matrix at α = αm. An increase in the rate of adatoms transference between layers, k∥, acts oppositely. In Figure 5 we show dependencies of the total amount of adsorbate clusters Ntot and

Fate and transformation of silver nanoparticles in different biological conditions

• Barbara Pem,
• Marija Ćurlin,
• Darija Domazet Jurašin,
• Valerije Vrček,
• Rinea Barbir,
• Vedran Micek,
• Raluca M. Fratila,
• Jesus M. de la Fuente and
• Ivana Vinković Vrček

Beilstein J. Nanotechnol. 2021, 12, 665–679, doi:10.3762/bjnano.12.53

• transformation, dissolution, and degradation behaviour of different types of AgNPs were evaluated in systems modelled to represent biological environments relevant for oral administration, as well as in cell culture media and tissue compartments obtained from animal models. A multimethod approach was employed by

• nanoparticulate, ionic, metallic, and complex salts forms [9][10][11][12][13][14]. Despite many scientific and medical evidences for (bio)chemical transformation patterns of AgNPs [15], questions about their final fate in the body are still open. Irreversible skin discoloration or argyria was described in

• significantly affect AgNPs and determine their colloidal stability and cellular interactions as evidenced earlier [27][31][32][33]. In the acidic medium of the stomach, AgNPs both agglomerate and dissolve [15][26][34]. The transformation will likely be incomplete due to protein corona formation and short

On the stability of microwave-fabricated SERS substrates – chemical and morphological considerations

• Limin Wang,
• Aisha Adebola Womiloju,
• Christiane Höppener,
• Ulrich S. Schubert and
• Stephanie Hoeppener

Beilstein J. Nanotechnol. 2021, 12, 541–551, doi:10.3762/bjnano.12.44

• can be found in Supporting Information File 1, Table S1. The observed band structure clearly identifies bands at 1394, 1440, and 1580 cm−1 which are indicative of 4,4’-dimercaptoazobenzene (DMAB), which is formed by an oxidative transformation of 4-ATP on Ag nanoparticle surfaces at higher laser power

A review on nanostructured silver as a basic ingredient in medicine: physicochemical parameters and characterization

• Gabriel M. Misirli,
• Kishore Sridharan and
• Shirley M. P. Abrantes

Beilstein J. Nanotechnol. 2021, 12, 440–461, doi:10.3762/bjnano.12.36

• effect of light irradiation on AgNPs with spherical and cubic morphologies under ambient conditions. They confirmed that light wavelengths below 495 nm, corresponding to the UV/blue part of the electromagnetic spectrum, were mainly responsible for their photo-transformation [52]. In both the cases, the

Spontaneous shape transition of Mn_xGe_1−x islands to long nanowires

• S. Javad Rezvani,
• Luc Favre,
• Gabriele Giuli,
• Yiming Wubulikasimu,
• Isabelle Berbezier,
• Augusto Marcelli,
• Luca Boarino and
• Nicola Pinto

Beilstein J. Nanotechnol. 2021, 12, 366–374, doi:10.3762/bjnano.12.30

• best of our knowledge, this is the first report on the spontaneous growth of MnxGe1−x NWs that do not result from seeded growth and/or phase transformation. Considering all the features of the NWs observed here, we suggest that they are formed by a two-step process. First, the growth of 3D islands to

Structural and optical characteristics determined by the sputtering deposition conditions of oxide thin films

• Petronela Prepelita,
• Florin Garoi and
• Valentin Craciun

Beilstein J. Nanotechnol. 2021, 12, 354–365, doi:10.3762/bjnano.12.29

• properties. Transparent oxides are an attractive class of plasmonic materials which are under intense study for their integration into low-loss metamaterial structures and a series of applications in transformation optics, sensors, and imaging. Here we used oxide thin films and studied their optical

Doxorubicin-loaded gold nanorods: a multifunctional chemo-photothermal nanoplatform for cancer management

• Uzma Azeem Awan,
• Abida Raza,
• Shaukat Ali,
• Rida Fatima Saeed and
• Nosheen Akhtar

Beilstein J. Nanotechnol. 2021, 12, 295–303, doi:10.3762/bjnano.12.24

• . There was an increase in temperature to 52 °C and 45 °C, respectively. In contrast, no significant change in temperature was observed when water was exposed to the same laser irradiation (Figure 3b). This confirmed the light–heat transformation through the GNRs. This hyperthermic effect mediated by GNRs

Characterization, bio-uptake and toxicity of polymer-coated silver nanoparticles and their interaction with human peripheral blood mononuclear cells

• Sahar Pourhoseini,
• Reilly T. Enos,
• Angela E. Murphy,
• Bo Cai and
• Jamie R. Lead

Beilstein J. Nanotechnol. 2021, 12, 282–294, doi:10.3762/bjnano.12.23

• human cells (peripheral blood mononuclear cells (PBMCs)). AgNPs were synthesized in-house and characterized using a multimethod approach. Results indicated the transformation of NPs in RPMI medium with a change in size and polydispersity over 24 h of exposure due to dissolution and reprecipitation. No

• is possible that the number of monocytes in the blood of different individuals could be elevated due to potential chronic inflammatory diseases or viral infection. The transformation of AgNPs to Ag ions may cause toxicity that is referred to as Trojan Horse mechanism, that is, AgNPs act as a carrier

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• in a layered trapezoidal shape along two directions. The Yoshimura fold has a 3D transformation in a spring-like form, which is promising to be explored in different applications. The waterbomb fold is also a basic 2D compression fold used to create unique geometries; yet they are difficult to apply

ZnO and MXenes as electrode materials for supercapacitor devices

• Ameen Uddin Ammar,
• Ipek Deniz Yildirim,
• Feray Bakan and
• Emre Erdem

Beilstein J. Nanotechnol. 2021, 12, 49–57, doi:10.3762/bjnano.12.4

• alternatives to metal oxides are two-dimensional (2D) MXenes. Their properties include environmental sustainability, lamellar structure, high transformation efficiency, high surface hydrophilicity, and good electrical conductivity [14]. Therefore, in the following section we discuss the main properties of

Free and partially encapsulated manganese ferrite nanoparticles in multiwall carbon nanotubes

• Saja Al-Khabouri,
• Salim Al-Harthi,
• Toru Maekawa,
• Mohamed E. Elzain,
• Ashraf Al-Hinai,
• Ahmed D. Al-Rawas,
• Abbsher M. Gismelseed,
• Ali A. Yousif and
• Myo Tay Zar Myint

Beilstein J. Nanotechnol. 2020, 11, 1891–1904, doi:10.3762/bjnano.11.170

• second peak is mainly from the sp3 carbon [42] (Figure 8b). The evaluation of the sp2/sp3 ratio shows that there is a 1% higher transformation of sp2-hybridized to sp3-hybridized carbon in MnFe2O4/MWCNTs compared to the as-prepared samples. Thus, it is assumed that there is negligible damage to the tubes

Molecular dynamics modeling of the influence forming process parameters on the structure and morphology of a superconducting spin valve

• Alexander Vakhrushev,
• Aleksey Fedotov,
• Vladimir Boian,
• Roman Morari and
• Anatolie Sidorenko

Beilstein J. Nanotechnol. 2020, 11, 1776–1788, doi:10.3762/bjnano.11.160

• coordination number and are characterized by a denser packing of atoms. The described regions arise in sufficiently thick films mainly near cobalt layers. The initial metal crystal lattice mismatch causes mutual rearrangements of atoms and structure transformation inside the material. The next series of

• thickened niobium layer, crystallization zones are observed where direct contact with the cobalt nanolayer occurs. The crystal lattice mismatch of the starting metals causes mutual rearrangements of atoms and the structure transformation inside the nanosystem. It was also found that a decrease in the area

Out-of-plane surface patterning by subsurface processing of polymer substrates with focused ion beams

• Serguei Chiriaev,
• Luciana Tavares,
• Vadzim Adashkevich,
• Arkadiusz J. Goszczak and
• Horst-Günter Rubahn

Beilstein J. Nanotechnol. 2020, 11, 1693–1703, doi:10.3762/bjnano.11.151

• transformation and volume shrinkage of PMMA under ion irradiation have been reported in several publications [6][7][9][10][11][12][13]. PC is the second most sold thermoplastic polymer. It is extensively used in microtechnology due to its excellent optical, mechanical, and chemical properties [14]. Compared to

• cutting a piece of the PDMS polymer from a bulk sample. In contrast, the irradiation of a pristine PDMS surface of this sample resulted in material compacting. The authors explained that this difference was due to mechanical stress in the cut surface. Other important aspects of the transformation of the

Oxidation of Au/Ag films by oxygen plasma: phase separation and generation of nanoporosity

• Abdel-Aziz El Mel,
• Said A. Mansour,
• Mujaheed Pasha,
• Atef Zekri,
• Janarthanan Ponraj,
• Akshath Shetty and
• Yousef Haik

Beilstein J. Nanotechnol. 2020, 11, 1608–1614, doi:10.3762/bjnano.11.143

• the low earth orbit (LEO) [1][2][3][4][5][6][7][8][9]. Silver degradation related to this phenomenon was attributed to the strong chemical reaction between silver and atomic oxygen present in the LEO resulting in the transformation of the metallic silver into highly stressed and nanoporous silver

• residual stress. The repeated oxidation and cracking events result in the transformation of the metallic silver into nanoporous silver oxide when it reaches the surface of the film. In parallel to the oxidation reaction, silver keeps diffusing from the alloy film toward the surface, feeding the metallic

• oxidation process. This phase separation led to the transformation of the Au/Ag alloy film into a gold-enriched nanoporous film. Based on the experimental results a mechanism was proposed to explain the entire oxidation process of Au/Ag alloy films by oxygen plasma, involving silver oxidation by atomic

Atomic defect classification of the H–Si(100) surface through multi-mode scanning probe microscopy

• Jeremiah Croshaw,
• Thomas Dienel,
• Taleana Huff and
• Robert Wolkow

Beilstein J. Nanotechnol. 2020, 11, 1346–1360, doi:10.3762/bjnano.11.119

• defect which remains in the subsequent empty states images (compare Figure 5c,f,i to the first scans in Figure 5a,d,g). Importantly, we observe the complete absence of a charged species after the transformation and a replacement with the neutral point defect. The change in contrast of the AFM image of

Magnetohydrodynamic stagnation point on a Casson nanofluid flow over a radially stretching sheet

• Ganji Narender,
• Kamatam Govardhan and
• Gobburu Sreedhar Sarma

Beilstein J. Nanotechnol. 2020, 11, 1303–1315, doi:10.3762/bjnano.11.114

• written as The transformed boundary conditions are and the dimensionless parameters are defined as The formulas for the dimensional form of the skin-friction coefficient Cf, the Nusselt number Nu, and Sherwood number Sh, are given by and the formulas for τw, qw, and qm are The result of the transformation

Magnetic-field-assisted synthesis of anisotropic iron oxide particles: Effect of pH

• Andrey V. Shibaev,
• Petr V. Shvets,
• Darya E. Kessel,
• Roman A. Kamyshinsky,
• Anton S. Orekhov,
• Sergey S. Abramchuk,
• Alexei R. Khokhlov and
• Olga E. Philippova

Beilstein J. Nanotechnol. 2020, 11, 1230–1241, doi:10.3762/bjnano.11.107

• transformation into magnetite. The reaction pathway was strongly dependent on R and also on the rate in which the base was added. At the same time, the effect of pH on the templated directional synthesis of iron oxide as well as the formation of nanorods within this context are yet to be determined. In this work

Gas sorption porosimetry for the evaluation of hard carbons as anodes for Li- and Na-ion batteries

• Yuko Matsukawa,
• Fabian Linsenmann,
• Maximilian A. Plass,
• George Hasegawa,
• Katsuro Hayashi and
• Tim-Patrick Fellinger

Beilstein J. Nanotechnol. 2020, 11, 1217–1229, doi:10.3762/bjnano.11.106

• weight of Na), the lower volumetric energy density (because of the need for the less dense disordered carbons), as well as the more complicated storage mechanism complicate the commercialization SIBs. With the current strong interest in electromotive driving and the transformation of the energy grid to

Revealing the local crystallinity of single silicon core–shell nanowires using tip-enhanced Raman spectroscopy

• Marius van den Berg,
• Ardeshir Moeinian,
• Arne Kobald,
• Yu-Ting Chen,
• Anke Horneber,
• Steffen Strehle,
• Alfred J. Meixner and
• Dai Zhang

Beilstein J. Nanotechnol. 2020, 11, 1147–1156, doi:10.3762/bjnano.11.99

• oriented crystalline grains. b) The fast Fourier transformation image of the indicated area in panel a. c) TEM image showing a migrated metal particle on a SiNW. d) TEM image of a Pt-catalyzed core–shell SiNW showing the morphology of the junction between SiNW core and shell. e) Pt silicide catalyst and