Synthesis of boron nitride nanotubes from unprocessed colemanite

• Saban Kalay,
• Zehra Yilmaz and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2013, 4, 843–851, doi:10.3762/bjnano.4.95

• BNNTs are more toxic than CNTs [13]. The first BNNTs were synthesized by Chopra et al. with the arc-discharge method [14]. Later, the use of chemical vapor deposition (CVD), laser ablation, ball milling, a template-assisted process, and displacement reactions were reported for the synthesis [15][16][17

• with the use of a laser-ablation technique [22]. As can be concluded from these studies, CVD is a commonly used technique to synthesize BNNTs. The BNNT synthesis and growth mechanism depend on the reaction parameters such as substrate, catalyst and temperature but the mechanism has not been elucidated

Mapping of plasmonic resonances in nanotriangles

• Simon Dickreuter,
• Julia Gleixner,
• Andreas Kolloch,
• Johannes Boneberg,
• Elke Scheer and
• Paul Leiderer

Beilstein J. Nanotechnol. 2013, 4, 588–602, doi:10.3762/bjnano.4.66

• these structures with short laser pulses and imaging the resulting ablation and melting patterns. The triangular gold structures were prepared on Si substrates and had a thickness of 40 nm and a side length of ca. 500 nm. Irradiation was carried out with single femtosecond and picosecond laser pulses at

• a wavelength of 800 nm, which excited higher order plasmon modes in these triangles. The ablation distribution as well as the local melting of small parts of the nanostructures reflect the regions of large near-field enhancement. The observed patterns are reproduced in great detail by FDTD

• for the field enhancement are typically somewhat smaller than the calculated ones. The results demonstrate the caveats for FDTD simulations and the potential and the limitations of “near field photography” by local ablation and melting for the mapping of complex plasmon fields and their applications

Femtosecond-resolved ablation dynamics of Si in the near field of a small dielectric particle

• Paul Kühler,
• Daniel Puerto,
• Mario Mosbacher,
• Paul Leiderer,
• Francisco Javier Garcia de Abajo,
• Jan Siegel and
• Javier Solis

Beilstein J. Nanotechnol. 2013, 4, 501–509, doi:10.3762/bjnano.4.59

• “Rocasolano”, CSIC, Serrano 119, 28006 Madrid, Spain 10.3762/bjnano.4.59 Abstract In this work we analyze the ablation dynamics of crystalline Si in the intense near field generated by a small dielectric particle located at the material surface when being irradiated with an infrared femtosecond laser pulse

• span from 0.1 ps to about 1 ns. Characteristic phenomena like electron plasma formation, ultrafast melting and ablation, along with their characteristic time scales are observed in the region surrounding the particle. The use of a time resolved imaging technique allows us recording simultaneously the

• material response at ordinary and large peak power densities enabling a direct comparison between both scenarios. The time resolved images of near field exposed regions are consistent with a remarkable temporal shift of the ablation onset which occurs in the sub-picosend regime, from about 500 to 800 fs

Structural and thermoelectric properties of TMGa₃ (TM = Fe, Co) thin films

• Sebastian Schnurr,
• Ulf Wiedwald,
• Paul Ziemann,
• Valeriy Y. Verchenko and
• Andrei V. Shevelkov

Beilstein J. Nanotechnol. 2013, 4, 461–466, doi:10.3762/bjnano.4.54

• purpose. However, it turned out that the pressed targets were not sufficiently stable but rather mechanically disintegrated during the ablation process. Thus, alternatively, thermal grain-by-grain evaporation from a powder source was applied leading to an averaging of the chemical composition over the

Hydrogen-plasma-induced magnetocrystalline anisotropy ordering in self-assembled magnetic nanoparticle monolayers

• Alexander Weddemann,
• Judith Meyer,
• Anna Regtmeier,
• Irina Janzen,
• Dieter Akemeier and
• Andreas Hütten

Beilstein J. Nanotechnol. 2013, 4, 164–172, doi:10.3762/bjnano.4.16

• with a FEI Helios Dual Beam FIB by cutting through a suitable particle agglomeration. The lamella was subsequently thinned down to a thickness of 20 nm. In order to protect the particles from contamination and possible ablation by gallium ions, an additional thin protective layer of platinum was

• wafer. Particles on top of the substrate (blue) are covered by a thin layer of Pt of approximately 15 nm thickness (green), to prevent oxidation, and an additional 15 nm Pt layer (bright green) deposited before cutting the lamella, to protect the sample from ablation by gallium ions. During the

Functionalization of vertically aligned carbon nanotubes

• Eloise Van Hooijdonk,
• Carla Bittencourt,
• Rony Snyders and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2013, 4, 129–152, doi:10.3762/bjnano.4.14

• were the synthesis on a large scale, the reproducibility, and the control of the diameter and number of walls of the CNTs using different synthesis techniques such as arc discharge, laser ablation or chemical vapor deposition. After these issues had been addressed, the focus in carbon nanotube research

• synthesize non-aligned CNTs, such as chemical vapor deposition (CVD), electrical arc discharge, or laser ablation, CVD has been reported to be the best for the synthesis of VA-CNTs. Different versions of CVD for the synthesis of VA-CNTs have been used, which can be mainly divided in two types: those

Diamond nanophotonics

• Katja Beha,
• Helmut Fedder,
• Marco Wolfer,
• Merle C. Becker,
• Petr Siyushev,
• Mohammad Jamali,
• Anton Batalov,
• Christopher Hinz,
• Jakob Hees,
• Lutz Kirste,
• Harald Obloh,
• Etienne Gheeraert,
• Boris Naydenov,
• Ingmar Jakobi,
• Florian Dolde,
• Sébastien Pezzagna,
• Daniel Twittchen,
• Matthew Markham,
• Daniel Dregely,
• Harald Giessen,
• Jan Meijer,
• Fedor Jelezko,
• Christoph E. Nebel,
• Rudolf Bratschitsch,
• Alfred Leitenstorfer and
• Jörg Wrachtrup

Beilstein J. Nanotechnol. 2012, 3, 895–908, doi:10.3762/bjnano.3.100

• additional refraction for the emitted fluorescence light. The ringlike ablation material at the bottom of the SIL lies within a spatial angle that is not detected by the high NA microscope objective of 0.95. With such a microscopic diamond hemisphere, fluorescence count rates up to about 480 kHz were

Characterization and properties of micro- and nanowires of controlled size, composition, and geometry fabricated by electrodeposition and ion-track technology

• Maria Eugenia Toimil-Molares

Beilstein J. Nanotechnol. 2012, 3, 860–883, doi:10.3762/bjnano.3.97

• deposition, laser ablation, or thermal evaporation. The first template-grown nanowires of amorphous Si were recently reported by using ionic liquids [100][101]. Ionic liquids have proved to be a good alternative electrolyte to fabricate materials such as Al, Ti, Si, or Ge, which cannot be electrodeposited in

Tuning the properties of magnetic thin films by interaction with periodic nanostructures

• Ulf Wiedwald,
• Felix Haering,
• Stefan Nau,
• Carsten Schulze,
• Herbert Schletter,
• Denys Makarov,
• Alfred Plettl,
• Karsten Kuepper,
• Manfred Albrecht,
• Johannes Boneberg and
• Paul Ziemann

Beilstein J. Nanotechnol. 2012, 3, 831–842, doi:10.3762/bjnano.3.93

• . After the preparation of the non-close-packed PS nanostructure, subsequent growth of magnetic films can be carried out in standard deposition chambers under ultrahigh-vacuum conditions. The percolated magnetic films discussed below were deposited either by pulsed laser ablation (Fe films) or e-beam

Influence of the diameter of single-walled carbon nanotube bundles on the optoelectronic performance of dry-deposited thin films

• Kimmo Mustonen,
• Toma Susi,
• Antti Kaskela,
• Patrik Laiho,
• Ying Tian,
• Albert G. Nasibulin and
• Esko I. Kauppinen

Beilstein J. Nanotechnol. 2012, 3, 692–702, doi:10.3762/bjnano.3.79

• sample-preparation routes. For example, Hecht et al. induced mechanical damage to liquid-suspended SWCNT bundles synthesized with the arc discharge and laser ablation methods, and were thus able to control the bundle lengths and diameters to some extent [14]. Geng et al. conducted a more thorough

• comparison between the performances of SWCNT networks from chemical vapor deposition (CVD), HiPCO, laser ablation, and arc discharge sources; although, again involving liquid suspensions [15]. While these initial studies have been steps in the right direction, the damage induced by sample preparation and the

Assessing the plasmonics of gold nano-triangles with higher order laser modes

• Laura E. Hennemann,
• Andreas Kolloch,
• Andreas Kern,
• Josip Mihaljevic,
• Johannes Boneberg,
• Paul Leiderer,
• Alfred J. Meixner and
• Dai Zhang

Beilstein J. Nanotechnol. 2012, 3, 674–683, doi:10.3762/bjnano.3.77

• ], photopolymerisation [6] and near-field ablation [3][10][11] have been performed. It was found that the material of the triangles plays a distinct role [9], as do the triangles' edge length and height [3][8][10][11] and the material of the underlying substrate [12]. Additionally, nano-particles and nano-particle

Synthesis and electrical characterization of intrinsic and in situ doped Si nanowires using a novel precursor

• Wolfgang Molnar,
• Alois Lugstein,
• Tomasz Wojcik,
• Peter Pongratz,
• Norbert Auner,
• Christian Bauch and
• Emmerich Bertagnolli

Beilstein J. Nanotechnol. 2012, 3, 564–569, doi:10.3762/bjnano.3.65

• achieve NWs with tailored properties, namely chemical vapor deposition (CVD) [11], metal–organic CVD [12], molecular-beam epitaxy [13] and laser ablation techniques [14]. In this work we focus on the well-established VLS growth mechanism [15][16], which has shown remarkable potential in the fabrication of

Directed deposition of silicon nanowires using neopentasilane as precursor and gold as catalyst

• Britta Kämpken,
• Verena Wulf,
• Norbert Auner,
• Marcel Winhold,
• Michael Huth,
• Daniel Rhinow and
• Andreas Terfort

Beilstein J. Nanotechnol. 2012, 3, 535–545, doi:10.3762/bjnano.3.62

• nanosized wires (NW) of silicon including thermal evaporation [9], molecular beam epitaxy [10], laser ablation [11], chemical vapor deposition (CVD) [12] and CVD in combination with the vapor–liquid–solid (VLS) method [13]. In the VLS mechanism, small solid metal particles catalyze the decomposition of the

Substrate-mediated effects in photothermal patterning of alkanethiol self-assembled monolayers with microfocused continuous-wave lasers

• Anja Schröter,
• Mark Kalus and
• Nils Hartmann

Beilstein J. Nanotechnol. 2012, 3, 65–74, doi:10.3762/bjnano.3.8

• complications, such as surface melting and substrate ablation. Hence, the procedure has to be carefully optimized in order to ensure selective processing of the SAM [11][24]. Calculated surface-coverage profiles at a typical laser pulse length of τ = 1 ms are displayed in Figure 7. Clearly, an increase in the

Nanoscaled alloy formation from self-assembled elemental Co nanoparticles on top of Pt films

• Luyang Han,
• Ulf Wiedwald,
• Johannes Biskupek,
• Kai Fauth,
• Ute Kaiser and
• Paul Ziemann

Beilstein J. Nanotechnol. 2011, 2, 473–485, doi:10.3762/bjnano.2.51

• ) substrates fixed at a distance of 30 mm from the target. To reduce particulate formation, the target was rotated as well as periodically tilted during the ablation process. To allow calibration of the deposition rate, a movable quartz crystal monitor can be placed at exactly the substrate position. More

• details on the PLD apparatus, including its UHV chamber, are given in [22][23]. By monitoring the deposition rate as a function of the laser power, an ablation threshold of 2.5 J/cm2 was determined for Pt. Standard deposition was performed at 5 J/cm2 resulting in a Pt deposition rate of 1 nm/min. Standard

Zirconium nanoparticles prepared by the reduction of zirconium oxide using the RAPET method

• Michal Eshed,
• Swati Pol,
• Aharon Gedanken and
• Mahalingam Balasubramanian

Beilstein J. Nanotechnol. 2011, 2, 198–203, doi:10.3762/bjnano.2.23

• production of metallic zirconium is the Kroll process [6]. In this reaction zirconium is produced by the reduction of zirconium tetrachloride with an active metal such as magnesium at 800–900 °C. Elsewhere in the literature, the preparation of metallic Zr nanoparticles by ultrafast laser ablation of a

• zirconium rod in isopropyl alcohol has been described [7]. This process produces a colloidal solution of zirconium nanoparticles. Moreover, it was shown that the size distribution of nanoparticles can be greatly reduced by employing femtosecond laser pulses for ablation. A plasma induced cathodic discharge

Room temperature synthesis of indium tin oxide nanotubes with high precision wall thickness by electroless deposition

• Mario Boehme,
• Emanuel Ionescu,
• Ganhua Fu and
• Wolfgang Ensinger

Beilstein J. Nanotechnol. 2011, 2, 119–126, doi:10.3762/bjnano.2.14

• development of applications in optoelectronics, sensors and biomedical sciences [4][5][6]. Miscellaneous methods for the fabrication of ITO nanostructures, such as the post calcination method [7], alkaline hydrolysis [8] or pulsed laser ablation [9] have been developed and used. For fabricating metal

Flash laser annealing for controlling size and shape of magnetic alloy nanoparticles

• Damien Alloyeau,
• Christian Ricolleau,
• Cyril Langlois,
• Yann Le Bouar and
• Annick Loiseau

Beilstein J. Nanotechnol. 2010, 1, 55–59, doi:10.3762/bjnano.1.7

• samples, a 3 nm-thick layer of a-Al2O3 was deposited over the NPs to protect them from air oxidation. After the synthesis, the sample was irradiated by using the same laser as the one used for the PLD experiment. A pulse frequency of 1 Hz was used and the laser energy was chosen well below the ablation