In situ magnesiothermic reduction synthesis of a Ge@C composite for high-performance lithium-ion batterie anodes

• Ha Tran Huu,
• Ngoc Phi Nguyen,
• Vuong Hoang Ngo,
• Huy Hoang Luc,
• Minh Kha Le,
• Minh Thu Nguyen,
• My Loan Phung Le,
• Hye Rim Kim,
• In Young Kim,
• Sung Jin Kim,
• Van Man Tran and
• Vien Vo

Beilstein J. Nanotechnol. 2023, 14, 751–761, doi:10.3762/bjnano.14.62

• , then placed in a ceramic crucible and heated to 800 °C for 5 h under argon gas flow with a heating rate of 10 °C·min−1. The obtained solid was washed with potassium hydroxide solution (KOH 20%) at 70 °C for 2 h, then leached with 2 M HCl at 70 °C for 15 h and washed several times with de-ionized (DI

• mixture of germanium dioxide, magnesium, and activated carbon at a mass ratio of 5:4:10, was ground well and transferred into a ceramic crucible. The solid was heated to 750 °C under Ar gas flow for 3 h. The obtained powder was rinsed with 1 M HCl to remove by-products. The sample, obtained after rinsing

• and transferred to a ceramic crucible. The mixture was heated at 750 °C in argon gas flow for 3 h. The obtained solid was re-ground and denoted as Ge/C-SS750. Material characterization X-ray diffraction measurements (XRD, Bruker D8 Advance with Cu Kα radiation (λ = 1.5406 Å) at 40 kV and 40 mA) were

Control of morphology and crystallinity of CNTs in flame synthesis with one-dimensional reaction zone

• Muhammad Hilmi Ibrahim,
• Norikhwan Hamzah,
• Mohd Zamri Mohd Yusop,
• Ni Luh Wulan Septiani and
• Mohd Fairus Mohd Yasin

Beilstein J. Nanotechnol. 2023, 14, 741–750, doi:10.3762/bjnano.14.61

• Muhammad Hilmi Ibrahim Norikhwan Hamzah Mohd Zamri Mohd Yusop Ni Luh Wulan Septiani Mohd Fairus Mohd Yasin Department of Thermo-Fluids, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru, Malaysia High Speed Reacting Flow Laboratory (HiREF), Universiti Teknologi

• flame is conducted regarding the morphology and crystallinity of the as-grown nanotubes. The premixed burner configuration created a flame that is stabilized through axisymmetric stagnation flow through sintered metal with one-dimensional geometry, different from a conventional co-flow flame. The

• ratio was also shown in another study by Hamzah et al. [13], utilizing a methane diffusion flame with different air flow rates. This study aims to synthesize CNTs on nickel wire through methane combustion in a one-dimensional premixed flat flame. The resulting CNT morphology and crystallinity will be

Nanoarchitectonics for advanced applications in energy, environment and biology: Method for everything in materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 738–740, doi:10.3762/bjnano.14.60

• instance. Katsuhiko Ariga Tsukuba, June 2023 Historical flow to bridge nanotechnology amd materials science.

Cross-sectional Kelvin probe force microscopy on III–V epitaxial multilayer stacks: challenges and perspectives

• Mattia da Lisca,
• José Alvarez,
• James P. Connolly,
• Nicolas Vaissiere,
• Karim Mekhazni,
• Jean Decobert and
• Jean-Paul Kleider

Beilstein J. Nanotechnol. 2023, 14, 725–737, doi:10.3762/bjnano.14.59

• ), and arsine (AsH3) were the source materials, with hydrogen (H2) as a carrier gas. Diethylzinc (DEZn) was used as a source of Zn for p-type doping the InP:Zn and the phosphorus-based quaternary (GaInAsP:Zn) and GaInAs:Zn layers. The precursor flow was varied to cover a doping level range from 1 × 1018

• ]. As illustrated in Figure 8, in the case of downward surface band bending in an p-type semiconductor, photogenerated holes are repelled from the surface, while photogenerated electrons flow in the direction of the surface, balancing the positive charges corresponding to empty donor-type surface states

• . This results in a reduction of surface band bending and a decrease of surface potential, that is, a negative SPV. Conversely, in the case of upward surface band bending in an n-type semiconductor, photogenerated electrons are repelled from the surface, while photogenerated holes flow towards the

Current-induced mechanical torque in chiral molecular rotors

• Richard Korytár and
• Ferdinand Evers

Beilstein J. Nanotechnol. 2023, 14, 711–721, doi:10.3762/bjnano.14.57

• qualitative description of the current-induced mechanical torque within a toy model framework. We consider a classical model of the molecular rotor where the molecule is modeled as a one-dimensional curve (“molecular wire”) that guides the flow of the charge carriers (see Figure 1 (left) for illustration

• fulfilled. First, the rotor’s velocity must be attenuated for the rotor to settle in the nearest potential minimum. Second, the current must flow in controlled short pulses. The optimal parameter regime can be sought using the EOM (Equation 22 and Equation 23), which is beyond the scope of the present work

Humidity-dependent electrical performance of CuO nanowire networks studied by electrochemical impedance spectroscopy

• Jelena Kosmaca,
• Juris Katkevics,
• Jana Andzane,
• Raitis Sondors,
• Liga Jasulaneca,
• Raimonds Meija,
• Kiryl Niherysh,
• Yelyzaveta Rublova and
• Donats Erts

Beilstein J. Nanotechnol. 2023, 14, 683–691, doi:10.3762/bjnano.14.54

• frequencies below 1 Hz, representing the ability of the sample to impede the flow of current between cathodic and anodic areas, equal to ca. 1 × 1010 Ω. When the RH is higher than 50%, the impedance modules at low f decrease by up to three orders of magnitude, and the log Z curves show a linear dependence on

• electron microscopy (SEM, Hitachi S4800) and atomic force microscopy (AFM, Asylum Research MFP-3D). Electrochemical impedance measurements were performed under various atmospheric conditions in a custom-made system described elsewhere [28]. The main system parameters were RH from 4% to 97%, gas flow from

Investigations on the optical forces from three mainstream optical resonances in all-dielectric nanostructure arrays

• Guangdong Wang and
• Zhanghua Han

Beilstein J. Nanotechnol. 2023, 14, 674–682, doi:10.3762/bjnano.14.53

• continuum (BIC)) which are current in focus nanophotonics research topics, all-dielectric nanostructures have proved themselves to be a good platform for light–matter interactions and an advantageous alternative to their plasmonic counterparts. A TD resonance is produced by the flow of electric currents on

Titania nanoparticles for photocatalytic degradation of ethanol under simulated solar light

• Evghenii Goncearenco,
• Iuliana P. Morjan,
• Claudiu Teodor Fleaca,
• Florian Dumitrache,
• Elena Dutu,
• Monica Scarisoreanu,
• Valentin Serban Teodorescu,
• Alexandra Sandulescu,
• Crina Anastasescu and
• Ioan Balint

Beilstein J. Nanotechnol. 2023, 14, 616–630, doi:10.3762/bjnano.14.51

• productivity, which are in some cases extremely low compared to a continuous flow method such as laser pyrolysis which, in the case of the studied powders, allows for a productivity of 1 g/h with the possibility of upscaling to an industrial level by increasing the reaction area. Another point is to find the

• is TO-250-a, that is, the sample synthesized at the lowest pressure and in the presence of the highest C2H4 sensitizer flow (120 sccm). Here, the rutile crystal structure is the main constituent. The crystallite size increases for both phases from 14 nm and 11 nm to 22 nm for anatase and rutile

• crystalline phase and rutile being a minor fraction. An exception to this is the sample synthesized at the lowest pressure without supplementary air flow. Two series of samples were tested in ethanol photodegradation experiments, observing that all samples from series “a” have a higher photocatalytic activity

Suspension feeding in Copepoda (Crustacea) – a numerical model of setae acting in concert

• Alexander E. Filippov,
• Wencke Krings and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2023, 14, 603–615, doi:10.3762/bjnano.14.50

• described as filtering or sieving with, for example, setae, cilia, or mucous nets, and is present in form of passive or active suspension feeding. Passive feeders rely on external water currents that bring food particles to the filtering structures and active feeders create a feeding flow by pumping systems

• . The second mechanism involves structures manipulating the water flow (e.g., setae and tentacles) that redirect the food particles and lead them to specialized structures that contact and capture them. A good example for the latter mechanism are the filtering setae of crustaceans (for in-depth reviews

• adhesive forces to retain particles. In contrast to organisms, which collect particles at the nano- to millimeter scale, most industrial cross-flow filtration systems can capture material only in more limited size ranges, highlighting the necessity to investigate particle retention in biological systems

Thermal transport in kinked nanowires through simulation

• Alexander N. Robillard,
• Graham W. Gibson and
• Ralf Meyer

Beilstein J. Nanotechnol. 2023, 14, 586–602, doi:10.3762/bjnano.14.49

• phonon reflection specularity on the heat flux is also examined. It is found that, in general, the flow of heat through systems simulated through phonon Monte Carlo methods is concentrated into a channel smaller than the wire dimensions, while this is not the case in the classical solutions of the

• increase with increasing kink angle. With the scattering rate becoming large, and consequently the mean free path of phonons becoming short, the effect of scattering off surfaces becomes negligible, and the heat flow becomes more diffusive (it is also reduced in magnitude due to overall reduced transport

• small “shortcuts” that the heat flow can use to reduce its effective path length, much like a race-car driver taking the inside corners of a series of curves. This corner cutting has been seen and discussed previously in the context of right-angled serpentine nanowires [20][22][30]. To reiterate a point

Carbon nanotube-cellulose ink for rapid solvent identification

• Tiago Amarante,
• Thiago H. R. Cunha,
• Claudio Laudares,
• Ana P. M. Barboza,
• Ana Carolina dos Santos,
• Cíntia L. Pereira,
• Vinicius Ornelas,
• Bernardo R. A. Neves,
• André S. Ferlauto and
• Rodrigo G. Lacerda

Beilstein J. Nanotechnol. 2023, 14, 535–543, doi:10.3762/bjnano.14.44

• two important properties of the liquids, namely dielectric constant and vapor pressure, on the transduction of the MFC-MWCNT sensors. These results were corroborated by independent heat flow measurements (thermogravimetric analysis). The proposed MFC-MWCNT sensor platform may help paving the way to

• contact mode. AC160TS silicon cantilevers from Olympus with a typical spring constant of k ≈ 46 N/m, a nominal radius of curvature of r ≈ 7 nm, and a resonant frequency of ω0 ≈ 300 kHz were employed. Heat flow and weight changes of selected solvents were determined by thermogravimetric analysis (TGA

• produced by the impinging liquid drops over the heated surface of the transducer. The temperature change and the heat flow produced by the liquid as it gets in contact with the heated surface were estimated by dripping a liquid (of about 6.5 µL) into an empty crucible kept at 55 °C inside a

Nanoarchitectonics to entrap living cells in silica-based systems: encapsulations with yolk–shell and sepiolite nanomaterials

• Celia Martín-Morales,
• Jorge Fernández-Méndez,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2023, 14, 522–534, doi:10.3762/bjnano.14.43

• , fresh yeast). All employed materials and equipment have been sterilized by heating to 120 °C for 25 min and subsequent cool down to room temperature within the autoclave chamber. All culture handling operations have been performed within a sterile laminar flow hood, which before and after its usage had

A mid-infrared focusing grating coupler with a single circular arc element based on germanium on silicon

• Xiaojun Zhu,
• Shuai Li,
• Ang Sun,
• Yongquan Pan,
• Wen Liu,
• Yue Wu,
• Guoan Zhang and
• Yuechun Shi

Beilstein J. Nanotechnol. 2023, 14, 478–484, doi:10.3762/bjnano.14.38

• membrane Ge waveguide [1]. The maximum coupling efficiency was −11 dB at the focusing SWG’s center wavelength of 2.37 μm. The high coupling efficiency was obtained experimentally. However, the fabrication flow of the suspended membrane Ge waveguide with focusing SWGs greatly increased the complexity of the

The steep road to nonviral nanomedicines: Frequent challenges and culprits in designing nanoparticles for gene therapy

• Yao Yao,
• Yeongun Ko,
• Grant Grasman,
• Jeffery E. Raymond and
• Joerg Lahann

Beilstein J. Nanotechnol. 2023, 14, 351–361, doi:10.3762/bjnano.14.30

• are assessed with the use of fluorescent-labeling carriers and the expression of fluorescent proteins (e.g., enhanced green fluorescent protein). Both of which are typically assessed by widefield fluorescent microscopy/confocal microscopy (referred to as “imaging”) and/or flow cytometry (Table 1

• after image capture (26%, Figure 1a2). Flow cytometry, also a fluorescence-based method, is an alternate assessment of uptake and transfection. It is commonly used for high-throughput cell studies and is known for both rapid data acquisition and large data sets [17]. Flow cytometry can generate large

• papers, Figure 1b). Despite the robust data it can provide, flow cytometry counts the total number of cells associated with NPs and cannot distinguish internalized cargo from surface-bound NPs [1][17]. To precisely quantify internalization, a secondary method is required that can differentiate between

Overview of mechanism and consequences of endothelial leakiness caused by metal and polymeric nanoparticles

• Magdalena Lasak and
• Karol Ciepluch

Beilstein J. Nanotechnol. 2023, 14, 329–338, doi:10.3762/bjnano.14.28

• vasoconstrictions factors (e.g., thromboxane, prostaglandin, and endothelin-1), regulating vessel tension and, thus, blood flow and pressure [4][5][6][7][8]. The endothelium also produces mediators involved in angiogenic processes (e.g., vascular endothelial growth factor (VEGF) and fibroblast growth factor (FGF

• nutrient molecules to NPs could change the toxicity of NPs (NP protein corona), and the physiological conditions, such as blood flow and physiological stretch, will also play a role [37][38][39]. NanoEL mechanism Adherens junctions between endothelial cells are maintained by a complex set of proteins

• EPR effect, but transport strictly depends on the stage of the tumor. Hence, the use of the EPR effect may be justified only in the case of mature tumors. Moreover, leaky vessels and heterogeneous blood flow limit its use for therapeutic purposes. By contrast, NanoEL is a mechanism completely

Biocatalytic synthesis and ordered self-assembly of silica nanoparticles via a silica-binding peptide

• Mustafa Gungormus

Beilstein J. Nanotechnol. 2023, 14, 280–290, doi:10.3762/bjnano.14.25

• molecular crowding-like effects, preventing efficient assembly of the particles. Therefore, tailoring intermolecular interactions between nanoparticles by modifying the particle surfaces or through external influences such as temperature, pH value, templates, and magnetic or flow fields, is important to

• –MS analyses were done with a fused silica capillary column a (Restek 14623, Thermo Fischer Scientific Inc, Waltham, MA, USA), 150 °C injection temperature, 250 °C detection temperature, 1 µL injection volume, and 1 mL/min He flow rate. Dionex Chromeleon 7.2 software (Thermo Fischer Scientific Inc

Spin dynamics in superconductor/ferromagnetic insulator hybrid structures with precessing magnetization

• Yaroslav V. Turkin and
• Nataliya Pugach

Beilstein J. Nanotechnol. 2023, 14, 233–239, doi:10.3762/bjnano.14.22

• proximity effect”. Distributions of spin current and induced magnetization were calculated in recent works [20][21], where the authors investigate spin current flow through Josephson-like trilayer structures. The proximity effect is the penetration of superconducting correlations in an adjacent

• proximity effect. The spin current can be induced only by the nonstationary flow of triplet Cooper pairs, just as in a conventional spin-pumping bilayer structure with a normal metal [33]. Thus, spin currents cannot emerge when the magnetization is stationary inside the ferromagnetic insulator layer

A novel approach to pulsed laser deposition of platinum catalyst on carbon particles for use in polymer electrolyte membrane fuel cells

• Bogusław Budner,
• Wojciech Tokarz,
• Sławomir Dyjak,
• Andrzej Czerwiński,
• Bartosz Bartosewicz and
• Bartłomiej Jankiewicz

Beilstein J. Nanotechnol. 2023, 14, 190–204, doi:10.3762/bjnano.14.19

• the catalytic and diffusion layers. The microscopic water droplets must leave the MEA and the cell, but in some cases, they are temporarily trapped in the diffusion layer or the flow fields. The presence of water results in a temporary decrease of the current due to the transport resistance increase

• of 20% Pt Vulcan XC-72R catalyst, while the anode was made of 20% Pt HiSpec 3000 catalyst. MEA tests were carried out on a single-cell fuel cell assembly with a single serpentine flow field on both electrodes. The assembled cells were fed with ambient air supplied by an oil-free compressor and H2 5.0

A distributed active patch antenna model of a Josephson oscillator

• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2023, 14, 151–164, doi:10.3762/bjnano.14.16

• ; Introduction A flux-flow oscillator (FFO) is the most extensively studied Josephson source of high-frequency electromagnetic waves (EMW) [1][2][3][4][5][6][7][8][9][10][11][12]. A FFO was used in the first direct demonstration of Josephson emission by Yanson et al., back in 1965 [13][14]. State of the art FFOs

• and the flux-flow phenomenon. Therefore, a JJ can be considered as an actively pumped patch antenna with a distributed feed-in current. In this work, I present a distributed, active patch antenna model of a Josephson oscillator. It expands the TL model of a patch antenna [36], taking into account the

• and the flux-flow phenomenon. (iii) The slow propagation speed of EMWs inside the JJ, c0 ≪ c. This is caused by a large kinetic inductance of superconducting electrodes. For Nb-based JJs, c/c0 ≈ 40 (see the estimation in section Discussion). For atomic-scale intrinsic JJs in layered cuprates, c0 can

Batch preparation of nanofibers containing nanoparticles by an electrospinning device with multiple air inlets

• Dong Wei,
• Chengwei Ye,
• Adnan Ahmed and
• Lan Xu

Beilstein J. Nanotechnol. 2023, 14, 141–150, doi:10.3762/bjnano.14.15

• that under the appropriate voltage (50 kV) and air flow (50 m3/h), the device could keep ZnO nanoparticles contained in the spinning solution evenly dispersed during the spinning process, thus obtaining functional nanofibers with more uniform distribution of ZnO nanoparticles, whose quality and yield

• enabled the ZnO nanoparticles contained in the spinning solution to maintain uniform dispersion in the batch preparation process of nanofibers by means of air flow produced through multiple pores. The airflow reduces the agglomeration of nanoparticles, thus yielding nanofibers with uniform ZnO loading. In

• experiments were performed at 25 °C and 60% relative humidity. The following MEAI parameters were used. The receiving distance was 18 cm, the speed of the receiving drum was 300 r/min, the air flow rates were 0, 50, 100, and 150 m3/h, and the spinning voltages were 40, 50, and 60 kV. Measurement and

Formation of nanoflowers: Au and Ni silicide cores surrounded by SiO_x branches

• Feitao Li,
• Siyao Wan,
• Dong Wang and
• Peter Schaaf

Beilstein J. Nanotechnol. 2023, 14, 133–140, doi:10.3762/bjnano.14.14

• out in a rapid thermal processing (RTP, Jipelec Jetstar 100) furnace. First, the chamber was evacuated and purged with Ar three times at room temperature, then a flow of forming gas of Ar + H2 (volume ratio 30:1) was kept till the end of the experiment. The temperature was ramped up to 300 °C in 20 s

Characterisation of a micrometer-scale active plasmonic element by means of complementary computational and experimental methods

• Ciarán Barron,
• Giulia Di Fazio,
• Samuel Kenny,
• Silas O’Toole,
• Robin O’Reilly and
• Dominic Zerulla

Beilstein J. Nanotechnol. 2023, 14, 110–122, doi:10.3762/bjnano.14.12

• scanning. While leaving the probe floating is counterproductive from the perspective of minimising electrostatic interaction, the possibility of current flow through the tip to ground is eliminated. As with the LIA phase selection for the SPR measurements discussed above, the phase was selected so as to

• effect. The presence of a constriction in the metal (the bridge) results in a localised heating effect. A schematic of the enhanced SPR experiment. Schematic describing the experimental setup used to perform SJEM measurements on a modulated element. Flow diagram of simulation process. FEM optical

Frontiers of nanoelectronics: intrinsic Josephson effect and prospects of superconducting spintronics

• Anatolie S. Sidorenko,
• Horst Hahn and
• Vladimir Krasnov

Beilstein J. Nanotechnol. 2023, 14, 79–82, doi:10.3762/bjnano.14.9

• : artificial neural networks; functional nanostructures; intrinsic Josephson effect; nanoelectronics; spintronics; The twenty-first century is marked by an explosive growth in the flow of information, which is necessary to process, archive, and transmit data through communication systems. For that purpose

Gap-directed chemical lift-off lithographic nanoarchitectonics for arbitrary sub-micrometer patterning

• Chang-Ming Wang,
• Hong-Sheng Chan,
• Chia-Li Liao,
• Che-Wei Chang and
• Wei-Ssu Liao

Beilstein J. Nanotechnol. 2023, 14, 34–44, doi:10.3762/bjnano.14.4

• , sequentially rinsed with acetone and isopropanol, and blown dry with nitrogen gas. To conduct CLL processes, a PDMS stamp was activated by 30 s of oxygen plasma exposure at a power of 18 W with 0.5 mbar oxygen flow. The stamp was then conformally sealed onto the SAM-modified Au substrate for 2 h under ambient

Atmospheric water harvesting using functionalized carbon nanocones

• Fernanda R. Leivas and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2023, 14, 1–10, doi:10.3762/bjnano.14.1

• occurs due to the presence of hydrophilic sites at the nanocone entrance. The functionalization, together with the high mobility of water inside nanostructures, leads to a fast water flow through the nanostructure. We show using molecular dynamics simulations that this device is able to collect water if

• addition to the hydrophobicity described above. The phenomena of density increasing with temperature at constant pressure and diffusion coefficients increasing with density at constant temperature were observed in experiments and simulations in bulk water [22][23][24]. Water presents both super flow and

• slowing down when confined in biological structures with the presence of hydrophobic and hydrophilic sites [25]. Water confined in hydrophobic structures, such as carbon nanotubes with diameters below 2 nm, exhibits a fast flow that exceeds values provided by classical hydrodynamics [26]. This super flow