Bending and punching characteristics of aluminum sheets using the quasi-continuum method

• Man-Ping Chang,
• Shang-Jui Lin and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2022, 13, 1303–1315, doi:10.3762/bjnano.13.108

• of the coupled regions [54]. Results and Discussion In this section, the QC method was used to explore the effects of different crystal orientations, workpiece thickness, clearance, and taper angle on the nano-punching process. The friction characteristic of interface and residual flash phenomena

• unloading curves shown in Figure 2, it can be found that there is a slight oscillation in the O2 and O3 curves, especially in the O2 curve, which means that the residual flash exists on the interface between the punch and both sides of the substrate. By contrast, there is no oscillation in the unloading

• curve of O1, which indicates that the unloading process of O1 was less affected by the residual flash. Therefore, the result confirms that there is almost no residual flash on the interface of the O1 orientation. Further, the fracture strength values of O1, O2, and O3 were 0.138, 0.324, and 0.133 GPa

Enhanced electronic transport properties of Te roll-like nanostructures

• E. R. Viana,
• N. Cifuentes and
• J. C. González

Beilstein J. Nanotechnol. 2022, 13, 1284–1291, doi:10.3762/bjnano.13.106

• vacuum, εav = 1.95 is the averaged relative permittivity of the SiO2/air interface of the FET [19][29]. Also, w = 550 nm, t = 50 nm, and L = 5.97 µm are the diameter of the nanostructure, the thickness of the nanostructure, and the length of the FET channel, respectively. The thickness of the dielectric

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• ion is used as the transition ion and the sodium ion is used as the fixed cation, the output performance of the device does not change much. These experimental results show that in nanochannels, only specific ions can interact with the channel material interface to convert their own flow potential

• . However, after the solid–liquid contact, the research on the principle of the selective interaction of ions at the solid interface is still not comprehensive and systematic. And more experimental work is needed to complement and prove it. In 2014, Zhu et al. fabricated a nanowire fluorinated ethylene

• Elsevier (2017). This content is not subject to CC BY 4.0. d) The device is designed through the interface to increase the output power. (e) Voltage and current output of the device. (f) Device configurations with different electrode designs. (g, h) Voltage and current output of three generators with

Recent advances in green carbon dots (2015–2022): synthesis, metal ion sensing, and biological applications

• Aisha Kanwal,
• Naheed Bibi,
• Sajjad Hyder,
• Arif Muhammad,
• Hao Ren,
• Jiangtao Liu and
• Zhongli Lei

Beilstein J. Nanotechnol. 2022, 13, 1068–1107, doi:10.3762/bjnano.13.93

Biomimetic chitosan with biocomposite nanomaterials for bone tissue repair and regeneration

• Se-Kwon Kim,
• Sesha Subramanian Murugan,
• Pandurang Appana Dalavi,
• Sebanti Gupta,
• Sukumaran Anil,
• Gi Hun Seong and
• Jayachandran Venkatesan

Beilstein J. Nanotechnol. 2022, 13, 1051–1067, doi:10.3762/bjnano.13.92

• computed tomography (CT) scan radiographs which show good bone lodging in all implants. There are noticeable holes at the hydroxyapatite implant interface. Ag–Si hydroxyapatite implants, on the other hand, have a smooth contact between the host bone and the implant. Acemannan and chitosan coatings have

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• ). Figure 3d shows an HRTEM image of BOM-20 composites. The lattice fringes of 0.37 nm correspond to the (120) facet of α-Bi2O3 [55]. Meanwhile, the tight contact interface between Bi2O3 and MIL101(Fe) can be clearly observed. Furthermore, the elemental mapping images of BOM-20 (Figure 3e–h) reveal the

• suggests that the formation of the heterojunction can promote charge transfer on the interface between MIL101(Fe) and Bi2O3. Furthermore, the interfacial charge transfer behavior of the BOM-20 composite is also confirmed by EIS. In Figure 5d, BOM-20 exhibits the smallest arc radius, meaning that BOM-20

• possesses the lowest resistance and the highest separation rate of electron–hole pairs on the interface of MIL101(Fe) and Bi2O3 [57], which is consistent with the results from PL spectra and photocurrent analysis. In summary, PL spectra, photocurrent responses, and EIS analysis all indicated that Bi2O3

Analytical and numerical design of a hybrid Fabry–Perot plano-concave microcavity for hexagonal boron nitride

• Felipe Ortiz-Huerta and
• Karina Garay-Palmett

Beilstein J. Nanotechnol. 2022, 13, 1030–1037, doi:10.3762/bjnano.13.90

• known as the q-parameters for the Gaussian beams, where z2 = L2 − Lp, z1 = L1 and zR,1,2 is the Rayleigh length for each beam. For a Gaussian beam passing through a plane dielectric interface, we have A = B = C = 0, and D = n2/n1, where n1 = 1 is the refractive index of the air gap, therefore, by

• substituting in Equation 3, q2 = (n2/n1)q1. This leads to z2 = (n2/n1)z1 and W01 = W02. Finally, by defining ∆z = z2 − z1 we get: As a threshold for R2 we set R2 ≥ L2 in accordance with the stability range where 0 ≤ g ≤ 1. Although work has been done to include the lensing effect of a curved “n1/n2” interface

• + DBR system a L(HL)15 dielectric stack. A transfer matrix model [24] was used to calculate the electric field distribution inside the hBN + DBR system (Figure 6). The full transfer matrix S of our microcavity is defined as: where L and I represent the transfer and interface matrix, respectively, of the

Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media

• Iyyappan Madakannu,
• Indrajit Patil,
• Bhalchandra Kakade and
• Kasibhatta Kumara Ramanatha Datta

Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89

• the electrode/electrolyte interface during the ORR, electrochemical impedance spectroscopy was performed. The Nyquist plot was acquired at 5 mV as AC amplitude between 100 kHz and 100 mHz with 0 V as a bias potential (Figure 4d). It is important to note that the prepared electrocatalysts displayed a

Design of a biomimetic, small-scale artificial leaf surface for the study of environmental interactions

• Miriam Anna Huth,
• Axel Huth,
• Lukas Schreiber and
• Kerstin Koch

Beilstein J. Nanotechnol. 2022, 13, 944–957, doi:10.3762/bjnano.13.83

• formation of biofilms [25][26]. A measure of the degree of wetting is the contact angle θ (CA). It describes the angle between the liquid–vapor interface and the liquid–solid interface. According to the CA, surfaces can be classified as superhydrophilic (0° < θ < 10°), hydrophilic (10° ≤ θ < 90

Comparing the performance of single and multifrequency Kelvin probe force microscopy techniques in air and water

• Jason I. Kilpatrick,
• Emrullah Kargin and
• Brian J. Rodriguez

Beilstein J. Nanotechnol. 2022, 13, 922–943, doi:10.3762/bjnano.13.82

• of topography and surface properties of interfaces in a wide range of environments [1]. Kelvin probe force microscopy (KPFM) utilizes the application of a bias and a conductive probe to map the local electrical properties of an interface at the nanoscale [2], allowing for the determination of the

• local contact potential difference (CPD) between the probe and the sample. This, in turn, allows the work function of the sample to be measured if the work function of the probe is known and vice versa. The mapping of local electrical properties of the interface is essential to further our understanding

Self-assembly of C₆₀ on a ZnTPP/Fe(001)–p(1 × 1)O substrate: observation of a quasi-freestanding C₆₀ monolayer

• Guglielmo Albani,
• Michele Capra,
• Alessandro Lodesani,
• Alberto Calloni,
• Gianlorenzo Bussetti,
• Marco Finazzi,
• Franco Ciccacci,
• Alberto Brambilla,
• Lamberto Duò and
• Andrea Picone

Beilstein J. Nanotechnol. 2022, 13, 857–864, doi:10.3762/bjnano.13.76

• measurements reveal a negligible charge transfer at the C60/ZnTPP interface. Finally, the difference between the energy of the lowest unoccupied molecular orbital (LUMO) and that of the highest occupied molecular orbital (HOMO) measured on C60 is about 3.75 eV, a value remarkably higher than those found in

• materials possessing antithetic electronic and structural properties. In this frame, the molecule–metal interaction arising at the interface plays a crucial role in determining the morphology and the electronic properties of the hybrid organic/inorganic system. With regard to the structural aspects, a

• metallic substrates. Here, the hybridization between the molecular orbitals and the electronic states of the substrate generally modifies the intrinsic properties of the molecules, inducing the broadening of the molecular resonances, the narrowing of the band gap, and the development of interface states

Temperature and chemical effects on the interfacial energy between a Ga–In–Sn eutectic liquid alloy and nanoscopic asperities

• Yujin Han,
• Pierre-Marie Thebault,
• Corentin Audes,
• Xuelin Wang,
• Haiwoong Park,
• Jian-Zhong Jiang and
• Arnaud Caron

Beilstein J. Nanotechnol. 2022, 13, 817–827, doi:10.3762/bjnano.13.72

• oxide [10]. This effect has also been used to trigger the reaction of thin oxide films at the liquid–vapor interface with liquid gallium alloys [11]. While the liquid–vapor interface of liquid gallium-based alloys has been well investigated, the wetting of liquid gallium alloys on different substrates

• drop is not disrupted during application onto a substrate. In contrast, when the oxide skin breaks, new oxide forms at the solid–liquid interface with a substrate, which results in adhesion. Also, the wetting of a liquid Ga–In alloy has been related to the adsorption energy of gallium on three

• could be tuned by texturing the substrate surface. The wetting of gallium-based liquid alloys is thus complex and depends on the stability of the oxide at the liquid–substrate interface, the reactivity with the substrate material, and the substrate topography. In this work, we applied atomic force

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• tailored by controlling the evaporation front and the withdrawal speed, making photonic sensors possible. To pack the coordination polymer particles denser, stronger forces were introduced by casting the particle dispersion at an ice–water interface [142]. After freezing of the residual water, the

• nanosheets spontaneously and precisely organized into films at the interface laminarly. The films could be easily transferred to other substrates, and showed superprotonic conductivity, which may be promising for fuel cells. The assembly process of 2D coordination polymer nanosheets could be confined inside

• single crystals involving the generation of Cu2L4 SBU and its fragmentation into CuL2. Figure 1c was reprinted from [97], Chem, vol. 8, by J. Han et al., “Determining factors in the growth of MOF single crystals unveiled by in situ interface imaging”, pages 1637-1657, Copyright (2022), with permission

Hierarchical Bi₂WO₆/TiO₂-nanotube composites derived from natural cellulose for visible-light photocatalytic treatment of pollutants

• Zehao Lin,
• Zhan Yang and
• Jianguo Huang

Beilstein J. Nanotechnol. 2022, 13, 745–762, doi:10.3762/bjnano.13.66

• presence of the hierarchical TiO2 nanotubes influences and inhibits the crystallinity of Bi2WO6 in between the interface of the two phases, revealing the strong interaction between TiO2 and Bi2WO6 phases [35][36]. Figure 2b displays the FTIR spectra of the hierarchical Bi2WO6/TiO2-NT nanocomposites, pure

• interface of the Bi2WO6/TiO2-NT heterostructures, which promotes the generation of more effective photogenerated charges. Besides, the 70%−Bi2WO6/TiO2-NT and 90%−Bi2WO6/TiO2-NT nanocomposites behave similarly but have higher photocurrent responses than those of the 50%−Bi2WO6/TiO2-NT nanocomposite, which

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• effect at a ferromagnetic insulator–superconductor (FI–S) interface. The calculations are based on the boundary condition for diffusive quasiclassical Green’s functions, which accounts for arbitrarily strong spin-dependent effects and spin mixing angles. The resulting phase diagram shows a transition

• field, we find good agreement between theory and experiment. The theory depends only on very few parameters, mostly specified by the experimental setup. We determine the effective spin of the interface moments as J ≈ 0.74ℏ. Keywords: circuit theory; magnetism; proximity effect; superconductivity

• = e2/h is the conductance quantum, and G = σNA/d is the conductance of the film (in the direction perpendicular to the interface of cross section A). D and σN are the diffusion constant and the normal-state conductivity of the film, respectively. Note, that due to the normalization condition for

Comparative molecular dynamics simulations of thermal conductivities of aqueous and hydrocarbon nanofluids

• Adil Loya,
• Antash Najib,
• Fahad Aziz,
• Asif Khan,
• Guogang Ren and
• Kun Luo

Beilstein J. Nanotechnol. 2022, 13, 620–628, doi:10.3762/bjnano.13.54

• layer at the liquid–particle interface) is another significant mechanism for heat transfer enhancement [18][19][20]. Furthermore, a number of researchers have shown that agglomeration (or clustering) of nanoparticles is another key factor that affects the thermal conductivity of nanofluids [21][22][23

Revealing local structural properties of an atomically thin MoSe₂ surface using optical microscopy

• Lin Pan,
• Peng Miao,
• Anke Horneber,
• Alfred J. Meixner,
• Pierre-Michel Adam and
• Dai Zhang

Beilstein J. Nanotechnol. 2022, 13, 572–581, doi:10.3762/bjnano.13.49

•  3b), while the photoluminescence intensity of CuPc on bilayer MoSe2 excited by radial polarization is only 1.49 times higher compared to that with azimuthal polarization. Based on the above experimental results, the Raman enhancement mechanism at the interface between CuPc molecules and the 2H MoSe2

• ]. Additionally, MoSe2 has a polar covalent bond (Mo–Se), which can induce interface dipole–dipole interactions with CuPc in a face-on orientation [24]. The dipole–dipole interaction will bring about a local symmetry-related perturbation, leading to an increase of the matrix element for the LUMO–HOMO transition

• polarization is more pronounced than it is with radial polarization. This is mainly due to the first-layer effect, where ground-state charge transfer and interface dipole–dipole interactions between the first layer of face-on lying CuPc molecules and MoSe2 are more efficient. The SHG and photoluminescence

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• is associated with the reduction of I3− at the cathode (CE/electrolyte), while the second one in the low-frequency region is attributed to electron transport in the TiO2 film in the back reaction at the TiO2/electrolyte interface (TiO2/dye/electrolyte). EIS data were fitted using an equivalent

• interface compared to the Pt/electrolyte interface. The high peak current density value for I3− reduction from CV analysis obtained for MoS2-based CEs was therefore attributed to the high number of catalytically active sites located on the edge planes of the MoS2 films. DSSC performance To further evaluate

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• occurred from Ag and Au NPs to ZnO NRs. The 3D hybrid structures improve the surface-to-volume ratio, yielding a higher SERS activity. Moreover, the formation of “hotspots” and the Shottky barrier at the interface between ZnO NRs and the decorated Au NPs increases the SERS activity. Furthermore, limits of

• at the ZnO–analyte or ZnO–Ag NP interface. Chin et al. [53] fabricated polydopamine-ZnO–based substrates using increasing Ag NP deposition times and observed a gradually decrease of the detected concentration of rhodamine 6G with increasing deposition time. However, for longer deposition times, which

Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy

• Patrick Stohmann,
• Sascha Koch,
• Yang Yang,
• Christopher David Kaiser,
• Julian Ehrens,
• Jürgen Schnack,
• Niklas Biere,
• Dario Anselmetti,
• Armin Gölzhäuser and
• Xianghui Zhang

Beilstein J. Nanotechnol. 2022, 13, 462–471, doi:10.3762/bjnano.13.39

• the pristine monolayer. Features similar to dark spots with a diameter of ≈10 Å were observed by Kondoh et al. on the methylthiolate/Au(111) surface after electron irradiation at 4 keV and assigned as sulfur species after cleavage of S–C bonds at the interface [69]. In our case, a higher magnification

• density of the dark spots is estimated to be (2.0 ± 1.0) × 1012 cm−2 and the corresponding area fraction is approximately 3.2%. Analogous to the formation of 2D polymers on a surface or interface [6], the cross-linking could proceed either by step-growth or chain-growth kinetics. In the step-growth

Tunable superconducting neurons for networks based on radial basis functions

• Andrey E. Schegolev,
• Nikolay V. Klenov,
• Sergey V. Bakurskiy,
• Igor I. Soloviev,
• Mikhail Yu. Kupriyanov,
• Maxim V. Tereshonok and
• Anatoli S. Sidorenko

Beilstein J. Nanotechnol. 2022, 13, 444–454, doi:10.3762/bjnano.13.37

• number, T is the temperature, kB is Boltzmann’s constant, where H is the exchange energy (H = 0 in S and N layers). The indexes “l” and “r” denote the materials at, respectively, the left and right side of an interface, ξ is the coherence length, ρ is the resistivity of the material (in the following, ξ

• and ρ will also will be mentioned with indexes that denote the layer of these parameters), TC is the critical temperature of the superconductor, and γB = (RBA)/(ρlξl) is the interface parameter, where RBA is the resistance per square of the interface The calculated distribution of the anomalous Green

A chemiresistive sensor array based on polyaniline nanocomposites and machine learning classification

• Jiri Kroutil,
• Alexandr Laposa,
• Ali Ahmad,
• Jan Voves,
• Vojtech Povolny,
• Ladislav Klimsa,
• Marina Davydova and
• Miroslav Husak

Beilstein J. Nanotechnol. 2022, 13, 411–423, doi:10.3762/bjnano.13.34

• coefficient. The resistivity of these nanocomposites depends on the p–n depletion layer width on the interface between the n-type nanoparticles and the surrounding p-type PANi molecules. Gas sensing analysis The gas sensing characterizations of sensitive layers were performed using a custom-built apparatus

Electrostatic pull-in application in flexible devices: A review

• Teng Cai,
• Yuming Fang,
• Yingli Fang,
• Ruozhou Li,
• Ying Yu and
• Mingyang Huang

Beilstein J. Nanotechnol. 2022, 13, 390–403, doi:10.3762/bjnano.13.32

• between GR and the outer coating interface of the metal electrode. In addition, the use of a GR-GR electrode structure can improve the flexibility of the whole switch, laying a good foundation for fully flexible devices. In 2009, Milaninia et al. [29] reported the first NEM switch with a GR-GR electrode

Micro- and nanotechnology in biomedical engineering for cartilage tissue regeneration in osteoarthritis

• Zahra Nabizadeh,
• Mahmoud Nasrollahzadeh,
• Hamed Daemi,
• Mohamadreza Baghaban Eslaminejad,
• Ali Akbar Shabani,
• Mehdi Dadashpour,
• Majid Mirmohammadkhani and
• Davood Nasrabadi

Beilstein J. Nanotechnol. 2022, 13, 363–389, doi:10.3762/bjnano.13.31

• and vertical to the articular surface. Meanwhile, this zone provides the greatest resistance to compressive forces [6]. The calcified cartilage zone, which is presumed to be an interface layer between the upper cartilage layers and the rigid subchondral bone, contains chondrocytes, which usually

• –cartilage interface [118]. 3.1.2.3 Nanotubes. Nanotubes are a particular class of nanostructured compounds with a diameter of 1–100 nm known for their cylindrical geometry. Nanotubes are used in a wide variety of nanotechnology-related areas, with recent widespread applications in biomedicine and

Interfacial nanoarchitectonics for ZIF-8 membranes with enhanced gas separation

• Season S. Chen,
• Zhen-Jie Yang,
• Chia-Hao Chang,
• Hoong-Uei Koh,
• Sameerah I. Al-Saeedi,
• Kuo-Lun Tung and
• Kevin C.-W. Wu

Beilstein J. Nanotechnol. 2022, 13, 313–324, doi:10.3762/bjnano.13.26

• , the interfacial synthesis method confines the coordination of the MOF to the solvent interface, which ensures good control over MOF nucleation and growth processes [37][38]. Consequently, it is a promising approach to synthesize a defect-free MOF film. In comparison, the counter-diffusion method

• -octanol solution was added dropwise to the zinc nitrate solution. The mixture was kept at 80 °C in an oil bath for 12 h to form a ZIF-8 free-standing thin film on the liquid–liquid interface. After the reaction, fragments of the ZIF-8 thin film were dispersed in methanol to remove solvents and unreacted

• -methylimidazole/1-octanol solution were prepared to optimize the ZIF-8 membrane structure. Since 1-octanol is immiscible with water, ZIF-8 formation can be confined to the interface between water and the organic solvent. Prior to ZIF-8 crystal growth, the pretreated α-Al2O3 disk was immersed into the zinc nitrate