Self-assembled monolayers and titanium dioxide: From surface patterning to potential applications

• Yaron Paz

Beilstein J. Nanotechnol. 2011, 2, 845–861, doi:10.3762/bjnano.2.94

• of a modified C60 [87]. An agreement between the measured photocurrent action spectrum and the absorption spectrum of the modified fullerene served as an indication that the photoactive species was the modified fullerene. A photon-to-current conversion efficiency as high as 15% was measured

• force may compensate to some extent for the lack of chemical bonding between the quantum dots and the terminating groups of the monolayer, thus, enabling the high photocurrent response measured for this system. Another study on charge transport between SAMs and TiO2 was based on a mixed-monolayer

Highly efficient ZnO/Au Schottky barrier dye-sensitized solar cells: Role of gold nanoparticles on the charge-transfer process

• Tanujjal Bora,
• Htet H. Kyaw,
• Soumik Sarkar,
• Samir K. Pal and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2011, 2, 681–690, doi:10.3762/bjnano.2.73

• barrier at the ZnO/Au interface and not due to the faster electron injection from dye to ZnO. The effect of Au nanoparticles on the generation of photocurrent in the ZnO/Au-nanocomposite-based DSSC was studied for small- (0.1 cm2) as well as large-area (1 cm2) solar cells and the results are compared to

• sensitizer dye molecules, the photoexcited electrons in the Au nanoparticles are transferred to the conduction band (CB) of ZnO, and then diffuse through the ZnO nanorods towards the conducting fluorine-doped tin oxide (FTO) substrate resulting in higher photocurrent and photovoltage, as observed. The

• illumination; the results are shown in Table 2. In Figure 3a, the best J–V characteristics obtained for both bare ZnO-nanorod and ZnO/Au-nanocomposite DSSCs are shown. It was found that the photocurrent of the ZnO-nanorod DSSC improved upon the incorporation of Au nanoparticles in the ZnO-nanorod

Simple theoretical analysis of the photoemission from quantum confined effective mass superlattices of optoelectronic materials

• Debashis De,
• Sitangshu Bhattacharya,
• S. M. Adhikari,
• A. Kumar,
• P. K. Bose and
• K. P. Ghatak

Beilstein J. Nanotechnol. 2011, 2, 339–362, doi:10.3762/bjnano.2.40

• photo-emitted current density from the said SLs as a function of normalized electron degeneracy, normalized intensity, wavelength and thickness, respectively, for all the cases of Figure 1. Using Equation 15 and Equation 16, the normalized photocurrent from QWW effective mass HgTe/Hg1−xCdxTe SL, whose

• normalized photoemission from QWW effective mass HgTe/Hg1−xCdxTe and InxGa1−xAs/InP SLs decreases with increasing thickness and exhibits large oscillations. From Figure 7, it appears that the normalized photocurrent for the said system increases with increasing carrier concentration, exhibiting a quantum

• jump for a particular value of the said variable, for all the models of both the SLs. From Figure 8 and Figure 9, it can be inferred that the normalized photocurrent in this case increases with decreasing intensity and wavelength in different manners. From Figure 10, it has been observed that the

Schottky junction/ohmic contact behavior of a nanoporous TiO₂ thin film photoanode in contact with redox electrolyte solutions

• Masao Kaneko,
• Hirohito Ueno and
• Junichi Nemoto

Beilstein J. Nanotechnol. 2011, 2, 127–134, doi:10.3762/bjnano.2.15

• redox waves in the dark due to the [Fe(CN)6]4−/3− couple. Further studies showed that multiple Schottky junctions/ohmic contact behavior inducing simultaneously both photocurrent and overlapped reversible redox waves was found in the CV of a nanoporous TiO2 photoanode soaked in an aqueous redox

• electrolyte solution containing methanol and [Fe(CN)6]4−. That is, the TiO2 nanosurface responds to [Fe(CN)6]4− to give ohmic redox waves overlapped simultaneously with photocurrents due to the Schottky junction. Additionally, a second step photocurrent generation was observed in the presence of both MeOH and

• potential; nanoporous TiO2 thin film; photocurrent; Schottky junction and ohmic contact; Introduction Photoelectrocatalytic reactions at semiconductor electrodes were investigated before the 1960s [1][2]. A semiconductor electrode forms a type of Schottky junction with liquid electrolytes called a liquid