Beilstein J. Nanotechnol.2012,3, 82–100, doi:10.3762/bjnano.3.10
inorganic nanostructures instead of flat surfaces has been demonstrated to be an effective process for preparing various previously untested functional organic/inorganic nanohybrids. The organic parts generally provide functional groups for the nanohybrids, while the inorganic parts act as the scaffold for
ratios and ability to form network structures. It is no doubt that nanotubes with reactive surfaces and a reliable supply are preferred for the application as scaffold of organic molecules. Carbon nanotubes (CNTs) play an important role in the nanotube family. However, the surface of CNTs is inert for
adsorption and assembly of organic molecules on the imogolite surface is expected to produce interesting results. Imogolite may act as a one-dimensional scaffold for functional molecules. Moreover, the surface energy of imogolite nanotubes can be lowered by the organic layer, and this can greatly improve the
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Figure 1:
Schematic illustration of imogolite-nanotube structure (left). DFM image of imogolite (right).
Beilstein J. Nanotechnol.2011,2, 525–544, doi:10.3762/bjnano.2.57
a common self-assembly mechanism, as discussed previously, it is natural to assume that similar peptide–peptide interactions play the structure-determining role during the aggregation of our hybrid compound and form the scaffold of the fibrils.
Relying on the basic ideas and our current
molecules preserved their relative positions in the aggregates with respect to their neighbors, however, certain conformational rearrangements both at the molecular level and at the nanoscale were observed. In all the cases, the β-sheet organization dominated the structure and remained the main scaffold for
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Figure 1:
Various morphological organization examples of fibrillar aggregates that can be formed by polymer b...