Proinflammatory and cytotoxic response to nanoparticles in precision-cut lung slices

• Stephanie Hirn,
• Nadine Haberl,
• Kateryna Loza,
• Matthias Epple,
• Wolfgang G. Kreyling,
• Barbara Rothen-Rutishauser,
• Markus Rehberg and
• Fritz Krombach

Beilstein J. Nanotechnol. 2014, 5, 2440–2449, doi:10.3762/bjnano.5.253

• zinc oxide (ZnO-NPs) nanoparticles as well as quartz particles were used because these materials have been previously shown in several in vitro and in vivo studies to induce a dose-dependent cytotoxic and inflammatory response. PCLS were exposed to three concentrations of 70 nm monodisperse

Synthesis and characterization of fluorescence-labelled silica core-shell and noble metal-decorated ceria nanoparticles

• Rudolf Herrmann,
• Markus Rennhak and
• Armin Reller

Beilstein J. Nanotechnol. 2014, 5, 2413–2423, doi:10.3762/bjnano.5.251

• , ceria, titania and zinc oxide. This review article concentrates on synthesis and characterization of fluorescent silica and ceria NP, the latter also decorated with noble metals as models for decomposition products of automobile catalysts. We have recently reported on fluorescence-labelled coated

• titania NP and their interaction with human cell lines [1] and pointed out that the determination of the biological effects of zinc oxide NP is problematic since they are sensitive towards phosphate ions [2]. This work will not be included in this article. The fluorescence dyes and the labelling process

• well as to coated titania [1] and zinc oxide nanoparticles [2]. For experiments where several cell organelles are stained and detected in different ranges of fluorescence emission (channels), dyes with single sharp emission peaks are desirable. We therefore changed the dye for our experiments with

Interaction of dermatologically relevant nanoparticles with skin cells and skin

• Annika Vogt,
• Fiorenza Rancan,
• Sebastian Ahlberg,
• Berouz Nazemi,
• Chun Sik Choe,
• Maxim E. Darvin,
• Sabrina Hadam,
• Ulrike Blume-Peytavi,
• Kateryna Loza,
• Jörg Diendorf,
• Matthias Epple,
• Christina Graf,
• Eckart Rühl,
• Martina C. Meinke and
• Jürgen Lademann

Beilstein J. Nanotechnol. 2014, 5, 2363–2373, doi:10.3762/bjnano.5.245

• DNA damage and apoptosis were detected in human skin epidermal cells after exposure to nickel nanoparticles [42]. Phototoxicity of zinc oxide nanoparticles induced the generation of oxidative DNA damage during UVA and visible light irradiation in keratinocytes [43]. Oxidative stress and skin cell

Influence of stabilising agents and pH on the size of SnO₂ nanoparticles

• Olga Rac,
• Patrycja Suchorska-Woźniak,
• Marta Fiedot and
• Helena Teterycz

Beilstein J. Nanotechnol. 2014, 5, 2192–2201, doi:10.3762/bjnano.5.228

• polyelectrolyte that is protonated in acidic solutions, whereas at pH > 8, it exists in the free alkaline form [23]. PEI is often used as a colloidal metal nanoparticle and metal oxide stabiliser. Studies show that many metal nanoparticles (such as silver, gold, zinc oxide or tin dioxide) synthesised in solutions

Biopolymer colloids for controlling and templating inorganic synthesis

• Laura C. Preiss,
• Katharina Landfester and
• Rafael Muñoz-Espí

Beilstein J. Nanotechnol. 2014, 5, 2129–2138, doi:10.3762/bjnano.5.222

• groups were shown to have an effect on the growth and on the final properties of inorganic materials such as zinc oxide [40][41], calcium oxalate [38], or calcium carbonate [42][43]. It is expectable that analogous effects should be obtained when biopolymeric (or synthetic biomimetic chains) are attached

Rapid degradation of zinc oxide nanoparticles by phosphate ions

• Rudolf Herrmann,
• F. Javier García-García and
• Armin Reller

Beilstein J. Nanotechnol. 2014, 5, 2007–2015, doi:10.3762/bjnano.5.209

• Rudolf Herrmann F. Javier Garcia-Garcia Armin Reller Institut für Physik, Universität Augsburg, Universitätsstr. 1, 86159 Augsburg, Germany ICTS Centro Nacional de Microscopía Electrónica, Facultad de Químicas, Av. Complutense s/n, 28040 Madrid, Spain 10.3762/bjnano.5.209 Abstract Zinc oxide

• solubility. The morphology of the zinc oxide particles has only a minor influence on the kinetics of this reaction. Surface properties related to different production methods and the presence and absence of labelling with a perylene fluorescent dye are more important. Particles prepared under acidic

• account when assessing the biological effects or the toxicology of zinc oxide nanoparticles. Keywords: degradation; phosphate; silica shell; zinc oxide nanoparticles; zinc phosphate; Introduction Crystalline nanoparticles of the semiconductor zinc oxide (ZnO-NP) show a broad fluorescence band in the

Mimicking exposures to acute and lifetime concentrations of inhaled silver nanoparticles by two different in vitro approaches

• Fabian Herzog,
• Kateryna Loza,
• Sandor Balog,
• Martin J. D. Clift,
• Matthias Epple,
• Peter Gehr,
• Alke Petri-Fink and
• Barbara Rothen-Rutishauser

Beilstein J. Nanotechnol. 2014, 5, 1357–1370, doi:10.3762/bjnano.5.149

• effects of zinc oxide [41], gold (Au) [42][43] and Ag NPs as well as Ag ions [44] have been evaluated. The aim of the present study was therefore to use a recently established system [44] to assess the effects of Ag NPs and Ag+ on the 3D lung model. Compared to the citrate-coated Ag NPs in the previous

• exposures are less expensive, easier and quicker to perform than animal studies. In previous studies we have employed ALI exposures to investigate the toxic potential of various materials such as diesel car and scooter exhaust gases [58][59], zinc oxide [41], cerium oxide [60], gold (Au) [42] and silver [44

Effects of palladium on the optical and hydrogen sensing characteristics of Pd-doped ZnO nanoparticles

• Anh-Thu Thi Do,
• Hong Thai Giang,
• Thu Thi Do,
• Ngan Quang Pham and
• Giang Truong Ho

Beilstein J. Nanotechnol. 2014, 5, 1261–1267, doi:10.3762/bjnano.5.140

• of zinc oxide nanoparticles on the photoluminescence (PL) properties and hydrogen sensing characteristics of gas sensors is investigated. The PL intensity shows that the carrier dynamics coincides with the buildup of the Pd-related green emission. The comparison between the deep level emission and

Integration of ZnO and CuO nanowires into a thermoelectric module

• Dario Zappa,
• Simone Dalola,
• Guido Faglia,
• Elisabetta Comini,
• Matteo Ferroni,
• Caterina Soldano,
• Vittorio Ferrari and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2014, 5, 927–936, doi:10.3762/bjnano.5.106

• , 25123, Brescia, Italy Dipartimento di Ingegneria dell’Informazione, University of Brescia, via Branze 38, 25123, Brescia, Italy Currently at ETCs.r.l., via Gobetti 101, 40129 Bologna, Italy 10.3762/bjnano.5.106 Abstract Zinc oxide (ZnO, n-type) and copper oxide (CuO, p-type) nanowires have been

• of further integration of metal oxide nanostructures into efficient thermoelectric devices. Keywords: copper oxide; nanowires; thermoelectric; zinc oxide; Introduction A thermoelectric generator (TEG) is a device capable of converting a temperature gradient into an electrical voltage difference

• (Table 1). Thermoelectric power factor (TPF) was estimated for both CuO and ZnO nanowires, based on sheet resistance Rs. The electrical conductivity was calculated as σ = 1/(Rs·h), where h is the thickness of each strip. We found values of σ of 2.0 S/m for copper oxide and 0.7 S/m for zinc oxide. While

Nanostructure sensitization of transition metal oxides for visible-light photocatalysis

• Hongjun Chen and
• Lianzhou Wang

Beilstein J. Nanotechnol. 2014, 5, 696–710, doi:10.3762/bjnano.5.82

• photosensitization of nanoporous titanium dioxide, zinc oxide, tin dioxide, niobium oxide, and tantalum oxide by quantum-sized cadmium sulfide, lead sulfide, silver sulfide, antimony sulfide, and bismuth sulfide. They found that the photocurrent quantum yields of these photosensitized transition metal oxides can be

Injection of ligand-free gold and silver nanoparticles into murine embryos does not impact pre-implantation development

• Ulrike Taylor,
• Wiebke Garrels,
• Annette Barchanski,
• Svea Peterson,
• Laszlo Sajti,
• Andrea Lucas-Hahn,
• Lisa Gamrad,
• Ulrich Baulain,
• Sabine Klein,
• Wilfried A. Kues,
• Stephan Barcikowski and
• Detlef Rath

Beilstein J. Nanotechnol. 2014, 5, 677–688, doi:10.3762/bjnano.5.80

• ][17][18][19][20], nickel (NiNP) [21], zinc oxide (ZnONP) [22][23], titanium dioxide (TiO2NP) [23][24][25], aluminium trioxide (Al2O3NP) [23] and copper (CuNP) [22][25]. Toxic effects were observed after exposure to AgNP, CuNP, ZnONP and NiNP. AuNP, TiO2NP and Al2O3NP, on the other hand, seemed to be

An ultrasonic technology for production of antibacterial nanomaterials and their coating on textiles

• Anna V. Abramova,
• Vladimir O. Abramov,
• Aharon Gedanken,
• Ilana Perelshtein and
• Vadim M. Bayazitov

Beilstein J. Nanotechnol. 2014, 5, 532–536, doi:10.3762/bjnano.5.62

• after washing. Antimicrobial textiles can be produced by coating textiles with antibacterial nanoparticles (NPs). NPs such as zinc oxide NPs are known to have antibacterial properties due to OH• radicals, which result from defects in their crystal structure [2]. In the case of power ultrasound

• analyse the antibacterial properties of the samples comparing their antibacterial activity and the antibacterial activity of samples coated with industrially produced NPs. In the research described in this paper we produced a suspension of zinc oxide NPs in water by using a sonoplasma discharge between

• about 10 nm. The length of these rods is about 50 nm. We have obtained the size distribution of the zinc oxide particles produced in the sonoplasma discharge by using DLS measurements (Figure 4). The results confirm that a stable monodispersed suspension of ZnO NPs can be produced by using a sonoplasma

Preparation of poly(N-vinylpyrrolidone)-stabilized ZnO colloid nanoparticles

• Tatyana Gutul,
• Emil Rusu,
• Nadejda Condur,
• Veaceslav Ursaki,
• Evgenii Goncearenco and
• Paulina Vlazan

Beilstein J. Nanotechnol. 2014, 5, 402–406, doi:10.3762/bjnano.5.47

• from the most intense PL band at 356 nm coming from the PVP, exhibits a strong PL band at 376 nm (3.30 eV) which corresponds to the emission of the free exciton recombination in ZnO nanoparticles. Keywords: colloidal solutions; nanocomposite; poly(N-vinylpyrrolidone); sol–gel; zinc oxide

• ; Introduction Zinc oxide is widely used in various applications such as gas sensors, solar cells, antireflection coatings, varistors, surface acoustic wave devices, light emitting diodes and random lasers [1][2][3][4]. Among different processing methods, the sol–gel technique has various advantages such as cost

• -shifted to 1559.6 cm−1 as a result of the interaction of the carbonyl oxygen with the zinc ion [23]. As concerns the absorption in the region of 1500–1200 cm−1, an overlap of absorption bands of PVP with bands of the hydrated zinc oxide, as well as interaction between them occurs. As a result, we observe

Photovoltaic properties of ZnO nanorods/p-type Si heterojunction structures

• Rafal Pietruszka,
• Bartlomiej S. Witkowski,
• Grzegorz Luka,
• Lukasz Wachnicki,
• Sylwia Gieraltowska,
• Krzysztof Kopalko,
• Eunika Zielony,
• Piotr Bieganski,
• Ewa Placzek-Popko and
• Marek Godlewski

Beilstein J. Nanotechnol. 2014, 5, 173–179, doi:10.3762/bjnano.5.17

• , Wroclaw, Poland Department of Mathematics and Natural Sciences College of Science, Cardinal Stefan Wyszynski University, Warsaw, Poland 10.3762/bjnano.5.17 Abstract Selected properties of photovoltaic (PV) structures based on n-type zinc oxide nanorods grown by a low temperature hydrothermal method on p

• the structure containing closely-spaced nanorods, which show light conversion efficiency of 3.6%. Keywords: atomic layer deposition; hydrothermal method; solar cells; zinc oxide; zinc oxide nanorods; Introduction Solar cells are intensively studied as an alternative energy source and may replace

• have been studied since the 1930s [6], and several applications have been found in the past decades. For example, they are used in PV systems based on thin films, so-called PV structures of the second generation [7][8][9]. At the moment, zinc oxide is the most studied wide band gap material [10][11][12

Synthesis of boron nitride nanotubes from unprocessed colemanite

• Saban Kalay,
• Zehra Yilmaz and
• Mustafa Çulha

Beilstein J. Nanotechnol. 2013, 4, 843–851, doi:10.3762/bjnano.4.95

• , hydrogen storage, and the improvement of the mechanical as well as the chemical durability of polymer composites. Experimental Material and methods Colemanite (Ca2B6O11·5H2O) was a gift from Eti Mine Works General Management (Turkey). Iron (III) oxide, iron (II, III) oxide, aluminum oxide, zinc oxide

Modulation of defect-mediated energy transfer from ZnO nanoparticles for the photocatalytic degradation of bilirubin

• Tanujjal Bora,
• Karthik K. Lakshman,
• Soumik Sarkar,
• Abhinandan Makhal,
• Samim Sardar,
• Samir K. Pal and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2013, 4, 714–725, doi:10.3762/bjnano.4.81

• ; Förster resonance energy transfer (FRET); neonatal jaundice; oxygen vacancy; photocatalysis; phototherapy; zinc oxide nanoparticles; Introduction Bilirubin (BR) is a yellow-orange pigment which is a byproduct of the normal heme catabolism in mammals. In the human body, 250–400 mg BR is produced every day

• the numerous nanostructured materials, zinc oxide (ZnO) is one of the most promising materials for applications in the medical field, because of its biocompatibility, biodegradability and non-toxicity [9]. Moreover, ZnO can degrade various organic compounds efficiently through photocatalysis [10][11

Evolution of microstructure and related optical properties of ZnO grown by atomic layer deposition

• Adib Abou Chaaya,
• Roman Viter,
• Mikhael Bechelany,
• Zanda Alute,
• Donats Erts,
• Anastasiya Zalesskaya,
• Kristaps Kovalevskis,
• Vincent Rouessac,
• Valentyn Smyntyna and
• Philippe Miele

Beilstein J. Nanotechnol. 2013, 4, 690–698, doi:10.3762/bjnano.4.78

• ultrathin ZnO films in optical sensors and biosensors. Keywords: atomic layer deposition; optical properties; photoluminescence; thin films; ZnO; Introduction Zinc oxide (ZnO) is an n-type semiconductor and a transparent conductive oxide (TCO) with excellent optoelectronic properties, a wide band gap

• different deposition techniques such as sol–gel [18], chemical vapor deposition [19], electro-deposition [5][6][7], RF sputtering, and atomic layer deposition (ALD) [16][17]. It is well known that the optoelectronic properties of zinc oxide thin film [20][21] are strongly dependent on the structure [11][22

• defect concentration and diminishes at annealing in an oxygen environment (oxygen vacancy healing) [21]. One of the methods applied to analyze the crystalline structure and defect level in zinc oxide is photoluminescence. It has been shown that ZnO exhibits a narrow UV emission band in the 378–381 nm

Ferromagnetic behaviour of Fe-doped ZnO nanograined films

• Boris B. Straumal,
• Svetlana G. Protasova,
• Andrei A. Mazilkin,
• Thomas Tietze,
• Eberhard Goering,
• Gisela Schütz,
• Petr B. Straumal and
• Brigitte Baretzky

Beilstein J. Nanotechnol. 2013, 4, 361–369, doi:10.3762/bjnano.4.42

• behaviour of zinc oxide (see [2][3][4][5][6] and references therein). However, the obtained results were quite contradictory. Several teams of experimentalists reported observations of weak but quite reproducible ferromagnetism. Other research groups never succeeded in synthesizing ferromagnetic ZnO. The

• fact prompts us to check, whether the concentration dependence of the saturation magnetization for Fe-doped ZnO films has one or two maxima. Therefore, the goals of this work are to determine the threshold value sth of the specific GB area for Fe-doped zinc oxide and to analyse experimentally the

• originally supposed in [1]. Moreover, Fe improved the FM properties of pure zinc oxide more effectively than Co and Mn. For the transition from paramagnetic to FM behaviour in the Fe-doped ZnO one needs many times fewer GBs than in the Co- and Mn-doped ZnO. The reason for the sth difference for the pure ZnO

Paper modified with ZnO nanorods – antimicrobial studies

• Mayuree Jaisai,
• Sunandan Baruah and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2012, 3, 684–691, doi:10.3762/bjnano.3.78

• the paper samples are 102% and 70%, and for Aspergillus niger, 224% and 183% of the sample area, under similar lighting conditions. Keywords: antimicrobial; nanorod; paper; photocatalysis; zinc oxide; Introduction Deterioration of library materials due to fungal growth is a worldwide problem and a

• ) nanoparticles embedded into a paper matrix have been reported as exhibiting antibacterial properties [4]. Wallpaper prepared by using zinc oxide nanoparticle (~20 nm) coatings has been reported to render antibacterial surfaces that inhibit growth of bacteria such as Escherichia coli (E. coli) [5]. An increase

• in cellular internalization of ZnO nanoparticles has also been observed by Appierot et al. [6] in a study of their antibacterial effect on E. coli and S. aureus. This work reports on an antimicrobial paper containing zinc oxide (ZnO) nanorods grown by a hydrothermal process, and which can be used for

Functionalised zinc oxide nanowire gas sensors: Enhanced NO₂ gas sensor response by chemical modification of nanowire surfaces

• Eric R. Waclawik,
• Jin Chang,
• Andrea Ponzoni,
• Isabella Concina,
• Dario Zappa,
• Elisabetta Comini,
• Nunzio Motta,
• Guido Faglia and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2012, 3, 368–377, doi:10.3762/bjnano.3.43

• ) sensor toward particular target gases in the environment. In this study the effect of an adsorbed organic layer on the dynamic response of zinc oxide nanowire gas sensors was investigated. The effect of ZnO surface functionalisation by two different organic molecules, tris(hydroxymethyl)aminomethane

• target are positive results arising from the coating of these ZnO nanowire sensors with organic-SAM-functionalised ZnO nanoparticles. Keywords: gas sensor; nanowire; tris(hydroxymethyl)aminomethane; self-assembled monolayer; zinc oxide; Introduction Semiconductor gas sensors have been extensively

• semiconductor gas sensors based on zinc oxide nanowires. Significantly, we chose to examine the response of the same ZnO nanowire sensors to target gases before and after functionalisation rather than to compare different sensors prepared in the same batch, in order to eliminate the possibility of differences

Highly efficient ZnO/Au Schottky barrier dye-sensitized solar cells: Role of gold nanoparticles on the charge-transfer process

• Tanujjal Bora,
• Htet H. Kyaw,
• Soumik Sarkar,
• Samir K. Pal and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2011, 2, 681–690, doi:10.3762/bjnano.2.73

• for Basic Sciences, Sector - III, Block - JD, Salt Lake, Kolkata 700098, India 10.3762/bjnano.2.73 Abstract Zinc oxide (ZnO) nanorods decorated with gold (Au) nanoparticles have been synthesized and used to fabricate dye-sensitized solar cells (DSSC). The picosecond-resolved, time-correlated single

• the ZnO/Au interface. For large area DSSC (1 cm2), ~130% enhancement in PCE (from 0.50% to 1.16%) was achieved after incorporation of the Au nanoparticles into the ZnO nanorods. Keywords: dye-sensitized solar cell; gold nanoparticle; picosecond spectroscopy; Schottky barrier; zinc oxide nanorod

• electrons is high at each interface. Law et al. [5] proposed the use of single crystalline zinc oxide (ZnO) nanowires instead of the widely used titanium oxide (TiO2) porous thin film to reduce the probability of electron recombination in the DSSC by providing a direct pathway for the electrons to diffuse

Room temperature synthesis of indium tin oxide nanotubes with high precision wall thickness by electroless deposition

• Mario Boehme,
• Emanuel Ionescu,
• Ganhua Fu and
• Wolfgang Ensinger

Beilstein J. Nanotechnol. 2011, 2, 119–126, doi:10.3762/bjnano.2.14

• below yields open end nanotubes with well defined outer diameter and wall thickness. In the past, zinc oxide films were mostly preferred and were synthesized using electroless deposition based on aqueous solutions. All these methods previously developed, are not adaptable in the case of ITO nanotubes

• growth mechanism of the ITO-NTs was proposed on the basis of the experimental results. Previously zinc oxide films have been prepared by electroless deposition in aqueous solutions under different conditions as shown in Table 1. Ito et al. obtained highly oriented crystalline films, grown directly on a

• substrate in aqueous solutions containing urea [19]. Crystalline zinc oxide films were prepared in alkaline aqueous solutions containing ethane-1,2-diamine as a chelating agent [20]. Well aligned ZnO microrods within a thin film were formed by the thermal decomposition of an amino complex based on Zn2+ and

Enhanced visible light photocatalysis through fast crystallization of zinc oxide nanorods

• Sunandan Baruah,
• Mohammad Abbas Mahmood,
• Myo Tay Zar Myint,
• Tanujjal Bora and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2010, 1, 14–20, doi:10.3762/bjnano.1.3

• ][3][4]. Optical absorption in the ultraviolet region (peaking around 220 nm) [5] and low photoefficiency [6][7] are factors that deter the wide scale use of TiO2 for photocatalytic activities under sunlight. Zinc oxide (ZnO), with a high surface reactivity owing to a large number of native defect

• diameters of 5 to 7 nm in size (Figure 1a). Measurements of the lattice fringe widths on the high-resolution TEM micrographs (see Figure 1c) confirm the wurtzite structure of the zinc oxide crystallites. Fringe widths of 0.28 nm, 0.16 nm and 0.19 nm measured on different images show the dominance of the