Observation of unexpected uniaxial magnetic anisotropy in La_2/3Sr_1/3MnO₃ films by a BaTiO₃ overlayer in an artificial multiferroic bilayer

• John E. Ordóñez,
• Lorena Marín,
• Luis A. Rodríguez,
• Pedro A. Algarabel,
• José A. Pardo,
• Roger Guzmán,
• Luis Morellón,
• César Magén,
• Etienne Snoeck,
• María E. Gómez and
• Manuel R. Ibarra

Beilstein J. Nanotechnol. 2020, 11, 651–661, doi:10.3762/bjnano.11.51

• grown on STO (green triangles), LAO (purple diamonds), and LSAT (dark cyan pentagons) substrates; (c) BTO/ LSMO bilayer with tLSMO = 20 nm (blue circles), 27 nm (green triangles) and 40 nm (black squares). Continuous red lines correspond to numerical fits. (a) Cross-section HAADF-STEM image for a BTO

Comparison of fresh and aged lithium iron phosphate cathodes using a tailored electrochemical strain microscopy technique

• Matthias Simolka,
• Hanno Kaess and
• Kaspar Andreas Friedrich

Beilstein J. Nanotechnol. 2020, 11, 583–596, doi:10.3762/bjnano.11.46

• (MBraun, O2 and H2O < 2 ppm) and washed with dimethylcarbonate (DMC, Sigma-Aldrich). Cross-section cuts were obtained with an unfocused argon beam cross-section polisher (Jeol, 19520-CCP). The transfer of samples was done inside a transfer vessel to avoid any contact with air. ESM measurements ESM

• ]. Further information about the set-up with control experiments regarding the origin of the signal can be found in [34]. The ESM measurements were performed on micrometre-sized single particles of a cross-section of the electrodes cut as specified above. Results and Discussion Cell and cathode

• characterization The ESM analysis was conducted inside of particles of the cross-sections of the fresh and aged cathodes. Two examples of the cross-section structure of the cathodes are given in Figure 1. In Figure 1a the fresh and in 1b the aged cathode cross-section is shown. The electrode consists of particles

Evolution of Ag nanostructures created from thin films: UV–vis absorption and its theoretical predictions

• Robert Kozioł,
• Marcin Łapiński,
• Paweł Syty,
• Damian Koszelow,
• Wojciech Sadowski,
• Józef E. Sienkiewicz and
• Barbara Kościelska

Beilstein J. Nanotechnol. 2020, 11, 494–507, doi:10.3762/bjnano.11.40

• extinction cross section. It can be up to 50 times larger than the geometrical cross section of the nanoparticle [6]. Ag nanoparticles are also interesting because of the position of the plasmon resonance. The LSPR wavelength maximum of small Ag nanoparticles with a diameter of 10 nm in air is around 420 nm

• ), they consist of Ag. Detailed EDS analysis of a cross section of a nanoisland is presented in Figure 8c. As can be seen, a thin layer of natural SiO2, about 2 nm thick, is present on the silicon surface. Interestingly, there is no oxide layer around the Ag nanostructures. The quality of the

• (f) 600 °C; (g) average nanostructure diameter as a function of the annealing temperature. (a) HRTEM image of a cross section of a nanoisland formed from a 3 nm thick film, annealed at 550 °C for 15 min; (b) EDS analysis and (c) detailed EDS analysis of the cross section of the nanoisland. Absorbance

Interfacial charge transfer processes in 2D and 3D semiconducting hybrid perovskites: azobenzene as photoswitchable ligand

• Nicole Fillafer,
• Tobias Seewald,
• Lukas Schmidt-Mende and
• Sebastian Polarz

Beilstein J. Nanotechnol. 2020, 11, 466–479, doi:10.3762/bjnano.11.38

• cation needs a coordinating headgroup that is able to ionically interact with the perovskite structure. In addition, the molecular projection along the z-axis should fit into the square defined by four corner-sharing octahedral [14]. Thus, the cross section of the ligand is a limiting factor, whereas

Using gold nanoparticles to detect single-nucleotide polymorphisms: toward liquid biopsy

• María Sanromán Iglesias and
• Marek Grzelczak

Beilstein J. Nanotechnol. 2020, 11, 263–284, doi:10.3762/bjnano.11.20

• giving rise to the so-called localized surface plasmon resonance (LSPR). The position and the bandwidth of the LSPR can be modulated by the shape of the nanocrystals and can vary between 400 and 2000 nm. The high absorption cross section (plasmonic nanoparticles absorb photons over a region about ten

Nonclassical dynamic modeling of nano/microparticles during nanomanipulation processes

• Moharam Habibnejad Korayem,
• Ali Asghar Farid and
• Rouzbeh Nouhi Hefzabad

Beilstein J. Nanotechnol. 2020, 11, 147–166, doi:10.3762/bjnano.11.13

• Timoshenko beam of Figure 3 are described as where u1, u2 and u3 are displacements along the axes x, y and z, respectively, ψ(x,t) is the angular rotation of the beam cross section and w(x,t) is the beam lateral deformation. By replacing the equations of non-zero elements, one can obtain the strain, stress

Nanosecond resistive switching in Ag/AgI/PtIr nanojunctions

• Botond Sánta,
• Dániel Molnár,
• Patrick Haiber,
• Agnes Gubicza,
• Edit Szilágyi,
• Zsolt Zolnai,
• András Halbritter and
• Miklós Csontos

Beilstein J. Nanotechnol. 2020, 11, 92–100, doi:10.3762/bjnano.11.9

• distances granting metallic conductance also in this ultimate scaling limit. (iii) The device conductance is largely determined by the rearrangement of only a few atoms in this narrowest cross section, which can take place at a very large bandwidth and unprecedentedly low energy cost [5][6][7][8][9

Antimony deposition onto Au(111) and insertion of Mg

• Lingxing Zan,
• Da Xing,
• Abdelaziz Ali Abd-El-Latif and
• Helmut Baltruschat

Beilstein J. Nanotechnol. 2019, 10, 2541–2552, doi:10.3762/bjnano.10.245

• with the holding the potential at −0.88 V is shown in Figure 7d. The horizontal cross section on Figure 7b is shown in Figure 7e. It shows that the ≈1 nm height of the Sb deposits was formed at that time. At the bottom of Figure 7b, the height of the Sb deposits reaches to ≈6 nm, which is around 30

• adlayer is shown with cross section in the image g. (c, d) The electrode potential was held at −0.74 V, followed by formation of a complete monolayer. (e) The electrode potential was scanned back from −0.74 to −0.31 V and then stopped at −0.31 V, followed by dissolution of the monolayer. (f) The electrode

• direction. STM images of the Sb adlayer structure on Au(111) in 0.25 mM Sb2O3/0.5 M H2SO4 electrolyte at −0.74 V. (a) 50 × 50 nm; (b) 30 × 30 nm; (c) the cross section of image a; (d) the cross section of image b. Sample bias of 50 mV, set point = 0.5 nA and scan rate of 12 ln/s. Integral gain: 2 and

Formation of metal/semiconductor Cu–Si composite nanostructures

• Natalya V. Yumozhapova,
• Andrey V. Nomoev,
• Vyacheslav V. Syzrantsev and
• Erzhena C. Khartaeva

Beilstein J. Nanotechnol. 2019, 10, 2497–2504, doi:10.3762/bjnano.10.240

• comparison of EDX analysis of experimental and model nanoparticles obtained from the liquid phase for a cooling rate of 1 and 1.5 K/ps with a silicon concentration of 10 or 50 atom %. The values are obtained by summing the number of atoms in the cross section perpendicular to the axis of the nanoparticle and

• structure. The structure of a Cu–Si nanocluster with a silicon content of 50 atom % at different times at a cooling rate of 0.002 K/ps after a) 0.75 ns, b) 7.5 ns, c) 75 ns, and d) 750 ns; top row: cross section, bottom row: outside view. Transmission electron microscopy of the Cu–SiOx Janus-like, Cu@SiOx

Abrupt elastic-to-plastic transition in pentagonal nanowires under bending

• Sergei Vlassov,
• Magnus Mets,
• Boris Polyakov,
• Jianjun Bian,
• Leonid Dorogin and
• Vahur Zadin

Beilstein J. Nanotechnol. 2019, 10, 2468–2476, doi:10.3762/bjnano.10.237

• soft chemical colloidal techniques often demonstrate a morphology with axes of five-fold (pentagonal) symmetry [1]. Depending on the synthesis conditions such structures can be synthesized in the form of 0D nanoparticles or high-aspect ratio 1D nanowires (NWs) with pentagonal cross-section [2][3]. The

• pentagonal NWs can be considered as 1D materials consisting of five prismatic monocrystalline domains with a triangular cross-section rotated relative to each other by approximately 72°, as shown schematically in Figure 1. The crystalline domains are divided by twin boundaries [4][5]. Due to the fact that

• conjugated gradient method in order to make the configuration reach a local stable state. The NW is further equilibrated at 300 K for about 40 ps to relax the internal stress. Figure 1c shows the distribution of von Mises stress on the cross-section after this equilibration. To apply a bending load to the NW

Mobility of charge carriers in self-assembled monolayers

• Zhihua Fu,
• Tatjana Ladnorg,
• Hartmut Gliemann,
• Alexander Welle,
• Asif Bashir,
• Michael Rohwerder,
• Qiang Zhang,
• Björn Schüpbach,
• Andreas Terfort and
• Christof Wöll

Beilstein J. Nanotechnol. 2019, 10, 2449–2458, doi:10.3762/bjnano.10.235

• resistance, Rlat to the charge carrier mobility of anthracene and the charge carrier density N using the relation Here, l denotes the length of the current path, and A the cross-section. Using an average e-mobility in anthracene single crystals of 1 cm2/V s at 300 K [42], and a value of l/A of 1 nm−1, we

Coating of upconversion nanoparticles with silica nanoshells of 5–250 nm thickness

• Cynthia Kembuan,
• Maysoon Saleh,
• Bastian Rühle,
• Ute Resch-Genger and
• Christina Graf

Beilstein J. Nanotechnol. 2019, 10, 2410–2421, doi:10.3762/bjnano.10.231

• excitation power density, this can influence both the UCL intensity and the UCL spectral distribution. In general, the coating with a thick silica shell is not expected to strongly affect the brightness of the UCNPs as long as the two properties absorption cross section and fluorescence quantum yield, which

Semitransparent Sb₂S₃ thin film solar cells by ultrasonic spray pyrolysis for use in solar windows

• Jako S. Eensalu,
• Atanas Katerski,
• Erki Kärber,
• Lothar Weinhardt,
• Monika Blum,
• Clemens Heske,
• Wanli Yang,
• Ilona Oja Acik and
• Malle Krunks

Beilstein J. Nanotechnol. 2019, 10, 2396–2409, doi:10.3762/bjnano.10.230

• /TiO2/Sb2S3 stack. (c) EQE of the best-performing solar cell (100 nm Sb2S3) and absorption coefficients (α) of Sb2S3 and P3HT. (d) J–V curves at AM1.5G of 100 nm Sb2S3 solar cells of different size. SEM cross-section of the best-performing 5.5% PCE solar cell (100 nm Sb2S3) and the corresponding device

• Laboratory of Optoelectronic Materials Physics at Tallinn University of Technology (TUT) for recording the cross-section SEM image of the solar cell and for EDX measurements, and Eng. Jekaterina Kozlova from the Institute of Physics at Tartu University for recording surface SEM images of glass/ITO/TiO2/Sb2S3

Nontoxic pyrite iron sulfide nanocrystals as second electron acceptor in PTB7:PC₇₁BM-based organic photovoltaic cells

• Olivia Amargós-Reyes,
• José-Luis Maldonado,
• Omar Martínez-Alvarez,
• María-Elena Nicho,
• José Santos-Cruz,
• Juan Nicasio-Collazo,
• Irving Caballero-Quintana and
• Concepción Arenas-Arrocena

Beilstein J. Nanotechnol. 2019, 10, 2238–2250, doi:10.3762/bjnano.10.216

• OPV layers cross-section. We observe thicknesses of each layer that acceptably correlate with the sheet thicknesses determined by the AFM measurement in contact mode, namely ITO ≈197 nm, PEDOT:PSS ≈40 nm and PTB7:PC71BM active layer ≈113 nm. Figure S3(a–d) in Supporting Information File 1 shows the

Nonlinear absorption and scattering of a single plasmonic nanostructure characterized by x-scan technique

• Tushar C. Jagadale,
• Dhanya S. Murali and
• Shi-Wei Chu

Beilstein J. Nanotechnol. 2019, 10, 2182–2191, doi:10.3762/bjnano.10.211

• nonlinearity of a single nanostructure, but also reports surprisingly large plasmonic nonlinearities. Keywords: absorption cross section; laser scanning microscopy; nanoplasmonics; nonlinear absorption; nonlinear scattering; single gold nanostructures; Introduction It is well known that the optical

• with high-intensity laser light, the photothermal effect induces a change of the particle permittivity leading to the nonlinearity. However, this equation only explains a square-order difference between scattering and absorption. The above equation considers the total scattering cross section

Liquid crystal tunable claddings for polymer integrated optical waveguides

• José M. Otón,
• Manuel Caño-García,
• Fernando Gordo,
• Eva Otón,
• Morten A. Geday and
• Xabier Quintana

Beilstein J. Nanotechnol. 2019, 10, 2163–2170, doi:10.3762/bjnano.10.209

• of LC-cladding MMIs The pattern seen in Figure 4 repeats itself giving a number of specific effective device lengths for which a cross section would lead to several well-defined output channels at different distances LN. A graph of the characteristic lengths for four different output configurations

Nitrogen-vacancy centers in diamond for nanoscale magnetic resonance imaging applications

• Alberto Boretti,
• Lorenzo Rosa,
• Jonathan Blackledge and
• Stefania Castelletto

Beilstein J. Nanotechnol. 2019, 10, 2128–2151, doi:10.3762/bjnano.10.207

The importance of design in nanoarchitectonics: multifractality in MACE silicon nanowires

• Stefania Carapezzi and
• Anna Cavallini

Beilstein J. Nanotechnol. 2019, 10, 2094–2102, doi:10.3762/bjnano.10.204

• could induce a self-assembly [16][17] (see Figure 1). The process of the assembly of NWs induced by elastocapillary forces is complex. There are many factors that influence the assembly such as periodicity, height, cross section, and tensile strength of the NWs as well as evaporation rate and the

Nanostructured and oriented metal–organic framework films enabling extreme surface wetting properties

• Andre Mähringer,
• Julian M. Rotter and
• Dana D. Medina

Beilstein J. Nanotechnol. 2019, 10, 1994–2003, doi:10.3762/bjnano.10.196

• array of pillar-like structures with a cross-section of 20–30 nm and evident gaps between the pillars of about 150 nm for both samples (see Figure 2B,C). Cross-section SEM micrographs clearly visualize an array of vertically aligned MOF needles on the surface plane. In addition, a uniform film thickness

• of about 800 nm is observed throughout the cross-section of both Ni- and Co-CAT-1 samples, indicating a self-terminating growth under the employed conditions (Figure 3B and Figure S5.4, Supporting Information File 1). To confirm that the defined nanostructured film is indeed crystalline and the

• the solid/water interface on the identical pelletized sample. A) A scheme of the vapor-assisted conversion (VAC) set up and the resulting nanostructured films. B) SEM top view, 30° tilted cross-section and the related GIWAXS pattern of the Co-CAT-1 film. C) SEM top view, 30° tilted cross-section

Subsurface imaging of flexible circuits via contact resonance atomic force microscopy

• Wenting Wang,
• Chengfu Ma,
• Yuhang Chen,
• Lei Zheng,
• Huarong Liu and
• Jiaru Chu

Beilstein J. Nanotechnol. 2019, 10, 1636–1647, doi:10.3762/bjnano.10.159

• layer thicknesses. Cross-section profiles of Figure 7a at a middle layer thickness of 300 nm and a bottom layer thickness of 3500 nm are presented in Figure 7b and Figure 7c, respectively. It is obvious that a thicker bottom layer induces a better imaging contrast and the contrast plateaus at a higher

• different middle layer and bottom layer thicknesses. The theoretical calculations were made on the PMMA–Au–PMMA structures with a top layer thickness of 50 nm under a normal force of 100 nN. (b,c) Cross-section profiles at the middle layer thickness of 300 nm and the bottom layer thickness of 3500 nm

Effects of surface charge and boundary slip on time-periodic pressure-driven flow and electrokinetic energy conversion in a nanotube

• Mandula Buren,
• Yongjun Jian,
• Yingchun Zhao,
• Long Chang and
• Quansheng Liu

Beilstein J. Nanotechnol. 2019, 10, 1628–1635, doi:10.3762/bjnano.10.158

• nanotube, the net electric current over the cross section of the nanotube is zero, i.e., where σ = 2z2e2Dn0/(kBT) is the electric conductivity and D is the diffusivity of ions in the electrolyte. From the equation Is + Ic=0, the streaming electric field Es can be obtained in the form: Dimensionless

Flexible freestanding MoS₂-based composite paper for energy conversion and storage

• Florian Zoller,
• Jan Luxa,
• Thomas Bein,
• Dina Fattakhova-Rohlfing,
• Daniel Bouša and
• Zdeněk Sofer

Beilstein J. Nanotechnol. 2019, 10, 1488–1496, doi:10.3762/bjnano.10.147

• in Figure 2. The morphology images of the top side of the composite paper (Figure 2a and 2b) show a homogeneous distribution of SWCNTs among the MoS2 sheets. SEM micrographs of the cross-section (Figure 2c and 2d) also illustrate that the SWCNTs significantly contribute to the flexibility and

• MoS2-based composite paper showing its size and flexibility. SEM micrographs of (a,b) plane and (c,d) cross-section images of the composite paper at different magnifications. Core-level X-ray photoelectron spectra of a) Mo 3d region, b) S 2p region, and c) C 1s region. Charging–discharging curves of

Growth of lithium hydride thin films from solutions: Towards solution atomic layer deposition of lithiated films

• Ivan Kundrata,
• Karol Fröhlich,
• Lubomír Vančo,
• Matej Mičušík and
• Julien Bachmann

Beilstein J. Nanotechnol. 2019, 10, 1443–1451, doi:10.3762/bjnano.10.142

• cross-section sample. The differences in thickness are correct. Chemical composition of the sample surface as determined by XPS. Acknowledgements The author I.K. wishes to acknowledge the great help from, and the good spirit of the Bachmann group at FAU Erlangen. Also, we wish to acknowledge the

Multicomponent bionanocomposites based on clay nanoarchitectures for electrochemical devices

• Giulia Lo Dico,
• Bernd Wicklein,
• Lorenzo Lisuzzo,
• Giuseppe Lazzara,
• Pilar Aranda and
• Eduardo Ruiz-Hitzky

Beilstein J. Nanotechnol. 2019, 10, 1303–1315, doi:10.3762/bjnano.10.129

• Figure 3A, while SEM images (Figure 3D,F) reveal that the components are uniformly distributed throughout the film and are organized as a compact particle assembly within the chitosan matrix. Furthermore, the film cross section (Figure 3F) displays the typical layered structure of films solvent-cast from

• bionanocomposites: A) cross section of processed materials: HNTs and SEP are represented as tubes and fibres, while chitosan, GNPs and MWCNTs are depicted in the black matrix. Photographs of B) Film-1 and C) Foam-1. SEM micrographs of the film: D) upper surface, F) and H) cross section; SEM micrographs of the foam

Fabrication of phase masks from amorphous carbon thin films for electron-beam shaping

• Lukas Grünewald,
• Dagmar Gerthsen and
• Simon Hettler

Beilstein J. Nanotechnol. 2019, 10, 1290–1302, doi:10.3762/bjnano.10.128

• were generally smoother compared to the FIB-prepared thin films, higher quality PM gratings could be fabricated. For the highest spatial frequency of kρ = 10 µm−1 only the floated aC thin films showed good results (cf. Figure 4a,b). To study the depth profile of the PMs, cross-section TEM lamellas were

• is visible as a dark ring around the patterned structure in Figure 5a,b. Slight bulging of the aC film is also visible at the aperture edges. Cross-section samples were again prepared by FIB milling and investigated by bright-field TEM (Figure 5c,d). This time, the PMs were embedded between two

• ) floated aC thin films reveal a smoother surface for the latter. (c) The cross-section SEM image at the aperture edges reveals sagging of a floated thin film (10 nm) after additional deposition of 70 nm aC. (d) Floating of a comparably thick 80 nm aC film results in more stability at the aperture edge. (e