A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• Anh Quynh Huu Le Ngoc Nhu Thi Nguyen Hai Duy Tran Van-Huy Nguyen Le-Hai Tran Ho Chi Minh City University of Natural Resource and Environment, 236B Le Van Sy street, Tan Binh District, Ho Chi Minh City, Vietnam Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268

• the photoelectrochemical activity in aqueous environment [18][19][20]. Figure 4 shows the EDX spectra of MWCNTs and the TiO2@MWCNTs nanocomposite. The EDX spectrum for TiO2@MWCNTs confirms the presence of Ti, which accounts for 28.76 wt %. Small amounts of Fe, Al, and Si exists in as-synthesized

In search of cytotoxic selectivity on cancer cells with biogenically synthesized Ag/AgCl nanoparticles

• Mitzi J. Ramírez-Hernández,
• Mario Valera-Zaragoza,
• Omar Viñas-Bravo,
• Ariana A. Huerta-Heredia,
• Miguel A. Peña-Rico,
• Erick A. Juarez-Arellano,
• David Paniagua-Vega,
• Eduardo Ramírez-Vargas and
• Saúl Sánchez-Valdes

Beilstein J. Nanotechnol. 2022, 13, 1505–1519, doi:10.3762/bjnano.13.124

• ][27][28]. As mentioned by Raven [29], Cl− is an essential micronutrient for oxygenic photosynthetic organisms and is found in the environment in concentrations higher than those required by plants. Teixeira et al. [30] reported that the use of potassium chloride as a source of potassium for pineapple

Hydroxyapatite–bioglass nanocomposites: Structural, mechanical, and biological aspects

• Olga Shikimaka,
• Mihaela Bivol,
• Bogdan A. Sava,
• Marius Dumitru,
• Christu Tardei,
• Beatrice G. Sbarcea,
• Daria Grabco,
• Constantin Pyrtsac,
• Daria Topal,
• Andrian Prisacaru,
• Vitalie Cobzac and
• Viorel Nacu

Beilstein J. Nanotechnol. 2022, 13, 1490–1504, doi:10.3762/bjnano.13.123

• drawbacks. An ideal biomaterial to replace the bone tissue must integrate in the surrounding bone or soft tissue by stimulating osteoinduction and octeoconduction [1] at their interface in physiologic environment. Synthetic hydroxyapatite (HA), Ca10(PO4)6(OH)2, although being very similar to the mineral

• composition of bone, has a low resorption in physiologic environment and, therefore, does not form a tough bond with the bone [2]. The development of hydroxyapatite–bioglass (HA-BG) composites aimed to overcome this problem [3][4][5]. In these composites, the biocompatibility of HA is combined with the

• response in the physiologic environment [7][10][11][12][13][14][15][16][17][18]. The main role of SBG is the formation of CHA layer, whereas the role of PBG and BBG is the delivery of Ca and P ions, responsible for the osteogenesis, and other therapeutic elements due to their higher solubility. The

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• components of the g-tensor (Figure 8) show that the distortion of the coordination environment of Ni3+ ions (both axial and non-axial) decreases with the temperature at which the samples were prepared. There may be two reasons for the existence of two types of nickel complexes in the spectrum. The first

Coherent amplification of radiation from two phase-locked Josephson junction arrays

• Mikhail A. Galin,
• Vladimir M. Krasnov,
• Ilya A. Shereshevsky,
• Nadezhda K. Vdovicheva and
• Vladislav V. Kurin

Beilstein J. Nanotechnol. 2022, 13, 1445–1457, doi:10.3762/bjnano.13.119

• whole length of strips of JJs. However, for both samples the steps are more pronounced in the inner array-b than in the outer array-a. Presumably, this is due to a more beneficial EM environment for the inner strip, which has two adjacent strips on both sides operating as additional single-strip line

Facile preparation of Au- and BODIPY-grafted lipid nanoparticles for synergized photothermal therapy

• Yuran Wang,
• Xudong Li,
• Haijun Chen and
• Yu Gao

Beilstein J. Nanotechnol. 2022, 13, 1432–1444, doi:10.3762/bjnano.13.118

• μM), Au-LNPs (30 μM) and AB-LNPs (containing 30 μM BDP and 30 μM Au). Cells were cultured in dark environment with or without laser irradiation (680 nm, 0.5 W/cm2, 60 s). ** p < 0.01, **** p < 0.0001 compared with control by Student’s t-test. Schematic diagram of the preparation of AB-LNPs. Synthesis

Double-layer symmetric gratings with bound states in the continuum for dual-band high-Q optical sensing

• Chaoying Shi,
• Jinhua Hu,
• Xiuhong Liu,
• Junfang Liang,
• Jijun Zhao,
• Haiyan Han and
• Qiaofen Zhu

Beilstein J. Nanotechnol. 2022, 13, 1408–1417, doi:10.3762/bjnano.13.116

• , which are defined as the ratio of the resonant wavelength drift to the change in refractive index of the surrounding environment (S = Δλres/Δnc) and the ratio of sensitivity to the FWHM (FOM = S/FWHM), respectively [55]. Taking the structural parameters previously mentioned as an example, the proposed

• waves, while the FOM is proportional to the Q-factor, which ultimately represents the ability of the sensor to track small changes in the refractive index of the environment [39][57]. We also found that the S of mode 1 at different α and h values follows the same trend as the FOM. The simulation results

• symmetrical structure in vacuum which allows the optical field to be uniformly located in the grating and environment layers. This way, the confinement ability of the grating to the optical field is achieved while enhancing the relationship between light and matter. Finally, the performance of the DLSG-based

Orally administered docetaxel-loaded chitosan-decorated cationic PLGA nanoparticles for intestinal tumors: formulation, comprehensive in vitro characterization, and release kinetics

• Sedat Ünal,
• Osman Doğan and
• Yeşim Aktaş

Beilstein J. Nanotechnol. 2022, 13, 1393–1407, doi:10.3762/bjnano.13.115

• , enzymatic destructive environment, and transit time through the gastrointestinal tract, the ability of an orally administered formulation to reach colon carcinomas stably and effectively necessitates a serious pharmaceutical formulation study and a comprehensive evaluation. It is possible to overcome the

• because CS degrades more easily in a low-pH environment [50]. After the first four hours, uncoated PLGA NPs began to release more DCX compared to the coated formulation. Until the end of the experiment, the release profile of CS-coated PLGA NPs remained slower than that of uncoated PLGA NPs. This

• -PLGA NPs was examined in a release medium with progressively changing pH, reflecting the GIT environment. The real transit periods were examined with the dialysis membrane technique at 37 °C in a shaking water bath (100 rpm) under sink circumstances [10]. Release experiments were conducted by placing 3

LED-light-activated photocatalytic performance of metal-free carbon-modified hexagonal boron nitride towards degradation of methylene blue and phenol

• Nirmalendu S. Mishra and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2022, 13, 1380–1392, doi:10.3762/bjnano.13.114

• absorb LED light irradiation with a light harvesting efficiency of ≈90% and a direct bandgap of 2 eV. The introduction of carbon into the HBN lattice led to a significant change in the electronic environment through the formation of C–B and C–N bonds which resulted in improved visible light activity

Straight roads into nowhere – obvious and not-so-obvious biological models for ferrophobic surfaces

• Wilfried Konrad,
• Christoph Neinhuis and
• Anita Roth-Nebelsick

Beilstein J. Nanotechnol. 2022, 13, 1345–1360, doi:10.3762/bjnano.13.111

• (roughly) 1000 and 2500 °C prevail, it is, at best, possible to continuously measure the temperature of a tuyère, but no further experimental studies are possible within such an extreme environment. This means that in the considered project, such kind of systematic investigation was not possible

Near-infrared photoactive Ag-Zn-Ga-S-Se quantum dots for high-performance quantum dot-sensitized solar cells

• Roopakala Kottayi,
• Ilangovan Veerappan and
• Ramadasse Sittaramane

Beilstein J. Nanotechnol. 2022, 13, 1337–1344, doi:10.3762/bjnano.13.110

• , the Ag 3d, Zn 2p, S 2p, Se 3d, and Ga 2p peaks arise from AZGSSe QDs, and the O 1s and C 1s peaks are due to the absorption of oxygen and hydrocarbons from the environment [21][26][27]. The elemental Ag 3d spectrum (Figure 3b) shows the peaks of Ag 3d5/2 (368.32 eV) and Ag 3d3/2 (374.38 eV) with a

Recent trends in Bi-based nanomaterials: challenges, fabrication, enhancement techniques, and environmental applications

• Vishal Dutta,
• Ankush Chauhan,
• Ritesh Verma,
• C. Gopalkrishnan and
• Van-Huy Nguyen

Beilstein J. Nanotechnol. 2022, 13, 1316–1336, doi:10.3762/bjnano.13.109

• approaches affect the topological size and size distribution of semiconductor photocatalysts, substantially influencing adsorption characteristics and photocatalytic efficacy. As well as affecting the environment, synthesis size, and cost, the fabrication method also affects manufacturing safety

• applications [62]. A very good micro-/nanoscale hierarchical Bi7O9I3/NTC photocatalyst was created in a one-step, easy, and environmentally friendly way by Hou et al., who used an in situ ion exchange–recrystallization approach [63]. The used buffer provided a relatively stable environment for producing

Roll-to-roll fabrication of superhydrophobic pads covered with nanofur for the efficient clean-up of oil spills

• Patrick Weiser,
• Robin Kietz,
• Marc Schneider,
• Matthias Worgull and
• Hendrik Hölscher

Beilstein J. Nanotechnol. 2022, 13, 1228–1239, doi:10.3762/bjnano.13.102

• source [11][14]. All mentioned processes require potentially hazardous chemicals, chambers creating a suitable process environment, or extensive and costly operations to form superhydrophobic surfaces. Hence, they are not particularly well suited for upscaling. A rather cost-effective and, therefore

• durable. Other options for chemically treated superhydrophobic surfaces, such as the use of fluorinated silanes, fluoropolymer coatings, and carbon nanotubes, exist, but are either rather costly to apply and/or potentially harmful to the environment. A much simpler and cheaper option is the fabrication of

• . Furthermore secondary pollution is a problem with burning [34]. Chemical dispersion can be a last-ditch effort to protect sensitive areas from an oil spill but does not separate the oil from the water; many dispersants can also be toxic to the environment [33]. Commonly used sorbents used in the emergency

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• recognition modes could enable sensing even in a complex environment with harsh conditions, such as high temperature, acidity, or alkalinity [44]. Haupt and Kutner et al. embedded the β-blocker S-propranolol within a poly(trimethylolpropane trimethacrylate-co-methacrylic acid) membrane on the surface of QCM

• environment. The sensor showed excellent sensitivity and enantioselectivity to ʟ-phenylethylamine, whose recognition ability was temperature- and concentration-dependent. The variation in the chiral selectivity factors was suggested due to the matching of molecular size to the channel of the MOFs. Chiral

• , and the tetrahedral geometry of atomic packing in many nanoscale crystals [108][109][110]. The chiral inorganic nanostructures thus may create an asymmetric environment for enantiomers. As inorganic materials possess higher stability and might be suitable for different types of enantiomers, they are

Application of nanoarchitectonics in moist-electric generation

• Jia-Cheng Feng and
• Hong Xia

Beilstein J. Nanotechnol. 2022, 13, 1185–1200, doi:10.3762/bjnano.13.99

• from the residual soot after flame combustion of an organic liquid. After annealing and air plasma cleaning, the surface of these nanoparticles becomes hydrophilic, resulting in water molecules moving from the bottom to the top through capillary action in a natural water evaporation environment. The

• , how the largest possible proportion of nanochannels participates in the interaction with water molecules in a completely liquid environment is a problem for further exploration. The airflow rate is an important parameter for the output power (Figure 7d). From Equation 1, we can see that the faster the

• gradient structure can be constructed relative to any direction in space to meet the needs. Moisture-electric conversion devices in nanofluids have also been recently reported. An ionic liquid film of Omim+ Cl− was selected as the ion-exchange layer [88]. In a moisture-gradient environment (Figure 9) on

Rapid fabrication of MgO@g-C₃N₄ heterojunctions for photocatalytic nitric oxide removal

• Minh-Thuan Pham,
• Duyen P. H. Tran,
• Xuan-Thanh Bui and
• Sheng-Jie You

Beilstein J. Nanotechnol. 2022, 13, 1141–1154, doi:10.3762/bjnano.13.96

• Christian University, Taoyuan 32023, Taiwan Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology (HCMUT), VNU-HCM, 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City 700000, Viet Nam 10.3762/bjnano.13.96 Abstract Nitric oxide (NO) is an air pollutant impacting the

• environment, human health, and other biotas. Among the technologies to treat NO pollution, photocatalytic oxidation under visible light is considered an effective means. This study describes photocatalytic oxidation to degrade NO under visible light with the support of a photocatalyst. MgO@g-C3N4

• , Taiwan; Center for Environmental Risk Management, Chung Yuan Christian University, No.200, Taoyuan City, 32023, Taiwan; Faculty of Environment and Natural Resources, Ho Chi Minh City University of Technology (HCMUT), VNU-HCM, Vietnam. Funding This research was financially supported by the Chung Yuan

A cantilever-based, ultrahigh-vacuum, low-temperature scanning probe instrument for multidimensional scanning force microscopy

• Hao Liu,
• Zuned Ahmed,
• Sasa Vranjkovic,
• Manfred Parschau,
• Andrada-Oana Mandru and
• Hans J. Hug

Beilstein J. Nanotechnol. 2022, 13, 1120–1140, doi:10.3762/bjnano.13.95

• -based AFM instrument, which is not only optimized for atomic resolution work, but also permits high-bandwidth AFM operation and, thus, at least in principle, the implementation of more complex AFM operation modes (typically used for ambient environment AFM) also under UHV and low-temperature conditions

Green synthesis of zinc oxide nanoparticles toward highly efficient photocatalysis and antibacterial application

• Vo Thi Thu Nhu,
• Nguyen Duy Dat,
• Le-Minh Tam and
• Nguyen Hoang Phuong

Beilstein J. Nanotechnol. 2022, 13, 1108–1119, doi:10.3762/bjnano.13.94

• blue; methyl orange; rosin; ZnO nanoparticles; Introduction Currently, industrial development has generated a large number of pollutants which are released into the environment. The textile industry is one of the sources of organic pollution which is harmful to the environment and humans. Various

• physical routes have their own disadvantages, such as adverse environmental effects due to the use of environmentally unfriendly chemicals or to the release of heat into the environment [17]. Therefore, the development of green approaches is necessary. The biosynthetic process using plant extracts as an

• alternative route is a promising method for synthesizing nanomaterials due to its rapid, low-cost protocol, and safety to the environment [18]. Numerous studies applied green methods for the synthesis of ZnO nanoparticles from plants, fruits, plant extracts, and seaweeds [19][20][21][22]. Rafaie et al. [23

Recent advances in green carbon dots (2015–2022): synthesis, metal ion sensing, and biological applications

• Aisha Kanwal,
• Naheed Bibi,
• Sajjad Hyder,
• Arif Muhammad,
• Hao Ren,
• Jiangtao Liu and
• Zhongli Lei

Beilstein J. Nanotechnol. 2022, 13, 1068–1107, doi:10.3762/bjnano.13.93

Biomimetic chitosan with biocomposite nanomaterials for bone tissue repair and regeneration

• Se-Kwon Kim,
• Sesha Subramanian Murugan,
• Pandurang Appana Dalavi,
• Sebanti Gupta,
• Sukumaran Anil,
• Gi Hun Seong and
• Jayachandran Venkatesan

Beilstein J. Nanotechnol. 2022, 13, 1051–1067, doi:10.3762/bjnano.13.92

• performed using mouse embryonic fibroblasts and the increased activity on the 21st day demonstrates a favourable environment for cell development and differentiation. The in vivo investigation was conducted on two male rabbits by making two 25 mm longitudinal incisions on the right and left dorsum. The

• -hydroxybutyrate) composites generates a hydrophilic environment which promotes cell motility, adhesion, and protein adsorption. Furthermore, the mixture enhances the surface roughness of the composites, stimulating bone cells to attach to the surface [108]. The different characteristics of the 3D porous collagen

• , treating bone calvarial defects with a natural, mechanical, and biochemical environment with accomplished osteoblast differentiation and proliferation has been addressed by using chitosan–graphene nanocomposite materials. The bone structure. The magnified image shows the physiological arrangement of the

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• ]. Chlortetracycline (CTC) is the first tetracycline antibiotic used for veterinary purposes [3]. Due to the abusive use of CTC in livestock industry and the low absorption in animals, a large amount of CTC has been released into the environment through animal excretions. At present, CTC has been detected in aquatic

• environments in concentrations of approx. 0.08–0.61 μg/L [3]. The residual CTC in the environment can lead to the emergence of antibiotic-resistant pathogens, posing a serious threat to human health and aquatic ecosystems [4]. So, it is an important and urgent task to find an efficient and green method to

• remove CTC existing in the aquatic environment. Up to now, various technologies, including adsorption, hydrolysis, and biodegradation, have been applied in the removal of pollutants from water [5][6][7][8]. Owing to the relatively complicated treatment, high cost, and possible secondary pollution, these

Electrocatalytic oxygen reduction activity of AgCoCu oxides on reduced graphene oxide in alkaline media

• Iyyappan Madakannu,
• Indrajit Patil,
• Bhalchandra Kakade and
• Kasibhatta Kumara Ramanatha Datta

Beilstein J. Nanotechnol. 2022, 13, 1020–1029, doi:10.3762/bjnano.13.89

• n was found to be ca. 3.7 (Figure 3d) indicating single-step ORR kinetics. Thus, our RDE and RRDE studies reveals that ACC-2 catalyst exhibits a one-step conversion of O2 to OH− in alkaline electrolytic environment with kinetics similar to that of commercial Pt/C catalysts. Furthermore, the relative

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

• Dick Hartmann Douma,
• Lodvert Tchibota Poaty,
• Alessio Lamperti,
• Stéphane Kenmoe,
• Abdulrafiu Tunde Raji,
• Alberto Debernardi and
• Bernard M’Passi-Mabiala

Beilstein J. Nanotechnol. 2022, 13, 975–985, doi:10.3762/bjnano.13.85

• spectrum shows a further decrease in the intensity of the pre-edge peak, compared to the case of a single vacancy. Thus, the changes in the intensity of the pre-edge peak evidence a major structural change in the local environment around nickel atoms and, by extension, in the zirconia matrix. This change

• of the zirconia system due to the variation of the number of electrons in the transition metal d orbital states. In this context, an experimental probe sensitive to the oxidation states of the magnetic ion as well as the local environment specific to a probed atom will be vital. Thus, X-ray

• electric dipolar selection rule Δl = ±1, and also to the stereochemical arrangement of neighbors around the absorbing atom. By tuning the incident photon energy to the X-ray edge energy of the target atom, it is possible to determine the coordination environment, bonding characteristics, as well as spin

Design of a biomimetic, small-scale artificial leaf surface for the study of environmental interactions

• Miriam Anna Huth,
• Axel Huth,
• Lukas Schreiber and
• Kerstin Koch

Beilstein J. Nanotechnol. 2022, 13, 944–957, doi:10.3762/bjnano.13.83

• with its superimposed epicuticular waxes represents the barrier of all aboveground parts of higher plant primary tissues. Epicuticular waxes have multiple effects on the interaction of plants with their living and non-living environment, whereby their shape, dimension, arrangement, and chemical

• the plant cuticle and, thus, the first contact site of the plant with its biotic and abiotic environment. They form a thin crystalline wax film (less than 1 µm) and often various three-dimensional emerging wax crystals in the nano- and micrometer range (0.5–100 µm) [14][15][16]. Recrystallization of

• among the most common wax structures. An overview of the morphology of various wax structures has been given by Barthlott and co-workers [24]. Wetting The wettability of leaves plays an important role in the interaction of plants with the environment, such as the interaction with pathogens and the

Comparing the performance of single and multifrequency Kelvin probe force microscopy techniques in air and water

• Jason I. Kilpatrick,
• Emrullah Kargin and
• Brian J. Rodriguez

Beilstein J. Nanotechnol. 2022, 13, 922–943, doi:10.3762/bjnano.13.82

• first two eigenmodes of the cantilever. These comparisons allow the reader to quickly and quantitatively identify the parameters for the best performance for a given KPFM-based experiment in a given environment. Furthermore, we apply these performance metrics in the identification of KPFM-based modes

• function of the cantilever. This frequency-dependent gain, XGain, represents the sensitivity ratio of the cantilever at the two frequencies of interest. XGain is relatively stable for a given tip–sample distance in a given environment and, as such, can be approximated mathematically [29]. However, changes

• in environment, tip–sample distance, and the influence of piezo-based mechanical activation significantly complicates these relationships and, as such, many techniques require the explicit measurement of XGain in order to be quantitative [29]. Spectral KPFM techniques (e.g., band excitation KPFM (BE